Crystal structure refinement of chromites from two achondrites, their T-f(O2) conditions, and implications

1Davide Lenaz,2Birger Schmitz
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12885]
1Department of Mathematics and Geosciences, University of Trieste, Trieste, Italy
2Division of Nuclear Physics, Department of Physics, Lund University, Lund, Sweden
Published by arrangement with John Wiley & Sons

Six Cr-spinel grains from NWA 6077 brachinite-like and NWA 725 winonaite achondrites have been studied by single-crystal X-ray diffraction and structural refinement. From a chemical point of view, spinels from NWA 6077 show Cr/(Cr + Al) (i.e., Cr#) and Mg/(Mg + Fe2+) (i.e., Mg#) values similar to other brachinites, while the Cr# of NWA 725 is lower than that of literature winonaites. Spinels from NWA 6077 and NWA 725 meteorites show similar cell edges, while the oxygen positional parameter is rather different being about 0.2629 for NWA 6077 and 0.2622 for NWA 725. Considering both parameters, NWA 725 shows structural features that are close to some terrestrial spinel occurrences as in komatiites, kimberlites, or included in diamonds; those from NWA 6077 show values that have no terrestrial analogs. Olivine-chromite closure temperature ranges from ~737 to ~765° C for NWA 725, being similar to that of literature winonaites and ~846 to ~884° C for NWA 6077. The logfO2 ranges from −19.8 to −20.5 and −17.0 to −17.9 for the two meteorites, respectively. The u values for terrestrial samples can give information about the cooling history of the samples. For the extraterrestrial samples, it seems that it can give information about the cooling only for spinels where it is lower than 0.2625. For higher values, it appears related only to the chemistry of the spinels.

New insights on petrography and geochemistry of impactites from the Lonar crater, India

1Dwijesh Ray,2Dewashish Upadhyay,3Saumitra Misra,4Horton E. Newsom,1Sambhunath Ghosh
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12881]
1Planetary Sciences Division, Physical Research Laboratory, Ahmedabad, India
2Department of Geology and Geophysics, Indian Institute of Technology, Kharagpur, India
3Discipline of Geological Sciences, SAEES, University of KwaZulu-Natal, Durban, South Africa
4Institute of Meteoritics and Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, USA
Published by arrangement with John Wiley & Sons

The Lonar impact crater, India, is one of the few known terrestrial impact craters excavated in continental basaltic target rocks (Deccan Traps, ~65 Ma). The impactites reported from the crater to date mainly include centimeter- to decimeter-sized impact-melt bombs, and aerodynamically shaped millimeter- and submillimeter-sized impact spherules. They occur in situ within the ejecta around the crater rim and show schlieren structure. In contrast, non–in situ glassy objects, loosely strewn around the crater lake and in the ejecta around the crater rim do not show any schlieren structure. These non–in situ fragments appear to be similar to ancient bricks from the Daityasudan temple in the Lonar village. Synthesis of existing and new major and trace element data on the Lonar impact spherules show that (1) the target Lonar basalts incorporated into the spherules had undergone minimal preimpact alteration. Also, the paleosol layer as preserved between the top-most target basalt flow and the ejecta blanket, even after the impact, was not a source component for the Lonar impactites, (2) the Archean basement below the Deccan traps were unlikely to have contributed material to the impactite parental melts, and (3) the impactor asteroid components (Cr, Co, Ni) were concentrated only within the submillimeter-sized spherules. Two component mixing calculations using major oxides and Cr, Co, and Ni suggest that the Lonar impactor was a EH-type chondrite with the submillimeter-sized spherules containing ~6 wt% impactor components.

From planets to crops and back: Remote sensing makes sense

1John F. Mustard
Journal of Geophysical Research Planets (in Press) Link to Article [DOI: 10.1002/2017JE005315]
1Department of Earth, Environmental and Planetary Sciences, Brown University, Providence, Rhode Island, USA
Published by arrangement with John Wiley & Sons

Remotely sensed data and the instruments that acquire them are core parts of Earth and planetary observation systems. They are used to quantify the Earth’s interconnected systems, and remote sensing is the only way to get a daily, or more frequent, snapshot of the status of the Earth. It really is the Earth’s stethoscope. In a similar manner remote sensing is the rock hammer of the planetary scientist and the only way comprehensive data sets can be acquired. To risk offending many remotely sensed data acquired across the electromagnetic spectrum, it is the tricorder to explore known and unknown planets. Arriving where we are today in the use of remotely sensed data in the solar system has been a continually evolving synergy between Earth observation, planetary exploration, and fundamental laboratory work.

