Exploring the igneous chondrule bearing partially melted Antarctic and deep-sea micrometeorites

1Dafilgo Fernandes,1,2N. G. Rudraswami,1,2V. P. Singh
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.70206]
1National Institute of Oceanography (Council of Scientific and Industrial Research), Dona Paula, India
2Academy of Scientific and Innovative Research (AcSIR), Ghaziabad, India
Published by arrangement with John Wiley & Sons

We report 14 Antarctic and 15 deep-sea partially melted micrometeorites containing ~71 to 458 μm rounded, porous, and intact igneous objects. These objects likely represent non-porphyritic igneous chondrules. Analyzing these objects allows us to better relate them to the constituents of their parent bodies, thereby improving our understanding of the chondrule properties inherent to micrometeorite precursors. Seven identified Antarctic spherules and all deep-sea spherules primarily exhibit radial pyroxene (Rp) textures; one Antarctic composite spherule contains an Rp object embedded within an olivine matrix. Additionally, four Antarctic spherules show barred olivine (Bo) textures, two of which are surrounded by igneous rims, while two other Antarctic spherules show cryptocrystalline (Cc) textures. The bulk major and minor element oxides for the Rp objects vary significantly: MgO ~25.4 to 39.0 wt%, Al2O3 ~ 0.03 to 3.23 wt%, SiO2 ~ 44.7 to 55.1 wt%, CaO ~0.02 to 2.72 wt%, Cr2O3 ~ 0.18 to 1.44 wt%, MnO ~0.18 to 1.51 wt%, and FeO ~11.4 to 22.1 wt%. The chemical compositions of the pyroxene within the Rp spherules suggest they originate primarily from unequilibrated–equilibrated ordinary chondrites (UOC–EOC) rather than carbonaceous chondrites. Conversely, the glass chemical compositions of the Cc spherules (MgO ~32.9 to 42.4 wt% and FeO ~0.73 to 10.5 wt%; En98-83) largely support an origin from chondritic carbonaceous materials. Atmospheric entry heating has progressively altered the chemical composition of the Bo spherules beyond recognition from their original chondrule states. Ultimately, their collective chemical compositions suggest that these spherules may consist of chondrules similar to non-porphyritic chondrules in carbonaceous and ordinary chondrites. Based on their textures and mineralogy, these spherules indicate that the parent sources of these micrometeorites are chondrule-bearing asteroid bodies.

The Ames impact structure, Oklahoma: New radioisotopic constraints and implications for North American impact chronology

1,2Elizabeth J. Catlos,1Andrew F. Parisi,1Michael E. Brookfield,3Timmons Erickson,1,2Sean P.S. Gulick,4,5Axel K. Schmitt,1,2Daniel F. Stockli,6Daniel P. Miggins,7Ben Ruchte,1Mark Cloos
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70191]
1Department of Earth & Planetary Sciences, Jackson School of Geosciences, The University of Texas at Austin, Austin, Texas,USA
2Center for Planetary Systems Habitability, The University of Texas at Austin, Austin, Texas, USA
3Amentum – JETS II, Astromaterials Research and Exploration Science Division, NASA Johnson Space Center, Houston,Texas, USA
4Institute of Earth Sciences, Heidelberg University, Heidelberg, Germany
5John de Laeter Centre, Curtin University, Bentley, Western Australia, Australia
6College of Earth, Ocean, and Atmospheric Sciences, Oregon State University, Corvallis, Oregon, USA
7IXRF, Inc., Austin, Texas, USA
Published by arrangement with John Wiley & Sons

The Ames impact structure (Oklahoma) is thought to have formed during the Ordovician Meteor Event, based on conodont biostratigraphy of its crater fill. Here, U–Pb zircon dates from its impact-melt portion, conducted using secondary ion mass spectrometry and laser ablation–inductively coupled plasma–mass spectrometry (n = 37 spots), yield a Mesoproterozoic emplacement age for the impacted granodiorite (1401.2 ± 8.1 Ma, ±2σ, upper Concordia intercept). However, the youngest zircon dates define a weighted mean age of 369.7 ± 5.9 Ma (n = 10/11), with MSWD = 0.71 and p(χ2) = 0.7. Cathodoluminescence and electron backscattered diffraction images reveal that most zircons, including the youngest Devonian-age grains, show primary oscillatory zoning and lack deformation. However, two have impact-related textures, including regions of low-angle grain boundaries within microcracks and discrete arrays of granular zircon crosscutting oscillatory growth zoning. Plagioclase (n = 6 samples, 40Ar/39Ar) yields Late Carboniferous (~310.5 Ma) and Permian (~250.5 Ma) approximate total fusion dates that overlap the timing of heating and hydrocarbon maturation in the crater, suggesting the argon system records postimpact thermal overprinting. Based on the youngest zircon dates, the Ames impact structure may record activity near the Frasnian–Famennian boundary, contemporaneous with other North American impacts.

