Clay sediments derived from fluvial activity in and around Ladon basin, Mars

1Catherine M.Weitz,2Janice L.Bishop,3John A.Grant,3Sharon A.Wilson,3Rossman P.IrwinIII,4Arun M.Saranathan,4Yuki Itoh,4Mario Parente
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2022.115090]
1Planetary Science Institute, 1700 E Fort Lowell, Tucson, AZ 85719, USA
2SETI Institute, Carl Sagan Center, 339 Bernardo Ave., Mountain View, CA 94043, USA
3Center for Earth and Planetary Studies, National Air and Space Museum, Smithsonian Institution, 6th at Independence SW, Washington, DC 20560, United States of America
4University of Massachusetts Amherst, Dept. Electrical & Computer Engineering, 151 Holdsworth Way, Amherst, MA 01003, United States of America
Coypright Elsevier

The morphology and mineralogy of light-toned layered sedimentary deposits were investigated using multiple orbital datasets across the Ladon basin region, including within northern Ladon Valles, southern Ladon basin, and the southwestern highlands of Ladon basin. Light-toned layered deposits are particularly widespread in Ladon Valles and Ladon basin, ranging laterally for distances over 200 km, with the thickest exposure (54 m) located at the mouth of Ladon Valles. The restriction of layered sediments below a common elevation (−1850 m) in Ladon Valles and Ladon basin and their broad conformable distribution with bedding dips between 1 and 4° favor a lacustrine environment within this region during the Late Noachian to Early Hesperian. The Ladon layered deposits have spectral signatures consistent with Mg-smectites, even when the morphology of the layering varies considerably in color and brightness. These phyllosilicates were most likely eroded from the highlands upstream to the south, but the lacustrine environment may have also been favorable for in situ alteration and formation of clays. The southwestern highlands also display light-toned layered deposits within valleys and small basins. These sediments predominantly have signatures of Mg-smectites, although we also identified Fe/Mg-smectites and additional hydrated phases in some deposits. One of these altered deposits was found within a younger Holden crater secondary chain, possessing a Late Hesperian to Early Amazonian age for valleys and sediments that postdate the deposits within Ladon Valles and Ladon basin. Phyllosilicate signatures were also detected in the ejecta from two fresh craters that exposed highland materials upstream of Arda Valles, revealing that the highlands are clay-bearing and may be the most plausible source of the clay-bearing fluvial-derived sediments found within the valleys and basins downstream. Some of the highland deposits are likely coeval to similar clay-bearing sediments found to the south within Holden and Eberswalde craters, indicating late, widespread fluvial activity and deposition of allochthonous clays within the broader Margaritifer Terra region when Mars was thought to be colder and drier.

Formation and decomposition of vacancy-rich clinopyroxene in a shocked eucrite: New insights for multiple impact events

1,2Ai-Cheng Zhang,1Jie-Ya Li,1Jia-Ni Chen,3Yuan-Yun Wen,4Yan-Jun Guo,2,3Yang Li,5Naoya Sakamoto,5,6Hisayoshi Yurimoto
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2022.05.017]
1State Key Laboratory for Mineral Deposits Research, School of Earth Science and Engineering, Nanjing University, Nanjing 210023, China
2CAS Center for Excellence in Comparative Planetary, Hefei 230026, China
3Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
4CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, China
5Isotope Imaging Laboratory, Creative Research Institution, Hokkaido University, Sapporo 010-0021, Japan
6Department of Natural History Sciences, Hokkaido University, Sapporo 060-0810, Japan
Copyright Elsevier

Impact is a fundamental process shaping the formation and evolution of planets and asteroids. It is inevitable that some materials on the surface of planets and asteroids have been impacted for many times. However, unambiguous petrological records for multiple post-formation impact events are rarely described. Here, we report that the thin shock melt veins of the shocked eucrite Northwest Africa 8647 are dominated by a fine-grained intergranular or vermicular pigeonite and anorthite assemblage, rather than compact vacancy-rich clinopyroxene. Vacancy-rich clinopyroxene in the veins instead is ubiquitous as irregularly-shaped, relict grains surrounded by intergranular or vermicular pigeonite and anorthite assemblage. The silica fragments entrained in shock melt veins contain a coesite core and a quartz rim. The occurrences of vacancy-rich clinopyroxene and coesite can be best explained by two impact events. The first impact event produced the shock melt veins and lead to the formation of vacancy-rich clinopyroxene and coesite. The second impact event heated the fine-grained melt veins and lead to the widespread partial decomposition of vacancy-rich clinopyroxene and the partial back-transformation of coesite. This paper is the first report of the decomposition reaction of shock-induced vacancy-rich clinopyroxene in extraterrestrial materials. We propose that widespread decomposition and/or back-transformation of high-pressure minerals in shocked meteorites can be considered as important records of multiple impact events.