Alkali trace elements in Gale crater, Mars, with ChemCam: Calibration update and geological implications

1V.Payré et al. (>10)*
Journal of Geophysical Research Planets (in Press) Link to Article [DOI: 10.1002/2016JE005201]
1GeoRessources, Université de Lorraine, Nancy, France
*Find the extensive, full author and affiliation list on the publishers website
Published by arrangement with John Wiley & Sons

The Chemistry Camera (ChemCam) instrument onboard Curiosity can detect minor and trace elements such as lithium, strontium, rubidium, and barium. Their abundances can provide some insights about Mars’ magmatic history and sedimentary processes. We focus on developing new quantitative models for these elements by using a new laboratory database (more than 400 samples) that displays diverse compositions that are more relevant for Gale crater than the previous ChemCam database. These models are based on univariate calibration curves. For each element, the best model is selected depending on the results obtained by using the ChemCam calibration targets onboard Curiosity. New quantifications of Li, Sr, Rb, and Ba in Gale samples have been obtained for the first 1000 Martian days. Comparing these data in alkaline and magnesian rocks with the felsic and mafic clasts from the Martian meteorite NWA7533—from approximately the same geologic period—we observe a similar behavior: Sr, Rb, and Ba are more concentrated in soluble- and incompatible-element-rich mineral phases (Si, Al, and alkali-rich). Correlations between these trace elements and potassium in materials analyzed by ChemCam reveal a strong affinity with K-bearing phases such as feldspars, K-phyllosilicates, and potentially micas in igneous and sedimentary rocks. However, lithium is found in comparable abundances in alkali-rich and magnesium-rich Gale rocks. This very soluble element can be associated with both alkali and Mg-Fe phases such as pyroxene and feldspar. These observations of Li, Sr, Rb, and Ba mineralogical associations highlight their substitution with potassium and their incompatibility in magmatic melts.

Shocked chromites in fossil L chondrites: A Raman spectroscopy and transmission electron microscopy study

1,2Surya S. Rout,1,2,3Philipp R. Heck,4Nestor J. Zaluzec,5Takayuki Ishii,6Jianguo Wen,6Dean J. Miller,1,7Birger Schmitz
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12887]
1Robert A. Pritzker Center for Meteoritics and Polar Studies, The Field Museum of Natural History, Chicago, Illinois, USA
2Chicago Center for Cosmochemistry, The University of Chicago, Chicago, Illinois, USA
3Department of the Geophysical Sciences, The University of Chicago, Chicago, Illinois, USA
4Photon Science Division, Argonne National Laboratory, Argonne, Illinois, USA
5Bayerisches Geoinstitut, University of Bayreuth, Bayreuth, Germany
6Electron and X-ray Microscopy, Center for Nanoscale Materials, Argonne National Laboratory, Argonne, Illinois, USA
7Astrogeobiology Laboratory, Department of Physics, Lund University, SE, Lund, Sweden
Published by arrangement with John Wiley & Sons

Chromites from Middle Ordovician fossil L chondrites and from matrix and shock-melt veins in Catherwood, Tenham, and Coorara L chondrites were studied using Raman spectroscopy and TEM. Raman spectra of chromites from fossil L chondrites showed similarities with chromites from matrix and shock-melt veins in the studied L chondrite falls and finds. Chromites from shock-melt veins of L chondrites show polycrystallinity, while the chromite grains in fossil L chondrites are single crystals. In addition, chromites from shock-melt veins in the studied L chondrites have high densities of planar fractures within the subgrains and many subgrains show intergrowths of chromite and xieite. Matrix chromite of Tenham has similar dislocation densities and planar fractures as a chromite from the fossil meteorite Golvsten 001 and higher dislocation densities than in chromite from the fossil meteorite Sextummen 003. Using this observation and knowing that the matrix of Tenham experienced 20–22 GPa and <1000° C, an upper limit for the P,T conditions of chromite from Golvsten 001 and Sextummen 003 can be estimated to be 20–22 GPa and 1000° C (shock stage S3–S6) and 20 GPa and 1000° C (S3–S5), respectively, and we conclude that the studied fossil meteorite chromites are from matrix.

