Nature and evolution of Yamato-type carbonaceous chondrites: Clues from Ti-minerals in Dhofar 1988

1Shu-Zhou Wang, 1Ai-Cheng Zhang, 1Tian-Ran Du, 1Jia-Ni Chen, 2Yuan-Yun Wen
Meteoritics & Planetary Science (in Press) Link to Article [DOI: 10.1111/maps.70256]
1State Key Laboratory for Critical Earth Material Cycling and Mineral Deposits, School of Earth Sciences and Engineering, Nanjing University, Nanjing, China
2Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China

Published by arrangement with John Wiley & Sons

Yamato-type (CY) carbonaceous chondrites are a group of meteorites that experienced both intense aqueous alteration and subsequent dehydration. They consist of a few CY1 and CY2 samples; however, their nature and genetic relationship remains an issue of debate. Here, we report the detailed petrography and mineralogy of four sections of Dhofar 1988, a newly proposed CY chondrite. We find that Dhofar 1988 is a dimict breccia, containing a CY2-like host region (~73 area%) and numerous CY1-like dark clasts (~27 area%). Using Ti-minerals as a clue, we identified 14 calcium-aluminum-rich inclusions (CAIs) (including an Al-rich chondrule containing CAI material, with most of the CAIs present in the host region, ~1 area%) and only one CAI in dark clasts (~0.04 area%). These CAIs contain a series of Ti-minerals, including primary perovskite, Ti-rich fassaite, Ti-rich hibonite, and probably ilmenite–rutile assemblage, and secondary ilmenite, anatase, rutile, zirconolite (ideal formula CaZrTi2O7), and perovskite. Formation of the secondary Ti-minerals involves: (1) replacement of Ti-rich fassaite by melilite-like phase, perovskite, and minor spinel; (2) subsolidus breakdown of potential armalcolite to ilmenite and rutile and minor spinel and zirconolite; (3) alteration of perovskite to ilmenite; (4) alteration of perovskite to anatase; (5) alteration of fassaite to phyllosilicate and ilmenite; and (6) transition from ilmenite to perovskite. They probably formed during pre-alteration metamorphism (1 and 2), intense aqueous alteration (3–5), and postalteration metamorphism (6), respectively, and reflect the evolution of temperature and water/rock ratio. The similarity between the two components in Dhofar 1988 and the CY1 and CY2 samples indicates that the material from CY1 and CY2 samples was once mixed with each other through collision-induced mixing or during initial planetesimal accretion.

Water and hydroxyl on asteroid Bennu: Reconciling remote observations with OSIRIS-REx sample analysis

1Hannah H. Kaplan, 1Amy A. Simon, 2Victoria E. Hamilton, 3Joshua P. Emery, 1Dennis Reuter, 1Andy J. López-Oquendo
Meteoritics & Planetary Science (in Press)
Open Access Link to Article [DOI: 10.1111/maps.70239]
1Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, Maryland, USA
2Solar System Science & Exploration Division, Southwest Research Institute, Boulder, Colorado, USA
3Department of Astronomy and Planetary Science, Northern Arizona University, Flagstaff, Arizona, USA

Published by arrangement with John Wiley & Sons

This study investigates the spatial distribution and spectral characteristics of the broad hydration feature near 3 μm across the surface of asteroid (101955) Bennu using OVIRS (OSIRIS-REx Visible and InfraRed Spectrometer) data. We analyzed multiple global OVIRS data sets obtained at different times throughout the Bennu day, revealing variations in band depth with wavelength, as well as wavelength-dependent correlations with temperature and other surface properties. Our analysis distinguishes between the behavior of the 2.74-μm and 3.0-μm features, which contribute to a broad 3-μm region absorption, suggesting they may have different origins or respond differently to surface conditions. The 2.74-μm band depth shows strong negative correlation with temperature and positive correlation with albedo and hydroxyl, whereas the 3.0-μm band depth exhibits primarily weak relationships with other spectral and surface parameters, such as temperature, albedo, and UV/visible spectral slope, indicating that these features probe different aspects of the surface materials. These findings demonstrate that space weathering likely plays a strong role within the hydration band. Specifically, temperature and time-of-day dependencies observed at 2.74-μm point to an active hydroxyl cycle on Bennu’s surface driven by solar wind hydrogen implantation, hydroxylation, and subsequent thermal desorption. Conversely, the distinct behavior of the 3.0-μm band suggests it may serve as an indicator of surface composition, including the phosphate minerals recently found in the returned sample; however, the lack of correlation with other expected diagnostic spectral features, such as a bluer UV/visible slope, currently leaves this relationship inconclusive.