Shock recovery with decaying compressive pulses: Shock effects in calcite (CaCO3) around the Hugoniot elastic limit

1Kosuke Kurosawa et al. (>10)
Journal of Geophysical Research (Planets)(in Press) Link to Article [https://doi.org/10.1029/2021JE007133]
1Planetary Exploration Research Center, Chiba Institute of Technology, 2-17-1, Tsudanuma, Narashino, Chiba, 275-0016 Japan
Published by arrangement with John Wiley & Sons

Shock metamorphism of minerals in meteorites provides insights into the ancient Solar System. Calcite is an abundant aqueous alteration mineral in carbonaceous chondrites. Return samples from the asteroids Ryugu and Bennu are expected to contain calcite-group minerals. Although shock metamorphism in silicates has been well studied, such data for aqueous alteration minerals are limited. Here, we investigated the shock effects in calcite with marble using impact experiments at the Planetary Exploration Research Center of Chiba Institute of Technology. We produced decaying compressive pulses with a smaller projectile than the target. A metal container facilitates recovery of a sample that retains its pre-impact stratigraphy. We estimated the peak pressure distributions in the samples with the iSALE shock physics code. The capability of this method to produce shocked grains that have experienced different degrees of metamorphism from a single experiment is an advantage over conventional uniaxial shock recovery experiments. The shocked samples were investigated by polarizing microscopy and X-ray diffraction analysis. We found that more than half of calcite grains exhibit undulatory extinction when peak pressure exceeds 3 GPa. This shock pressure is one order of magnitude higher than the Hugoniot elastic limit (HEL) of marble, but it is close to the HEL of a calcite crystal, suggesting that the undulatory extinction records dislocation-induced plastic deformation in the crystal. Finally, we propose a strategy to re-construct the maximum depth of calcite grains in a meteorite parent body, if shocked calcite grains are identified in chondrites and/or return samples from Ryugu and Bennu.

The Heterogeneous Surface of Asteroid (16) Psyche

1Saverio Cambioni,2Katherine de Kleer,3Michael Shepard
Journal of Geophysical Research (Planets) (in Press) Open Access Link to Article [https://doi.org/10.1029/2021JE007091]
1Department of Earth, Atmospheric & Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA, USA
2Division of Geological & Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
3Department of Environmental, Geographical & Geological Sciences, Bloomsburg University, Bloomsburg, PA, USA
Published by arrangement with John Wiley & Sons

Main-belt asteroid (16) Psyche is the largest M-type asteroid, a class of object classically thought to be the metal cores of differentiated planetesimals and the parent bodies of the iron meteorites. de Kleer, Cambioni, and Shepard (2021) presented new data from the Atacama Large Millimiter Array (ALMA), from which they derived a global best-fit thermal inertia and dielectric constant for Psyche, proxies for regolith particle size, porosity, and/or metal content, and observed thermal anomalies that could not be explained by surface albedo variations only. Motivated by this, here we fit a model to the same ALMA dataset that allows dielectric constant and thermal inertia to vary across the surface. We find that Psyche has a heterogeneous surface in both dielectric constant and thermal inertia but, intriguingly, we do not observe a direct correlation between these two properties over the surface. We explain the heterogeneity in dielectric constant as being due to variations in the relative abundance of metal and silicates. Furthermore, we observe that the lowlands of a large depression in Psyche’s shape have distinctly lower thermal inertia than the surrounding highlands. We propose that the latter could be explained by a thin mantle of fine regolith, fractured bedrock, and/or implanted silicate-rich materials covering an otherwise metal-rich surface. All these scenarios are indicative of a collisionally evolved world.

