Zixu Zhao, Jian Chen, Zongcheng Ling, Xuejin Lu, Zexi Li
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2023.115531]
Shandong Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment, Institute of Space Sciences, School of Space Science and Physics, Shandong University, Weihai 264209, China
Copyright Elsevier

The timeline of volcanic activity is critical for constraining the thermal evolution of the Moon. The spatial extents of mare basalts, major products of lunar volcanism, have been precisely extracted from LROC (Lunar Reconnaissance Orbiter Camera) image mosaics. With the maria extents newly extracted from LROC mosaics, we found that a large area of mare basalts in the junction of Oceanus Procellarum, Mare Imbrium, Mare Insularum, and Mare Vaporum (the PIV region) has not yet been dated. This study analysed the chronology, composition, and mineralogy of the PIV region, aiming to finish the picture of basaltic volcanism in the Procellarum region, which is a key puzzle of our global geological mapping of the Moon. According to the topographical, spectral, and compositional characteristics, mare units of the PIV region are defined, and the crater size frequency distribution is measured. The primary craters with diameters >0.1 km in the PIV region are measured, and the absolute model ages of basalt units between ~3.78 Ga and ~ 1.71 Ga are derived. Most western PIV basalt units are Eratosthenian-aged, while eastern units mostly formed in the Imbrian period. The spectra of 4965 small impact craters are extracted to interpret the mineral compositions of the PIV basalt units using Chandrayaan-1 Moon Mineralogy Mapper data. Using a Modified Gaussian Model, the reflectance spectra are deconvoluted, and the obtained modal proportions of mafic minerals show low olivine and high low-Ca pyroxene abundances in the eastern PIV region, while the western region features high olivine and calcic pyroxene concentrations. Three episodes of volcanic events occurring in the PIV region are identified. The first (main) occurred at approximately 3.5 Ga (Late Imbrian), with erupted lava flows with less evolved compositions covering most of the PIV area. The peak of volcanic activity in the Eratosthenian period occurred around 2.5 Ga, where mare basalts with moderately evolved compositions and mineralogy were formed. The last major eruption occurred at approximately 1.8 Ga, forming mare basalts with highly evolved compositions.

¹Shaofan Che, ¹Kenneth J. Domanik, ^1,2Thomas J. Zega
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2023.03.010]
¹Lunar and Planetary Laboratory, University of Arizona, Tucson AZ
²Department of Materials Science and Engineering, University of Arizona, Tucson AZ
Copyright Elsevier

The microstructures and chemistry of secondary feldspars and phosphates in equilibrated ordinary chondrites (OCs) suggest that fluids were involved in the formation of these phases, challenging the conventional view that secondary alteration of equilibrated OCs occur under water-absent conditions. The newly discovered Sidi El Habib 001 (SEH 001), a halite-bearing H5 OC, provides a unique opportunity to further probe the role of fluids during thermal metamorphism on the OC parent bodies. Here we report a petrographic and mineralogic study of SEH 001, with the aim of understanding the origins of halite grains and their implications for the alteration histories of equilibrated OCs. Our investigation reveals a main halite-bearing lithology and a halite-free lithology, both of which show equilibrated textures. Except for halides, no significant textural or compositional differences were observed between halite-bearing and -free lithologies. Halite occurs at all spatial scales in the main lithology and shows clear textures of replacing albitic plagioclase and Cl-apatite. Chlorapatite grains in SEH 001 are Cl-rich and many of them contain elevated amounts of “other” anions.

Our observations suggest that halite grains in SEH 001 formed in situ on the parent body via precipitation from an aqueous fluid. The replacement of plagioclase and Cl-apatite by halite and the equilibrated textures of halite-bearing and halite-free lithologies point to a hydrothermal alteration history where halite formed during advanced thermal metamorphism before the fluid was completely lost. The two lithologies were likely affected by fluids with different Cl concentrations that resulted from heterogeneous distribution of HCl hydrate. Based on comparison to experimental data, halite in SEH 001 could have survived peak metamorphism because of its relatively high thermal stability. Collisional disruption of its original parent body could also facilitate the preservation of halite via release of heat. In the rubble pile model of the OC parent body formation, subsequent accretion of hot fragments into a rubble pile body could have resulted in the blurred boundaries between halite-free and -bearing lithologies now observed in our sample. The occurrence of halite in SEH 001 is clear evidence that aqueous fluids were involved in the alteration of equilibrated OCs.