Potassium isotopic compositions and exposure ages of evolved and silica-rich achondrites

1Z. Vaci,2Z. Tian,2P. Koefoed,3M. Habermann,4M. Humayun,3K. Ziegler,5H. Busemann,5D. Krietsch,6J. M. D. Day,2K. Wang
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70199]
1Institute of Petrology and Structural Geology, Charles University, Prague, Czech Republic
2Department of Earth, Environmental, and Planetary Sciences, Washington University in St. Louis, St. Louis, Missouri, USA
3Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, USA
4National High Magnetic Field Laboratory, Florida State University, Tallahassee, Florida, USA
5Institute of Geochemistry and Petrology, ETH Z€urich, Z€urich, Switzerland
6Scripps Institution of Oceanography, University of California San Diego, La Jolla, California, USA
Published by arrangement with John Wiley and Sons

Some of the oldest igneous rocks in the Solar System include evolved and silica-rich achondrites that originate from parent bodies less than 1000 km in diameter, referred to as planetesimals. While Earth was initially in a molten state and required continental crust formation and plate tectonics to generate andesite bulk compositions, evolved and silica-rich achondrites likely formed from smaller degrees of melting and differentiation on initially chondritic parent bodies. Petrographic descriptions, bulk and in situ chemical analyses, oxygen and potassium isotope measurements, and noble gas analyses are presented to constrain the petrogenesis and possible associations of a suite of evolved and silica-rich achondrites including a trachyandesitic clast from the Almahata Sitta fall (ALM-A), Northwest Africa (NWA) 6698, NWA 11119, its launch pair NWA 11558, NWA 11575, and Graves Nunataks 06128 and 06129. In addition, leaching experiments were conducted that included terrestrial samples to examine the effects potential weathering-induced alteration might have on potassium isotope compositions. The measured potassium isotopic compositions do not covary with volatile depletion, as found when comparing samples from Earth, the Moon, Mars, and the asteroid Vesta, indicating that the planetary depletion trend observed in larger bodies does not apply in the absence of complete planetary differentiation. Modeled noble gas retention ages confirm the ancient formation times of several of these achondrites, while cosmic ray exposure ages suggest separation from their parent bodies in the past ~25 million years.

Petrogenesis of the Amazonian enriched gabbroic shergottite Northwest Africa 13440

1,2Robert W. Nicklas,2Dylan M. Seal,2Melody Z. Chen,2Kyra L. Schroeder,3James M. D. Day,4Ben G. Rider-Stokes,5Anthony B. Love,4James Malley
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.70202]
1Lunar and Planetary Institute, USRA, Houston, Texas, USA
2Department of Earth and Environmental Sciences, Boston College, Chestnut Hill, Massachusetts, USA
3Scripps Institution of Oceanography, University of California San Diego, La Jolla, California, USA
4School of Physical Sciences, The Open University, Milton Keynes, UK
5Department of Geological and Environmental Sciences, Appalachian State University, Boone, North Carolina, USA
Published by arrangement with John Wiley & Sons

As the most common samples available from Mars, shergottites offer important constraints on the igneous history of the planet into the Amazonian epoch. The newly recognized shergottite Northwest Africa (NWA) 13440 is here classified as a gabbroic shergottite and is likely launched-paired with NWA 6963, exhibiting many of the unusual textural features of that sample. The Sm-Nd isotope systematics of NWA 13440 yielded an errorchron age of 206 ± 34, with an εNdi = −7.1. This age and εNdi, coupled with a bulk rock (La/Yb)N of 1.02, allow for its classification as an enriched shergottite. The presence of unusual augite inclusions in pigeonite laths testifies to the importance of undercooling and nonequilibrium crystallization early in the history of the parental magma of the meteorite. Additionally, Si-rich mesostasis consisting of fine-grained irregular quartz-alkaline feldspar intergrowths suggests extreme fractional crystallization of the final few percent of melt. Shock textures indicate a moderate shock stage of approximately M-S4. The discovery of NWA 13440 supports the model that many of the enriched shergottites are the martian equivalent of a continental flood basalt province.

