Back-transformation of high-pressure minerals in shocked chondrites: low-pressure mineral evidence for strong shock

1Jinping Hu,1Thomas G. Sharp
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2017.07.018]
1School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85287-1404, USA
Copyright Elsevier

Post-shock annealing of meteorites can destroy their shock-induced features, particularly high-pressure minerals, and complicate the estimation of impact pressure-temperature conditions. However, distinguishing post-shock annealing features from thermal metamorphism effects can be practically difficult. Here we report results from Mbale, a highly shocked L chondrite, to investigate the mechanisms, kinetics and identification criteria for post-shock annealing of high-pressure signatures. Olivine fragments within shock-melt veins in Mbale occur as chemically heterogeneous nanocrystalline aggregates that contain trace wadsleyite and ringwoodite. Their strong variation in fayalite content provides evidence of iron partitioning during transformation of olivine to wadsleyite, followed by back-transformation to olivine after decompression. Experimental studies of transformation kinetics show that wadsleyite transforms to olivine in seconds at temperatures above ∼1200 K and in hours at temperatures between 900 and 1200 K. Thermal models of shock-melt cooling show that shock veins in Mbale cooled to 1200 K in 1 s. The shock pulse must have been shorter than ∼1 s to provide the high temperature conditions for post-shock back-transformation of wadsleyite. Many highly shocked L chondrites, which have abundant high-pressure minerals, must have experienced relatively long shock durations combined with rapid cooling of shock-melt regions to preserve high-pressure phases. The most highly shocked samples, such as impact melt breccias, lack high-pressure phases because of post-shock back-transformations.

Spectral and rotational properties of near-Earth asteroid (162173) Ryugu, target of the Hayabusa2 sample return mission

1D.Perna et al. (>10)*
Astronomy & Astrophysics 599, L1 Link to Article [https://doi.org/10.1051/0004-6361/201630346]
1LESIA – Observatoire de Paris, PSL Research University, CNRS, Sorbonne Universités, UPMC Univ. Paris 06, Univ. Paris Diderot, Sorbonne Paris Cité, 5 place Jules Janssen, 92195 Meudon, France
*Find the extensive, full author and affiliation list on the publishers website

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Optical spectroscopic characterizations of laser irradiated olivine grains

1Yazhou Yang (杨亚洲), 1,2Hao Zhang (张昊), 1Ziwei Wang (王紫薇), 1Ye Yuan (袁野), 3Shaolin Li (李少林), 3Weibiao Hsu (徐伟彪), 4Chujian Liu (刘初见)
Astronomy & Astrophysics 597, A50 Link to Article [https://doi.org/10.1051/0004-6361/201629327]
1Planetary Science Institute, School of Earth Sciences, China University of Geosciences, Wuhan 430074, PR China
e-mail: um_zhanghao@yahoo.com; yangyazhou1@gmail.com
2Key Laboratory of Spectral Imaging Technology, Xi’an Institute of Optics and Precision Mechanics, Chinese Academy of Sciences, Xi’an 710119, PR China
3Purple Mountain Observatory, Chinese Academy of Sciences, Nanjing, PR China
4State Key Laboratory of Geological Process and Mineral Resources, China University of Geosciences, Wuhan, PR China

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Mid-IR water and silicate relation in protoplanetary disks

1S. Antonellini, 1J. Bremer, 1I. Kamp, 2P. Riviere-Marichalar, 1,3F. Lahuis, 4W.-F. Thi, 5P. Woitke, 6R. Meijerink, 1,7G. Aresu, 1M. Spaans
Astronomy&Astrophysics 597, A72 Link to Article [https://doi.org/10.1051/0004-6361/201527820]
1Kapteyn Astronomical Institute, Postbus 800, 9700 AV Groningen, The Netherlands
e-mail: antonellini@astro.rug.nl
2Centro de Astrobiología (INTA-CSIC) – Depto. Astrofísica, POB 78, ESAC Campus, 28691 Villanueva de la Cañada, Spain
3SRON Netherlands Institute for Space Research, PO Box 800, 9700 AV Groningen, The Netherlands
4Max-Planck-Institut für extraterrestrische Physisk, Giessenbachstrasse 1, 85748 Garching, Germany
5St. Andrews University, School of Physics and Astronomy, St. Andrews KY16 9SS, UK
6Leiden Observatory, Leiden University, PO Box, 2300 RA Leiden, The Netherlands
7INAF–Osservatorio Astronomico di Cagliari, via della Scienza 5, 09047 Selargius, Italy

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Stellar Origin of 15N-rich Presolar SiC Grains of Type AB: Supernovae with Explosive Hydrogen Burning

1Nan Liu, 1Larry R. Nittler, 2,3Marco Pignatari, 1Conel M. O’D. Alexander, 1Jianhua Wang
The Astrophysical Journal Letters 842 L1 Link to Article [https://doi.org/10.3847/2041-8213/aa74e5]
1Department of Terrestrial Magnetism, Carnegie Institution for Science, Washington, DC 20015, USA
2E. A. Milne Centre for Astrophysics, Department of Physics & Mathematics, University of Hull, Hull HU6 7RX, UK
3NuGrid collaboration, http://www.nugridstars.org.