Novel extraction protocol for evaluating abundances and structural features of amorphous SiO2

1Aditi Pandey,2Monique Nguyen-Vu,1Paul Schwab
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2022.115096]
1Department of Soil and Crop Sciences, Texas A&M University, College Station, TX 77843, United States of America
2Department of Biology, Texas A&M University, College Station, TX 77843, United States of America
Copyright Elsevier

Spectral data from satellite and rover missions on Mars identified significant abundances of amorphous phases in most samples analyzed, and SiO2 is the principal amorphous constituent in the Gale crater. Identifying and quantifying these short-range ordered, highly reactive phases is challenging but necessary to gain insight into the evolution of these materials. Terrestrial analogs are frequently employed to allow detailed analyses that cannot be performed on Martian samples. Historically, chemical extraction techniques have been extensively used to characterize amorphous materials in terrestrial soils, but most automated systems are complex, expensive, and limited to analyzing a single sample at one time. This study aims to develop a cost-effective apparatus that will allow latitude in choosing an extractant, process several samples simultaneously, enable rapid sampling over time without interruption and provide the resolution for quantitative differentiation of rapidly dissolving SiO2(a) phases in natural samples. Dissolution rates as a function of time were used as input for kinetic models to estimate the abundances of amorphous phases. When 2 M Na2CO3 is used as the extractant, dissolution rates differ significantly between secondary phases such as opal and primary glass phases. A stronger base, NaOH, is necessary for the complete dissolution of basaltic glass. Palagonitic tuffs from Iceland (proposed analogs of Martian soils) with >90% (w/w) amorphous composition were analyzed with 2 M Na2CO3 in the proposed apparatus, and both primary glass and secondary SiO2 appear to be present. Using the kinetic model of the dissolution, the palagonitic tuff has a composition of approximately 25% (w/w) of a rapidly reacting amorphous phase and 13% (w/w) of the slower reacting glass-like phase. The proposed high-efficiency analytical method can be applied to screen through multiple terrestrial analogs and archive dissolution kinetics of many standard amorphous minerals. Although this paper focuses on extracting SiO2 (a), the same setup can be applied to study time-based dissolution reactions using other extractants such as ammonium oxalate oxalic acid.

Negative polarization of light at backscattering from a numerical analog of planetary regoliths

1Yevgen Grynko,2Yuriy Shkuratov,1Samer Alhaddad,1Jens Förstner
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2022.115099]
1Department of Theoretical Electrical Engineering, Paderborn University, Warburger Str. 100, 33102 Paderborn, Germany
1Institute of Astronomy of Kharkiv National University, Sumska Str. 35, 61022 Kharkiv, Ukraine
Copyright Elsevier

We model negative polarization, which is observed for planetary regoliths at backscattering, solving a full wave problem of light scattering with a numerically exact Discontinuous Galerkin Time Domain (DGTD) method. Pieces of layers with the bulk packing density of particles close to 0.5 are used. The model particles are highly absorbing and have irregular shapes and sizes larger than the wavelength of light. This represents a realistic analog of low-albedo planetary regoliths. Our simulations confirm coherent backscattering mechanism of the origin of negative polarization. We show that angular profiles of polarization are stabilized if the number of particles in a layer piece becomes larger than ten. This allows application of our approach to the negative polarization modeling for planetary regoliths.

Constraints on the emplacement of Martian nakhlite igneous rocks and their source volcano from advanced micro-petrofabric analysis

1S.Griffin et al. (>10)
Journal of Geophysical Research (Planets)(in Press) Open Access Link to Article [https://doi.org/10.1029/2021JE007080]
1School of Geographical and Earth Sciences, University of Glasgow, Glasgow, UK
Published by arrangement with John Wiley & Sons

The Martian nakhlite meteorites, which represent multiple events that belong to a single magma source region represent a key opportunity to study the evolution of Martian petrogenesis. Here 16 of the 26 identified nakhlite specimens are studied using coupled electron backscatter diffraction (EBSD) and emplacement end-member calculations. EBSD was used to determine shape preferred orientation (SPO) of contained augite (high Ca-clinopyroxene) phenocrysts by considering their crystallographic preferred orientation (CPO). Parameters derived from EBSD, and energy dispersive X-ray spectroscopy (EDS) data were used in basic emplacement models to assess their dominant mechanism against three end-member scenarios: thermal diffusion, crystal settling, and crystal convection. Results from CPO analyses indicate low intensity weak-moderate CPO. In all samples, a consistent foliation within the <001> axes of augite are observed typically coupled with a weaker lineation CPO in one of the other crystallographic axes. These CPO results agree best with crystal settling being the dominant emplacement mechanism for the nakhlites. Modelled crystal settling results identify two distinguishable groups outside of the model’s resolution indicating the presence of secondary emplacement mechanisms. Comparison of the two identified groups against petrofabric, geochemical, and age parameters indicate random variability between individual meteorites. Therefore, coupled petrofabric and emplacement modelling results identify an overarching characteristic of a dominant crystal settling emplacement mechanism for the nakhlite source volcano despite exhibiting random variation with each discharge through time.