Distribution of purine and pyrimidine bases in Antarctic carbonaceous meteorites

1Yasuhiro Oba et al. (>10)
Geochimica et Cosmochimica Acta (in Press) Link to Article [10.1016/j.gca.2026.06.040]
1Institute of Low Temperature Science (ILTS), Hokkaido University, N19W8, Kita-ku, Sapporo, Hokkaido 060-0819, Japan
Copyright Elsevier

Carbonaceous meteorites preserve organic records of early Solar System chemistry, yet nucleobase inventories remain difficult to interpret owing to potential terrestrial contamination and parent–body processing effects. Here we report high–resolution liquid chromatography/Orbitrap mass spectrometry analyses of purine and pyrimidine bases in six Antarctic carbonaceous meteorites (CM: Y–791198, A–12236, Y–793321, B–7904; CR: A–881828, Y–002540) using rigorously controlled extractions (hot water and 20% HCl treatments) performed in ISO–class clean environments, together with Antarctic ice as an environmental blank. All five canonical nucleobases were identified in Y–791198, A–12236, and A–881828; subsets were found in Y–793321 and Y–002540; and none were detected in B–7904 or in the ice meltwater/hydrolysate. These patterns, coupled with the thermal metamorphic history of B–7904, indicate no detectable incorporation of nucleobases from Antarctic ice during ∼ 105–year residence. Total pyrimidines correlate positively with NH3 across Antarctic meteorites and previously reported extraterrestrial samples, whereas purines do not, implicating NH3-facilitated pyrimidine formation and the involvement of additional precursors (e.g., cyanides) in purine synthesis. Cytosine is systematically depleted relative to other canonical bases, likely reflecting its low–temperature hydrolysis to uracil; leaching losses appear negligible as highly water-soluble species (e.g., hydroxypyrimidines and NH3) are retained within the meteorites. Our results establish Antarctic meteorites as some of the least contaminated materials for constraining nucleobase distributions and underscore the need for direct cyanide measurements to resolve purine formation pathways.

Chemical and isotopic compositions of aluminum-rich chondrules: insights into material mixing in the early solar system

1Yuki Masuda, 2Yoshiaki Shiraishi, 2Tetsuya Yokoyama, 3Tsuyoshi Iizuka, 1Martin Schiller, 1Martin Bizzarro
Geochimica et Cosmochimica Acta (in Press) Open Access Link to Article [10.1016/j.gca.2026.07.004]
1Centre for Star and Planet Formation, Globe Institute, University of Copenhagen, Øster Voldgade 5-7, 1350 Copenhagen, Denmark
2Department of Earth and Planetary Sciences, Institute of Science Tokyo, Meguro, Tokyo 152-8551, Japan
3Department of Earth and Planetary Science, University of Tokyo, Hongo 7-3-1, Bunkyo, Tokyo 113-0033, Japan
Copyright Elsevier

Chondrules are high-temperature products formed in the protoplanetary disk and are ubiquitous components of undifferentiated extraterrestrial materials. Nucleosynthetic isotope anomalies preserved in chondrules provide a valuable record of isotopic evolution of solids from presolar dust to the accretion of planets. Among various types of chondrules, Al-rich chondrules (ARCs) possess intermediate isotopic and chemical compositions between calcium-aluminum-rich inclusions (CAIs) and ferromagnesian chondrules (FMCs), providing insights into mixing processes of various materials formed in different regions and/or at different times in the protoplanetary disk. This study performed analyses of the abundances of 54 elements and multi-elemental isotopic compositions of Ca-Ti-Cr-Sr on fourteen ARCs extracted from four Vigarano-type chondrites (CVs). Their element abundance patterns demonstrate enrichments reaching up to 10 times of Ivuna-type carbonaceous chondrites (CIs) in refractory elements and depletions down to < 0.05 × CI in volatile elements. Eight ARCs show highly fractionated rare-earth-elements (REEs) signatures, while six ARCs display flat REE patterns. These features suggest that CV ARCs have recycled refractory inclusions, including fine-grained CAIs (FG-CAIs) and other REE-unfractionated types, in addition to less-refractory components with chondritic or matrix-like compositions similar to those contributing to FMCs. The Ca, Ti, and Sr isotopic compositions of the ARCs exhibit variations ranging from those of non-carbonaceous chondrite (NC) components to coarse-grained CAIs (CG-CAIs) and FG-CAIs. The observed isotopic compositions are not consistent with a simple mixture of NC with a single type of refractory inclusion, suggesting that they contain various types of refractory materials. The Cr isotopic compositions of CV ARCs are intermediate between those of NCs and CIs. The observed isotopic variation indicates that components of NC, CI, and refractory inclusions coexisted in the CV chondrule-forming region. This is in contrast to NC chondrule-forming regions, which do not exhibit isotopic anomalies characteristic of refractory inclusions. The significant difference in the degree of CAI signatures between OC ARCs and CV ARCs suggests that CAIs were trapped between the accretion regions of NC and CC parent bodies, leading to an isotopic dichotomy based on the presence or absence of isotopically anomalous CAIs. Meanwhile, fine dust grains with NC or CI isotopic compositions, which are smaller in size than CAIs, were distributed extensively in NC and CC accretion regions, resulting in continuous variations in chondrule isotopic composition.