Preferential Formation of Sodium Salts from Frozen Sodium-Ammonium-Chloride-Carbonate Brines – Implications for Ceres’ Bright Spots

1,2Tuan H. Vu, 1,2Robert Hodyss, 1,2Paul V. Johnson, 1,2Mathieu Choukroun
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2017.04.014]
1Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109, USA
2NASA Astrobiology Institute

We currently do not have a copyright agreement with this publisher and cannot display the abstract here

Meteorite transport—Revisited

1Jack Wisdom
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12876]
1Massachusetts Institute of Technology, Cambridge, Massachusetts, USA
Published by arrangement with John Wiley & Sons

Meteorites are delivered from the asteroid belt by way of chaotic zones (Wisdom 1985a). The dominant sources are believed to be the chaotic zones associated with the ν6 secular resonance, the 3:1 mean motion resonance, and the 5:2 mean motion resonance. Though the meteorite transport process has been previously studied, those studies have limitations. Here I reassess the meteorite transport process with fewer limitations. Prior studies have not been able to reproduce the afternoon excess (the fact that approximately twice as many meteorites fall in the afternoon as in the morning) and suggested that the afternoon excess is an observational artifact; here it is shown that the afternoon excess is in fact consistent with the transport of meteorites by way of chaotic zones in the asteroid belt. By studying models with and without the inner planets it is found that the inner planets significantly speed up the transport of meteorites.

Meteorite falls in Bulgaria: Reappraisal of mineralogy, chemistry, and classification

1,2Vesselin Dekov, 3Pierre Rochette, 3Jérôme Gattacceca
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.12879]
1Tokyo University of Marine Science and Technology, Tokyo, Japan
2Department of Marine Geosciences, IFREMER, Centre de Brest, Plouzané, France
3Aix-Marseille Univ, CNRS, IRD, Coll France, CEREGE, Aix-en-Provence, France
Published by arrangement with John Wiley & Sons

We present a summary of the mineralogy, mineral chemistry, and magnetic characteristics of all the five Bulgarian meteorite falls. We report the first mineralogical descriptions, chemical analyses, and magnetic measurements of the Konevo (1931) and Silistra (1917) meteorites. We classify Konevo as LL5, and Silistra as an ungrouped achondrite with HED affinities. Pavel (1966; previously classified as an H5) is reclassified as H3-anomalous. We also provide precise mineralogy and mineral chemistry of the Virba meteorite (1873, L6), and more details on the mineral chemistry of Gumoschnik (1904, H5).

Magmatic evolution of lunar highland rocks estimated from trace elements in plagioclase: A new bulk silicate Moon model with sub-chondritic Ti/Ba, Sr/Ba, and Sr/Al ratios

1Shigeko Togashi, 2Noriko T. Kita, 1Akihiko Tomiya, 1,3Yuichi Morishita
Geochimica et Cosmochimica Acta (in Press) Link to Article [http://doi.org/10.1016/j.gca.2017.04.031]
1Geological Survey of Japan, AIST, Central 7, Higashi 1-1-1, Tsukuba 305-8567, Japan
2Department of Geoscience, University of Wisconsin-Madison, 1215 W Dayton Street Madison, WI 53706-1692, USA
3Department of Geoscience, Shizuoka University, 836 Ohya, Suruga-ku, Shizuoka 422-8529, Japan
Copyright Elsevier

The compositions of host magmas of ferroan anorthosites (FAN-host magmas) were estimated from secondary ion mass spectrometry analyses of plagioclase in lunar highland rocks. The evolution of the magmas was investigated by considering phase relations based on the MELTS algorithm and by re-examining partition coefficients for trace elements between plagioclase and melts. Data little affected by post-magmatic processes were selected by using plagioclase with relatively primitive Sc and Co contents. The FAN-host magma contained 90–174 ppm Sr, 40–119 ppm Ba and 0.5–1.3% TiO2, and had sub-chondritic Sr/Ba and Ti/Ba ratios. It is difficult to account for the formation of FAN-host magma on the basis of magma evolution processes of previously proposed bulk silicate Moon models with chondritic ratios for refractory elements at global scale. Therefore, the source of the FAN-host magma must have had primordial sub-chondritic Sr/Ba and Ti/Ba ratios. The FAN-host magmas were consistent in refractory elements with the estimated host mafic magma for feldspathic crust based on lunar meteorites, and some very-low-Ti mare rocks from lunar meteorites. Here, we propose an alternative bulk silicate Moon model (the cBSM model), which is enriched in crustal components of proto-bodies relative to the present whole Earth–Moon system.