Combined with previous reports of hydrous minerals (such as phyllosilicates) and other related aqueous products in unequilibrated OCs, our study further suggests that S-type asteroids, the parent bodies of OCs, could be more hydrated than previously thought and might serve as a potential source of water for terrestrial planets in the inner solar system. Nevertheless, whether the proposed hydrothermal history of SEH 001 can be extrapolated to other equilibrated OCs needs to be tested. The in-situ formation origin of halite in SEH 001 contrasts with the exogeneous origin of halite in Monahans (1998) and Zag, suggesting that halites with different origins occurred on the OC parent bodies. The rarity of halite in OCs could be attributed to the heterogeneous distribution of HCl hydrate in the OC parent bodies, although the fragile nature of halite in terrestrial and laboratory environments also increases the likelihood of halite being destroyed in OC samples.

¹Aaron S. Bell,²Charles Shearer,¹Lydia Pinkham,³Anthony J. Irving
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2023.02.019]
¹Department of Geological Sciences, University of Colorado Boulder
²Institute of Meteoritics and Department of Earth and Planetary Sciences, University of New Mexico
³Department of Earth and Space Sciences, Seattle, WA 98195
Copyright Elsevier

One of the enduring problems in angrite petrogenesis is how to reconcile the extraordinary Fe-rich compositions of many angritic liquids – which seemingly require modestly oxidized fO2 conditions that fall outside the stability field of Fe-Ni alloys during primordial melting – with the geochemical and paleomagnetic evidence that the angrite parent body contains a small metallic Fe-Ni-S-C core. One of the major impediments to resolving these contradictions stems from a distinct lack of rigorous fO2 data for the angrite meteorite clan. To begin addressing this issue, we have developed a new approach for calculating magmatic fO2 values directly from the late-stage olivine-ulvöspinel- silicate liquid assemblages that are common in the volcanic or hypabyssal angrites. The adaptation of the olivine-spinel-oxybarometer for use in angrites requires a careful assessment of
of angritic liquids. We apply the results of metal saturated angrite crystallization experiments and an analysis of the Ca-Tschermak’s-anorthite-equilibrium to obtain estimates of thevalues angritic magmas. We then use the
estimates derived from the experiments and thermodynamic analysis in conjunction with the olivine-spinel-
oxybarometer to calculate the magmatic fO2 of Sahara 99555, D’Orbigny, and Northwest Africa 12004. With this approach we estimate oxygen fugacity values that range from IW+0 to IW+0.25. The relatively reducing fO2 values obtained from our analysis are inconsistent with redox conditions required by the oxidized melting hypothesis. Some caution is warranted in extrapolating these late-stage magmatic fO2 values to higher temperatures; however, we stress that fractionated silicate liquids typically become more oxidized with increasing crystallization via auto-oxidation (i.e., the accumulation of incompatible ferric iron in the liquid). Therefore, we suggest that late stage magmatic fO2 values from our calculations may represent the most oxidized conditions along the angrite liquid line of descent. If this interpretation is correct, a large-scale oxidation event on the APB need not be invoked to reconcile mildly reducing conditions (ΔIW-1.35) thought to have prevailed during core formation with the magmatic fO2 record preserved in angritic meteorites. Future redox studies of compositionally primitive angrites (e.g., Northwest Africa 12774) may shed new light on the redox relationships among primitive angrite magmas, evolved angrite magmas, and core forming alloys.