Impact provenance and age of a unique basalt found in Apollo 12 regolith

1,2C. Deligny,1M. J. Whitehouse,3R. E. Merle,1H. Jeon,4,5A. A. Nemchin,6B. L. Jolliff
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70204]
1Department of Geosciences, Swedish Museum of Natural History, Stockholm, Sweden
2School of Physical Sciences, The Open University, Milton Keynes, UK
3Department of Earth Sciences, Uppsala University, Uppsala, Sweden
4School of Earth and Planetary Sciences, Curtin University, Perth, Australia
5School of Earth Sciences and Engineering, Nanjing University, Nanjing, China
6Department of Earth, Environmental, and Planetary Sciences and the McDonnell Center for the Space Sciences, WashingtonUniversity in St. Louis, St. Louis, Missouri, USA
Published by arrangement with John Wiley & Sons

Basaltic sample 12032,366-18 from the Apollo 12 landing site is distinct among basalts collected at this site, other Apollo landing sites, and lunar meteorites in terms of its age, bulk rock composition, and isotopic composition. We present new Pb isotopic data obtained by in situ Secondary Ion Mass Spectrometry on multiple mineral phases in 12032,366–18. These data yield a crystallization age of 3400 ± 16 Ma, older than other Apollo 12 basalts, which crystallized between ~3.1 and 3.3 Ga. The initial Pb isotopic composition plots slightly below the mixing line between KREEP (an incompatible-element-rich lunar reservoir enriched in K, rare Earth elements, and P) and a depleted lunar mantle reservoir with low-μ (μ = 238U/204Pb) value. The bulk composition is characterized by elevated incompatible trace element abundances, including high thorium (~7 ppm), relatively high FeO, and intermediate Ti contents, distinguishing it from other Apollo 12 and lunar basalts. Although it shares some affinities with Apollo KREEP basalts, its higher bulk rock Al2O3 content and the presence of olivine are more consistent with high-Al basalts. Together, 12032,366–18 is not indigenous to the Apollo 12 landing site but instead represents material transported from a distant source region, most plausibly within western Oceanus Procellarum, potentially linked to the Kepler impact crater region.

Nanoscale space weathering features in mature lunar soil revealed by TEM and APT

1,2Jennika Greer,3Alexander M. Kling,4,5,6Luke Daly,7,8Dieter Isheim,7,8David N. Seidman,3Michelle S. Thompson,2,9Philipp R. Heck
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70196]
1Division of Microstructure Physics, Chalmers University of Technology, Göteborg, Sweden
2Robert A. Pritzker Center for Meteoritics and Polar Studies, Negaunee Integrative Research Center, Field Museum of NaturalHistory, Chicago, Illinois, USA
3Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, Indiana, USA
4School of Geographical & Earth Sciences, University of Glasgow, Glasgow, UK
5Australian Centre for Microscopy and Microanalysis, The University of Sydney, Sydney, New South Wales, Australia
6Department of Materials, University of Oxford, Oxford, UK
7Department of Materials Science and Engineering, Northwestern University, Evanston, Illinois, USA
8Northwestern University Center for Atom Probe Tomography, Northwestern University, Evanston, Illinois, USA
9Department of the Geophysical Sciences, University of Chicago, Chicago, Illinois, USA
Published by arrangement with John Wile & Sons