Oxidized and reduced sulfur observed by the Sample Analysis at Mars (SAM) instrument suite on the Curiosity rover within the Glen Torridon region at Gale crater, Mars

1G.M.Wong et al. (>10)
Journal of Geophysical Research (Planets)(In Press) Open Access Link to Article [https://doi.org/10.1029/2021JE007084]
1Department of Geosciences, The Pennsylvania State University, University Park, PA, USA
Published by arrangement with John Wiley & Sons

The Mars Science Laboratory (MSL) Curiosity rover has been assessing the habitability and geologic history of Gale crater, Mars since landing in 2012. One of the primary objectives of the mission was to investigate a clay-bearing unit identified using orbital spectral data, designated the Glen Torridon (GT) region. This region was of particular interest because of its elevated abundance of clay minerals that may have preserved geochemical evidence of ancient habitable environments. The Curiosity rover explored the GT region for ∼750 sols and analyzed eight drilled samples with the Sample Analysis at Mars (SAM) instrument suite using evolved gas analysis-mass spectrometry. Evolved sulfur-bearing gases provided insight about the composition of sulfur-containing compounds in Martian samples. Evolved gases were analyzed by three methods to understand the oxidation state of sulfur in the samples: (1) SO2 evolution temperature, (2) quadratic discriminant analysis comparing SAM data to SAM-like laboratory investigations, and (3) sulfur isotope values from evolved 34SO2/32SO2. The results of these three methods were consistent with the majority of sulfur in the GT region being in an oxidized state, but two of the eight samples analyzed by SAM were consistent with the presence of small amounts of reduced sulfur. The oxidized and reduced sulfur could have a variety of sources and represents a nonequilibrium assemblage that could have supported putative ancient chemolithotrophic metabolisms.

The noble gas inventory in metal samples and troilite inclusions from IIIAB iron meteorites: Reinvestigating the live 129I-129Xe dating method

1,2Thomas Smith,1Ingo Leya
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13827]
1Physics Institute, University of Bern, Sidlerstrasse 5, Bern, CH-3012 Switzerland
2State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, 19 Beitucheng Western Road, Chaoyang District, Box 9825, Beijing, 100029 China
Published by arrangement with John Wiley & Sons

The live 129I-129Xe dating technique, which internally corrects for shielding, is particularly well suited for large iron meteorites, for which shielding corrections might be difficult to obtain. In addition, the half-life of 129I of 16 Ma would allow the study of the important question of the constancy—or variability—of the galactic cosmic rays over a time scale not covered by other cosmogenic nuclides. Here, we present the results of a noble gas study of metal samples and adjacent troilite inclusions from the four IIIAB iron meteorites Cape York (including Agpalilik), Casas Grandes, Trenton, and Grant. The major result is that we can directly determine 129Xenc concentrations caused by (live) 129I decay for Cape York, Casas Grandes, Trenton, and Grant. The 129Xenc concentrations can be used, if combined to 129I activity concentrations (not measured by us), to calculate cosmic ray exposure (CRE) ages using the (live) 129I-129Xe chronometer. For the light noble gases measured in metal and troilite samples, the new data confirm the earlier estimates of a production rate ratio 21Necos(troilite)/21Necos(metal) in the range 3.08–3.53. Surprisingly, 38Arcos in troilite from Agpalilik and Casas Grandes is only, respectively, ~36% and ~44% relative to that in the respective metal phases. Considering that 38Arcos is only produced from iron but not from sulfur, the 38Arcos concentration measured in troilite is expected to be ~64% relative to that in adjacent metal, that is, some 38Arcos is missing. Considering krypton in troilite, only 80Kr, 82Kr, and 83Kr are higher than the blank, likely indicating a spallogenic contribution. On average, ~4.2% of measured 80Kr, ~2.5% of 82Kr, and ~11.6% of 83Kr are spallogenic.