¹Emerson J. Speyerer,¹Mark S. Robinson,¹Aaron Boyd,¹Victor H. Silva,²Samuel Lawrence
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2023.115506]
¹School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85282, United States of America
²NASA Lyndon B. Johnson Space Center, Houston, TX 77058, United States of America
Copyright Elsevier

The Ultraviolet/Visible (UVVIS) camera on the Clementine spacecraft provided a global, multispectral view of the Moon. Scientists commonly use individual observations and derived products (optical maturity, mineral abundance, etc.) over 25 years later, addressing questions concerning the composition and relative age of surface features. However, since the mission concluded, our knowledge of lunar topography and the locations of features on the surface have improved with results from the Lunar Reconnaissance Orbiter (LRO) and Gravity Recovery and Interior Laboratory (GRAIL) missions. Before this work, cross-mission comparisons were impaired by spatial offsets between the derived products, which are as large as 2.5 km in some regions. Lunar Reconnaissance Orbiter Camera (LROC) Wide Angle Camera (WAC) images, acquired under similar lighting conditions, were used as a cartographic reference. We used image-based feature-matching algorithms to automatically derive control points to improve the positional accuracy of each UVVIS observation with the LROC WAC basemap. From ground control points, we calculate a precise camera model (focal length, optical distortion, etc.) for the UVVIS camera and update the pointing for each UVVIS image. Using the updated geometric information and projecting the UVVIS image to the LOLA global shape model, we map the five-band multispectral UVVIS mosaic, the optical maturity map, and FeO and TiO2 abundance maps. We also analyze pitch observations of the polar regions to investigate the influence phase angle has on the derived optical maturity. The new images are registered to the GRAIL-based LRO geodetic framework within a WAC pixel (Ground Sampling Distance ~75 m; average UVVIS sigma0 = 0.084), creating a foundational geospatial data product that does not require any manual interpretation or nonlinear warping of map products to align with the current lunar reference frame.

¹Liang Zhang,²Xubing Zhang,¹Maosheng Yang,¹Xiao Xiao,³Denggao Qiu,³Jianguo Yan,¹Long Xiao,^1,2Jun Huang
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2023.115505]
¹State Key Laboratory of planetary processes and mineral resources, School of Earth Sciences, China University of Geosciences (Wuhan), Wuhan 430074, China
²School of Geography and Information Engineering, China University of Geosciences, Wuhan 430078, China
³State Key Laboratory of Information Engineering in Surveying, Mapping and Remote Sensing, Wuhan University, Wuhan 430070, China
⁴Chinese Academy of Sciences Center for Excellence in Comparative Planetology, Hefei 230026, China
Copyright Elsevier

In the past, global maps of major oxides and magnesium number (Mg #) on the lunar surface had been derived from spectral data of remote sensing images, combined with “ground truth” geochemical information from Apollo and Luna samples. These compositional maps provide insights into the chemical variations of different geologic units, revealing the regional and global geologic evolution. In this study, we produced new maps of five major oxides (i.e., Al2O3, CaO, FeO, MgO, and TiO2) and Mg # using imaging spectral data from the KAGUYA multiband imager (MI) and the one-dimensional convolutional neural network (1D-CNN) algorithm. We took advantage of recently acquired geochemical information from China’s Chang’E-5 (CE-5) samples. We used the coefficients of determination (R2) and Root Mean Squared Error (RMSE) as model evaluation indicators. We compared the results with the models used by Wang et al. (2021) and Xia et al. (2019). Our study shows that the 1D-CNN algorithm model used in this study had a higher degree of fit and smaller dispersion between the “ground truth” value of geochemical information and the predicted value of spectral data. The 1D-CNN algorithm generally performs better in describing the complex nonlinear relationship between spectra and chemical components. In addition, we present regions of mare domes in Mairan Dome (43.76°N, 49.90°W) and irregular mare patches (IMPs) in Sosigenes (8.34°N, 19.07°E) to demonstrate the geologic implications of these new maps. With the highest spatial resolution (~ 59 m/pixel), these new maps of five major oxides and Mg # will serve as an important guide in future studies of lunar geology.

