1Shu-Zhou Wang, 1Ai-Cheng Zhang, 1Tian-Ran Du, 1Jia-Ni Chen, 2Yuan-Yun Wen
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.70256]
1State Key Laboratory for Critical Earth Material Cycling and Mineral Deposits, School of Earth Sciences and Engineering, Nanjing University, Nanjing, China
2Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China
Published by arrangement with John Wiley & Sons
Yamato-type (CY) carbonaceous chondrites are a group of meteorites that experienced both intense aqueous alteration and subsequent dehydration. They consist of a few CY1 and CY2 samples; however, their nature and genetic relationship remains an issue of debate. Here, we report the detailed petrography and mineralogy of four sections of Dhofar 1988, a newly proposed CY chondrite. We find that Dhofar 1988 is a dimict breccia, containing a CY2-like host region (~73 area%) and numerous CY1-like dark clasts (~27 area%). Using Ti-minerals as a clue, we identified 14 calcium-aluminum-rich inclusions (CAIs) (including an Al-rich chondrule containing CAI material, with most of the CAIs present in the host region, ~1 area%) and only one CAI in dark clasts (~0.04 area%). These CAIs contain a series of Ti-minerals, including primary perovskite, Ti-rich fassaite, Ti-rich hibonite, and probably ilmenite–rutile assemblage, and secondary ilmenite, anatase, rutile, zirconolite (ideal formula CaZrTi2O7), and perovskite. Formation of the secondary Ti-minerals involves: (1) replacement of Ti-rich fassaite by melilite-like phase, perovskite, and minor spinel; (2) subsolidus breakdown of potential armalcolite to ilmenite and rutile and minor spinel and zirconolite; (3) alteration of perovskite to ilmenite; (4) alteration of perovskite to anatase; (5) alteration of fassaite to phyllosilicate and ilmenite; and (6) transition from ilmenite to perovskite. They probably formed during pre-alteration metamorphism (1 and 2), intense aqueous alteration (3–5), and postalteration metamorphism (6), respectively, and reflect the evolution of temperature and water/rock ratio. The similarity between the two components in Dhofar 1988 and the CY1 and CY2 samples indicates that the material from CY1 and CY2 samples was once mixed with each other through collision-induced mixing or during initial planetesimal accretion.