Space weathering significantly alters the optical, chemical, and structural properties of lunar regolith at micro- and nanoscales; yet detailed nanoscale variability within individual soils remains underexplored. Here we apply transmission electron microscopy (TEM) and atom probe tomography to four mineral grains (olivine, ilmenite, and two agglutinitic grains) from mature Apollo 17 soil 79221, characterizing solar wind-induced damage, vesiculation, nanophase Fe formation, and volatile retention with nanometer resolution. Our analyses reveal pronounced heterogeneity in vesicle morphology, nanophase Fe abundance, and volatile content that varies with mineralogy and exposure history. Oxygen depletion near grain surfaces indicates sputtering effects. Beyond confirming nanoscale heterogeneity, our coordinated analyses resolve, by APT, the Fe-depleted halos around npFe0 in mature ilmenite that we previously documented with the same technique in submature Apollo 17 ilmenite. We identify impact-melt quench textures that contribute non-weathering npFe0 to agglutinitic grains, and find a thick damage rim with few npFe0 in Mg-rich olivine accumulates. TEM observations of elongated, linear vesicles aligned parallel to ilmenite blade margins within a bladed agglutinitic grain further suggest crystallographic rather than directional control of vesicles in ilmenite inclusions. We also establish that vesicles distort APT reconstructions and degas during field evaporation, complicating quantitative inventories of npFe0 and volatiles in space-weathered grains.

Colomeraite, NaTi3+Si2O6, a new clinopyroxene mineral from the Colomera iron meteorite

1Chi Ma,2,3Alan E. Rubin
American Mineralogist 111, 1186-1191 Link to Article [https://doi.org/10.2138/am-2025-10003]
1Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A.
2Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, California 90095, U.S.A.
3Maine Mineral & Gem Museum, 99 Main Street, P.O. Box 500, Bethel, Maine 04217, U.S.A.
Copyright: The Mineralogical Society of America

Colomeraite (IMA 2021-061), with an end-member formula NaTi3+Si2O6, is a new Na pyroxene identified in the Colomera IIE iron meteorite. Colomeraite occurs with albite and K-feldspar in a silicate inclusion. The mean chemical composition of type colomeraite by electron probe microanalysis is (wt%) SiO2 54.82, Ti2O3 17.15, TiO2 5.58, NaO2 12.33, MgO 3.93, FeO 3.59, CaO 1.98, MnO 0.28, Al2O3 0.24, Cr2O3 0.13, K2O 0.02, total 100.05, giving rise to an empirical formula of (Na0.88Ca0.08Mg0.04)(⁠Mg0.17Fe0.11Mn0.01Al0.01)Si2.01O6, with Ti3+ and Ti4+ partitioned, based on stoichiometry. Colomeraite has the C2/c diopside-type structure with a = 9.70(1) Å, b = 8.88(1) Å, c = 5.30(1) Å, β = 106.8(1)°, V = 437(2) Å3, and Z = 4, as revealed by electron backscatter diffraction. The calculated density using the measured composition is 3.36 g/cm3. Colomeraite is a high-pressure and high-temperature Na-Ti3+-pyroxene, probably formed from an alkali plagioclase-Ti-rich phase melt via impact mixing of metal and silicates under extremely reducing conditions. The mineral is named after the host meteorite “Colomera.”

Impact-induced nano-sized rare mineral kuratite with correlated disorder on near and far sides of the Moon using 3DED method

1,2,3Yiping Yang et al. (>10)
American Mineralogist 111, 1036-1045 Link to Article [https://doi.org/10.2138/am-2025-9674]
1Key Laboratory for Deep Earth Processes and Strategic Mineral Resources, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
2Center for Advanced Planetary Science (CAPS), Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
3Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China
Copyright: The Mineralogical Society of America

Mineral structures record the formation and evolution of the Earth-Moon system. Here we report the discovery of correlated disorder in a silicate mineral kuratite [ideal formula ], which cannot be well documented by classical crystallography, in breccia clasts from near and far sides of the Moon. We employed the advanced three-dimensional electron diffraction (3DED) method in combination with spherical aberration corrected transmission electron microscopy to thoroughly characterize its structural features. The results indicate that the kuratite, coexisting with dendritic pigeonite and ulvöspinel, displays intricate correlated disorder features. These are characterized by alternating arrangements of five correlated site pairs confined within a single disordered layer. The occurrence of a vitrified dendritic pigeonite with similar composition suggests that kuratite formed during the impact-induced melting-cooling processes. This finding shows consistency in impact-driven surface processes between the lunar near and far sides, while demonstrating the utility of advanced nanoscale crystallographic methods for decoding extraterrestrial mineral formation mechanisms.