Laser alteration on iron sulfides under various environmental conditions

1I. Weber,2U. Böttger,2S. G. Pavlov,2,3H.-W. Hübers,1H. Hiesinger,1E. K. Jessberger
Journal of Raman Spectroscopy 48, 1509-1517 Link to Article [DOI: 10.1002/jrs.5083]
1Institut für Planetologie, Münster, Germany
2Deutsches Zentrum für Luft- und Raumfahrt (DLR), Institut für Optische Sensorsysteme, Berlin, Germany
3Institut für Optik und Atomare Physik, Humboldt Universität, Institut für Physik, Berlin, Germany

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Ab initio simulations and experimental Raman spectra of Mg2SiO4 forsterite to simulate Mars surface environmental conditions

1C. Stangarone,2U. Böttger,1D. Bersani,1M. Tribaudino,3M. Prencipe
Journal of Raman Spectroscopy 48, 1528-1535 Link to Article [DOI: 10.1002/jrs.5127]
1Physics and Earth Science Department, University of Parma, Parma, Italy
2Institute of Optical Sensor Systems, DLR, Berlin, Germany
3Earth Science Department, University of Turin, Torino, Italy

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Geochemical study of the Northwest Africa 6148 Martian meteorite and its terrestrial weathering processe

1Imanol Torre-Fdez,1Julene Aramendia,1Leticia Gomez-Nubla,1Kepa Castro,1Juan M. Madariaga
Journal of Raman Spectroscopy 48, 1536-1543 Link to Article [DOI: 10.1002/jrs.5148]
1Department of Analytical Chemistry, Faculty of Science and Technology, University of the Basque Country (UPV/EHU), Bilbao, Spain

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The on-ground calibration performances of the hyperspectral microscope MicrOmega for the Hayabusa-2 mission

1Lucie Riu,1Jean-Pierre Bibring, 1Cédric Pilorget, 1François Poulet, 1Vincent Hamm
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2018.01.009]
1Institut d’Astrophysique Spatiale, Université Paris-Sud 11, 91405, Orsay, France

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Raman spectroscopy of various phosphate minerals and occurrence of tuite in the Elga IIE iron meteorite

1,2,3Konstantin D. Litasov, 1Nikolay M. Podgornykh
Journal of Raman Spectroscopy 48, 1518-1527 Link to Article [DOI: 10.1002/jrs.5119DOI: 10.1002/jrs.5119]
1V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Novosibirsk, Russia
2Novosibirsk State University, Novosibirsk, Russia
3Konstantin D. Litasov, V.S. Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, Koptyuga Ave., 3, Novosibirsk 630090, Russia.

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Mineralogy and Chemistry of Ti-Bearing Lunar Soils: Effects on Reflectance Spectra and Remote Sensing Observations

1Ecaterina O. Coman, 1Bradley L. Jolliff, 1Paul Carpenter
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2018.02.008]
1Washington University in St. Louis, Saint Louis, MO, 63123, USA
Copyright Elsevier

This paper presents results of coordinated ultraviolet and visible wavelength reflectance measurements, X-ray diffraction analyses of mineral components, and micro X-ray fluorescence analyses of Ti concentrations of 13 lunar soil samples (<210 μm) that span a range of maturity and TiO2 contents. Results of these analyses are used to determine the effects of soil maturity, TiO2 concentration, and specific mineralogical makeup, especially ilmenite content, on the ultraviolet/visible (UV/VIS) ratio for application to remote sensing observations of the Moon and other airless bodies. We find that measured ilmenite weight percent correlates highly with measured TiO2 concentrations. Thus, the ilmenite content is a good predictor of TiO2 concentration. Ilmenite is the main contributor of TiO2 for soils with greater than about 2 weight percent TiO2, so we take the effects of TiO2 on reflectance spectra to be essentially those of ilmenite. Constraining the data set to eight mature Apollo soils, we find that among the UV/VIS ratios from laboratory-measured spectra, the 321/415 nm ratio shows the best correlation with TiO2 and ilmenite. Moreover, for soils with similar maturity in the submature to mature range, those with higher TiO2 have higher 321/415 UV/VIS ratios. Finally, the correlation between TiO2 content and 321/415 ratio in samples measured in the lab appears weaker than for the same relationship using the Lunar Reconnaissance Orbiter (LRO) Wide Angle Camera (WAC) spectral data for the 321/415 ratio of Apollo ground-truth sites. The correlation between lab-derived 321/415 ratios and TiO2 content for measured samples improves when low-maturity samples are excluded from the dataset, implying that the LROC WAC spectra at 400 m/pix spatial resolution senses mostly mature soil.