¹Ming Ma,¹Jingran Chen,²Clive R. Neal,^3,4Shengbo Chen,¹Bingze Li,¹Chenghao Han,¹Peng Tian
Icarus (in Press) LinktoArticle [https://doi.org/10.1016/j.icarus.2023.115464]
¹School of Surveying and Exploration Engineering, Jilin Jianzhu University, Changchun, China
²Department of Civil and Environmental Engineering and Earth Sciences, University of Notre Dame, Notre Dame, IN 46556, USA
³School of Geo-Exploration Science and Techniques, Jilin University, Changchun, China
⁴Center for Excellence in Comparative Planetology, Chinese Academy of Sciences, Hefei, China
Copyright Elsevier

High alumina (HA) mare basalts play unique roles in understanding the heterogeneity of lunar mantle. Their presence was confirmed by the Apollo and Luna samples, and their remote sensing identification was implemented using HA sample FeO, TiO2 and Th concentration constraints. This study selected the surfaces with ~0.5% rock abundance as windows into HA basalts identification. The lithology of these rock pixels was first classified based on thorium maps from the Lunar Prospector and major element oxide products from Diviner data onboard the Lunar Reconnaissance Orbiter (LRO). Then, the LRO Diviner Al2O3 (~11 wt%) concentration constraint was applied in the mare basalt rock pixels across the Moon. The mare-highland mixtures were distinguished from HA basalt rocks based on the positive linear relationships between Al2O3 and Mg# in the adjacent pixels for four impact vector directions away from each candidate HA pixel. These HA basalts rock pixels identified by this study indicate that HA basalts are concentrated locally in South Pole-Aitken (SPA) basin, Schiller-Schickard region and 13 maria such as southern and northern Oceanus Procellarum, central Humorum, Tranquillitatis, Fecunditatis and Serenitatis, northern Imbrium and southern Nubium, but are seldom found in Mare Moscoviense and Orientale regions on the farside. Detailed investigations in Mare Fecunditatis found that fifteen HA basalt units or patches could be confidently identified. These HA basalts have the total area and volume of <77,658 km2 and < 54,301 km3, and the maximum depth and thickness of 1147 m and 1062 m respectively. In addition, analyses of the HA rocks indicated that the HA basalts are discontinuous and have variable thicknesses.

^1,2Razvan Caracas,³Sarah T. Stewart
Earth and Planetary Science Letters 608, 118014 Link to Article [https://doi.org/10.1016/j.epsl.2023.118014]
¹Université Paris Cité, Institut de Physique du Globe de Paris, CNRS, 1 rue Jussieu, Paris, 75005, France
²The Center for Earth Evolution and Dynamics, University of Oslo, Oslo, 0371, Norway
³Department of Earth and Planetary Sciences, University of California, Academic Surge, 1124 Crocker Ln, Davis, 95616, CA, USA
Copyright Elsevier

Vaporization is a major outcome of giant impacts during planet formation. The last giant impact marked a major stage in the early history of our planet, with the formation of a highly vaporized protolunar disk, that condenses onto the final Earth and Moon. The thermodynamic state of the disk and its condensation path are still uncertain, as most impact simulations have not used accurate material models. In this study, we compute the critical point and liquid spinodal of the bulk silicate Earth composition. We find that the thermal profiles through portions of the protolunar disk and the post-impact Earth exceeded the mantle critical point of 80-130 MPa kbars and 6500-7000 K. We find that Earth, and most rocky planets, will traverse a temporary state that lacks a surface defined by a magma ocean-atmosphere boundary. Furthermore, the atomic structure of the silicate fluid varies with the radius within the disk due to strong pressure and temperature gradients. Fluffy short-lived chemical species dominate the outer parts of the disk, and long-lasting dense polymers abound in the deeper parts. During cooling, the silicate vapor condenses and the composition of the post-impact atmosphere is dominated by species along the mantle vapor curve.