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Mixing and Transport of Dust in the Early Solar Nebula as Inferred from Titanium Isotope Variations among Chondrules

1Simone Gerber, 1Christoph Burkhardt, 1Gerrit Budde, 1Knut Metzler, 1Thorsten Kleine
The Astrophysical Journal Letters 841, L17 Link to Article [https://doi.org/10.3847/2041-8213/aa72a2]
1Institut für Planetologie, University of Münster, Wilhelm Klemm-Straße 10, D-48149 Münster, Germany

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Alternative Energy: Production of H2 by Radiolysis of Water in the Rocky Cores of Icy Bodies

1,2Alexis Bouquet, 2Christopher R. Glein, 2Danielle Wyrick, 1,2J. Hunter Waite
The Astrophysical Journal Letters 840 L8, Link to Article [https://doi.org/10.3847/2041-8213/aa6d56]
1Department of Physics and Astronomy, University of Texas at San Antonio, San Antonio, TX, USA
2Southwest Research Institute, Space Science and Engineering Division, San Antonio, TX, USA

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The Chemical Composition of an Extrasolar Kuiper-Belt-Object

1S. Xu (许偲艺), 2B. Zuckerman, 3P. Dufour, 4E. D. Young, 2B. Klein, 2M. Jura
The Astrophysical Journal 836, L7 Link to Article [https://doi.org/10.3847/2041-8213/836/1/L7]
1European Southern Observatory, Karl-Schwarzschild-Straße 2, D-85748 Garching, Germany
2Department of Physics and Astronomy, University of California, Los Angeles, CA 90095-1562, USA
3Institut de Recherche sur les Exoplanètes (iREx) and Département de physique, Université de Montréal, Montréal, QC H3C 3J7, Canada
4Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, CA 90095, USA

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A SOFIA FORCAST Grism Study of the Mineralogy of Dust in the Winds of Proto-planetary Nebulae: RV Tauri Stars and SRd Variables

1R.A.Arneson et al. (>10)*
The Astrophysical Journal 843, 51 Link to Article [https://doi.org/10.3847/1538-4357/aa75cf]
1Minnesota Institute for Astrophysics, School of Physics and Astronomy, University of Minnesota, 106 Pleasant Street S.E., Minneapolis, MN 55455, USA
*Find the extensive, full author and affiliation list on the publishers website

We present a SOFIA FORCAST grism spectroscopic survey to examine the mineralogy of the circumstellar dust in a sample of post-asymptotic giant branch (post-AGB) yellow supergiants that are believed to be the precursors of planetary nebulae. Our mineralogical model of each star indicates the presence of both carbon-rich and oxygen-rich dust species—contrary to simple dredge-up models—with a majority of the dust in the form of amorphous carbon and graphite. The oxygen-rich dust is primarily in the form of amorphous silicates. The spectra do not exhibit any prominent crystalline silicate emission features. For most of the systems, our analysis suggests that the grains are relatively large and have undergone significant processing, supporting the hypothesis that the dust is confined to a Keplerian disk and that we are viewing the heavily processed, central regions of the disk from a nearly face-on orientation. These results help to determine the physical properties of the post-AGB circumstellar environment and to constrain models of post-AGB mass loss and planetary nebula formation.

Nucleation of Small Silicon Carbide Dust Clusters in AGB Stars

1,4David Gobrecht, 1Sergio Cristallo, 1Luciano Piersanti, 2,3Stefan T. Bromley
The Astrophysical Journal 840, 2 Link to Article [https://doi.org/10.3847/1538-4357/aa6db0]
1Osservatorio Astronomico di Teramo, INAF, I-64100 Teramo, Italy
2Departament de Cincia de Materials i Química Fisica and Institut de Química Terica i Computacional (IQTCUB),Universitat de Barcelona, E-08028 Barcelona, Spain
3Institucio Catalana de Recerca i Estudis Avancats (ICREA), E-08010 Barcelona, Spain
4Instituut voor Sterrenkunde, Celestijnenlaan 200 D, B-3001 Heverlee (Leuven), Belgium

Silicon carbide (SiC) grains are a major dust component in carbon-rich asymptotic giant branch stars. However, the formation pathways of these grains are not fully understood. We calculate ground states and energetically low-lying structures of (SiC) n , n = 1, 16 clusters by means of simulated annealing and Monte Carlo simulations of seed structures and subsequent quantum-mechanical calculations on the density functional level of theory. We derive the infrared (IR) spectra of these clusters and compare the IR signatures to observational and laboratory data. According to energetic considerations, we evaluate the viability of SiC cluster growth at several densities and temperatures, characterizing various locations and evolutionary states in circumstellar envelopes. We discover new, energetically low-lying structures for Si4C4, Si5C5, Si15C15, and Si16C16 and new ground states for Si10C10 and Si15C15. The clusters with carbon-segregated substructures tend to be more stable by 4–9 eV than their bulk-like isomers with alternating Si–C bonds. However, we find ground states with cage geometries resembling buckminsterfullerens (“bucky-like”) for Si12C12 and Si16C16 and low-lying stable cage structures for n ≥ 12. The latter findings thus indicate a regime of cluster sizes that differ from small clusters as well as from large-scale crystals. Thus—and owing to their stability and geometry—the latter clusters may mark a transition from a quantum-confined cluster regime to a crystalline, solid bulk-material. The calculated vibrational IR spectra of the ground-state SiC clusters show significant emission. They include the 10–13 μm wavelength range and the 11.3 μm feature inferred from laboratory measurements and observations, respectively, although the overall intensities are rather low.