I-Xe dating of aqueous alteration in the CI chondrite Orgueil: I. Magnetite and ferromagnetic separates

1O. Pravdivtseva, 2A.N. Krot, 1C.M. Hohenberg
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2018.02.004]
1Physics Department, Washington University, St. Louis MO 63130, USA
2Hawai‘i Institute of Geophysics and Planetology, School of Ocean, Earth Science and Technology, University of Hawai’i at Mānoa, Honolulu, HI 96822, USA
Copyright Elsevier

The I-Xe system was studied in a ferromagnetic sample separated from the Orgueil CI carbonaceous chondrite with a hand-held magnet and in two magnetite samples, one chemically separated before and the other one after neutron irradiation. This work was done in order to investigate the effects of chemical separation by LiCl and NaOH on the I-Xe system in magnetite. Our test demonstrated that the chemical separation of magnetite before irradiation using either LiCl or NaOH, or both, does not contaminate the sample with iodine and thus cannot lead to erroneous I-Xe ages due to introduction of uncorrelated 128∗Xe.

The I-Xe ages of two Orgueil magnetite samples are mutually consistent within experimental uncertainties and, when normalized to an absolute time scale with the reevaluated Shallowater aubrite standard, place the onset of aqueous alteration on the CI parent body at 4564.3 ± 0.3 Ma, 2.9 ± 0.3 Ma after formation of the CV Ca-AI-rich inclusions (CAIs). The I-Xe age of the ferromagnetic Orgueil separate is 3.4 Ma younger, corresponding to a closure of the I-Xe system at 4560.9 ± 0.2 Ma. These and previously published I-Xe data for Orgueil (Hohenberg et al., 2002) indicate that aqueous alteration on the CI parent body lasted for at least 5 Ma.

Although the two magnetite samples gave indistinguishable I-Xe ages, their temperature release profiles differed. One of the two Orgueil magnetites released less radiogenic Xe than the other, 80% of it corresponding to the low-temperature peak of the release profile, compared to only 6% in case of the second Orgueil magnetite sample. This could be due to the difference in iodine trapping efficiencies for magnetite grains of different morphologies. Alternatively, the magnetite grains with the lower radiogenic Xe concentrations may have formed at a later stage of alteration when iodine in an aqueous solution was depleted.

High Abundances of Presolar Grains and 15N-rich Organic Matter in CO3.0 Chondrite Dominion Range 08006

1Larry R. Nittler, 1Conel M.O’D. Alexander, 1Jemma Davidson, 1My E.I. Riebe,2 Rhonda M. Stroud, 1Jianhua Wang
Geochimica et Cosmochimcia Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2018.01.038https://doi.org/10.1016/j.gca.2018.01.038]
1Department of Terrestrial Magnetism, Carnegie Institution of Washington, Washington, DC 20015, USA.
2Materials Science and Technology Division, Code 6366, US Naval Research Laboratory, Washington, DC 20375-5320, USA.
Copyright Elsevier

NanoSIMS C-, N-, and O-isotopic mapping of matrix in CO3.0 chondrite Dominion Range (DOM) 08006 revealed it to have in its matrix the highest abundance of presolar O-rich grains (257 +76/-96 ppm, 2σ) of any meteorite. It also has a matrix abundance of presolar SiC of 35 (+25/-17, 2 σ) ppm, similar to that seen across primitive chondrite classes. This provides additional support to bulk isotopic and petrologic evidence that DOM 08006 is the most primitive known CO meteorite. Transmission electron microscopy of five presolar silicate grains revealed one to have a composite mineralogy similar to larger amoeboid olivine aggregates and consistent with equilibrium condensation, two non-stoichiometric amorphous grains and two olivine grains, though one is identified as such solely based on its composition. We also found insoluble organic matter (IOM) to be present primarily as sub-micron inclusions with ranges of C- and N-isotopic anomalies similar to those seen in primitive CR chondrites and interplanetary dust particles. In contrast to other primitive extraterrestrial materials, H isotopic imaging showed normal and homogeneous D/H. Most likely, DOM 08006 and other CO chondrites accreted a similar complement of primitive and isotopically anomalous organic matter to that found in other chondrite classes and IDPs, but the very limited amount of thermal metamorphism experienced by DOM 08006 has caused loss of D-rich organic moieties, while not substantially affecting either the molecular carriers of C and N anomalies or most inorganic phases in the meteorite. One C-rich grain that was highly depleted in 13C and 15N was identified; we propose it originated in the Sun’s parental molecular cloud.