¹Lingzhi Sun,¹Paul G. Lucey
Earth and Planetary Science Letters(in Press) Link to Article [https://doi.org/10.1016/j.epsl.2023.118074]
¹Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa, Honolulu, HI 96822, USA
Copyright Elsevier

Dunite is a rock type composed of more than 90% olivine, and Mg-rich dunite has been suggested to be a rock type that may represent upper mantle of the Moon. Dunite rocks might have been exposed on basin rings by basin-forming impacts. However, previous studies reported no unambiguous evidence of mantle dunite from lunar samples and remote sensing detections. In this work, we applied a mantle boulder candidate search algorithm around the Imbrium basin using radiative transfer modeling and datasets from Moon Mineralogy Mapper and Multiband Imager. We found two boulders consisting of ∼90 vol% olivine with 95 Mg# on Copernicus central peaks, which are possible mantle dunite excavated by Imbrium basin or Copernicus crater. We also found that non-dunite boulders on Copernicus central peak show a large variation in olivine content (8–51 vol%). We infer this is a result of the complicated process of Mg-suite formation in the lower crust or mechanical mixing during the Imbrium basin forming event. The algorithm we presented has a great potential to be applied to lunar basins for a global search for mantle candidate boulders.

^1,2,3Samuel D. Crossley,²Richard D. Ash,^2,3Jessica M. Sunshine,⁴Catherine M. Corrigan,⁴Timothy J. McCoy
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13959]
¹Lunar and Planetary Institute, USRA, Houston, Texas, USA
²Department of Geology, University of Maryland, College Park, Maryland, USA
³Department of Astronomy, University of Maryland, College Park, Maryland, USA
⁴Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution, Washington, District of Columbia, USA
Published by arrangement with John Wiley & Sons

Models of planetary core formation beginning with melting of Fe,Ni metal and troilite are not readily applicable to oxidized and sulfur-rich chondrites containing only trace quantities of metal. Cores formed in these bodies must be dominated by sulfides. Siderophile trace elements used to model metallic core formation could be used to model oxidized, sulfide-dominated core formation and identify related meteorites if their trace element systematics can be quantified. Insufficient information exists regarding the behavior of these core-forming elements among sulfides during metamorphism prior to anatexis. Major, minor, and trace element concentrations of sulfides are reported in this study for petrologic type 3–6 R chondrite materials. Sulfide-dominated core-forming components in such oxidized chondrites (ƒO2 ≥ iron-wüstite) follow metamorphic evolutionary pathways that are distinct from reduced, metal-bearing counterparts. Most siderophile trace elements partition into pentlandite at approximately 10× chondritic abundances, but Pt, W, Mo, Ga, and Ge are depleted by 1–2 orders of magnitude relative to siderophile elements with similar volatilities. The distribution of siderophile elements is further altered during hydrothermal alteration as pyrrhotite oxidizes to form magnetite. Oxidized, sulfide-dominated core formation differs from metallic core formation models both physically and geochemically. Incongruent melting of pentlandite at 865°C generates melts capable of migrating along solid silicate grains, which can segregate to form a Ni,S-rich core at lower temperatures compared to reduced differentiated parent bodies and with distinct siderophile interelement proportions.

¹Patrick J. A. Hill,¹Libby D. Tunney,¹Christopher D. K. Herd
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13963]
¹Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada
Published by arrangement with John Wiley & Sons

The rapid recovery of meteorites mitigates the exposure of astromaterials to the terrestrial environment and subsequent contamination. Modern fireball observatories have enabled the more accurate triangulation of fireball trajectories, which has aided in the location of strewn fields, in the case of meteorite-producing events. Despite this advancement, most meteorite searches still use manual searching to locate any meteorite falls, which is often labor-intensive and has a slow coverage rate (km2 day−1). Recent work has begun exploring the application of drone technology to the recovery of meteorites; however, most of this work has focused on falls in arid environments. Our study examines the utilization of drones with thermal imaging technology to aid in the recovery of meteorites that have fallen on a snow-covered field. We created a simulated strewn field that included meteorite specimens as well as Earth rocks with similar properties (“meteowrongs”). Thermal imagery was utilized to determine whether the thermal contrast between meteorites and snow could aid in the identification of meteorites. We found that the thermal contrast was significant enough that meteorites were readily identifiable within thermal images; however, it was not significant enough to distinguish between the meteorites and the meteowrongs. The utilization of thermal imagery in conjunction with visible imagery has the potential to aid in the rapid recovery of meteorites in snow-covered landscapes.