Assessing the analytical capabilities of handheld laser-induced breakdown spectroscopy (hLIBS) on corroded iron objects of possible meteoritic origin

1Giorgio S. Senesi, 2Albert Jambon, 1Olga De Pascale, 3,4Lahcen Ouknine, 3,4Hassan Nachit, 4,5Fouad Khiri, 3,4Abderrahmane Ibhi
Meteoritics & Planetary Science (in Press)
Open Access Link to Article [DOI: 10.1111/maps.70242]
1CNR—Istituto per la Scienza e Tecnologia dei Plasmi (ISTP)—sede di Bari, Bari, Italy
2Université Côte d’Azur, Sorbonne Université, CNRS, OCA, IRD, Geoazur, Valbonne, France
3Earth Sciences Department, Faculty of Sciences, Ibn Zohr University, Agadir, Morocco
4University Meteorites Museum, Ibn Zohr University, Agadir, Morocco
5Faculty of Sciences, Earth Sciences Department, Laboratory of Geosciences, Environment and Geomatics (GEG), Ibn Zohr University, Agadir, Morocco

Published by arrangement with John Wiley & Sons

Despite meteorites having been recognized as the source of iron in some ancientiron artifacts, few archeological irons have been analyzed so far, as invasive methods areprecluded. In this work, four iron knives and one axe collected near Guelmime and Imilchil(Morocco) were investigated by advanced analytical techniques, including handheldlaser-induced breakdown spectroscopy (hLIBS), still not yet widely used, and portableX-ray fluorescence (pXRF). The analyzed objects are undated iron findings recoveredwithout an archeological context and represent test cases for assessing the analyticalcapabilities of hLIBS on corroded iron objects of possible meteoritic origin. Major andtrace element analyses, internal stratigraphy by depth profiling, and microscalecompositional mapping have been performed, which allowed assessment of the samplecomposition, heterogeneity, and corrosion. One of the five specimens studied appeared to bemade of meteoritic iron. The relative uncorroded state of this specimen, when compared toBronze Age irons, enabled investigation of the effect of forging on the composition,especially the mobility of Ni. In particular, the reliability of hLIBS-acquired analytical datafor the major elements Fe and Ni and the trace elements Ge and Au was shown. As well, apossible source relationship of sample #5 with NWA 859 (Taza)/Oglat Sidi Ali meteoritewas discussed and proposed, based on the chemical variations ascribed to the interplay ofprimordial heterogeneity and the introduction of carbon upon forging and corrosion.Furthermore, the analytical limitations of the hLIBS technique were suggested not to beinstrumental, but due to the heterogeneity of natural specimens, confirming that hLIBSrepresents a robust analytical tool for future field archeology and archeometric studies.

Thermal history of an amoeboid olivine aggregate in the early solar nebula

1M. Kimura, 1N. Imae, 2M. Komatsu, 1A. Yamaguchi
Meteoritics & Planetary Science (in Press)
Open Access Link to Article [DOI: 10.1111/maps.70248]
1National Institute of Polar Research, Tokyo, Japan
2Division of Liberal Arts and Sciences, Saitama Prefectural University, Saitama, Japan

Published by arrangement with John Wiley & Sons

Carbonaceous chondrites commonly contain amoeboid olivine aggregates (AOAs).Here, we investigated an AOA in the CR chondrite Y-793261. This AOA contains anunstable assemblage of forsterite and quartz. We found a rare occurrence of enstatite andquantitatively discuss its formation process. This enstatite occurs specifically betweenforsterite and quartz, indicating a solid-state reaction between them. By applying theexperimental results of Imae et al. (Proc. Japan Aca. 75: 229–234), we determined that thisAOA formed under high-temperature conditions (≳1169 K) over a period of approximately1–5 years. The reservoir where the AOA formed was enriched in 16 O. Subsequently, it cooledrapidly and was transported to the reservoir where the parent body accreted, incorporatingchondrules and matrix. The thermal history and physicochemical conditions of this AOA areapplicable to other AOAs.

An exposed magmatic feeder system for the regional olivine unit in Nili Fossae, Mars

1,2,3A. Valantinas, 1J. F. Mustard, 4A. Tullo, 5M. S. Bramble, 1J. W. Head
Earth and Planetary Science Letters, 696, 120390
Open Access Link to Article [DOI: 10.1016/j.epsl.2026.120390]
1Department of Earth, Environmental and Planetary Sciences, Brown University, Providence, USA
2Department of Earth and Planetary Sciences, ETH Zurich, Zurich, Switzerland
3Department of Earth Sciences, University of Cambridge, Cambridge, UK
4INAF, Osservatorio Astronomico di Padova, Padova, Italy
5Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA

Copyright Elsevier

The origin of the >100,000 km² regional olivine unit in the Nili Fossae-Jezero region has been variously attributed by orbital studies to airfall, effusive lavas, impact melt, or intrusive emplacement. In situ characterization of olivine-bearing igneous rocks in Jezero crater by the Mars 2020 Perseverance rover has revealed olivine cumulate textures indicative of effusive or intrusive magmatism, but conduits in the shallow-crustal feeder system that transported olivine-saturated magma have not been identified. Here we combine sub-meter pansharpened imagery from the Colour and Stereo Surface Imaging System (CaSSIS) and the High Resolution Imaging Science Experiment (HiRISE) with near-infrared spectral analysis from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) to characterize a population of olivine-rich ridges and elongated features that crosscut the Fe/Mg-smectite basement at the “Horseshoe” site in Nili Fossae, ∼200 km north of Jezero. The features display a continuum of morphologies, from planar dike-like ridges through sinuous and braided lineaments that locally crosscut topography. Analysis of the 1 µm olivine near-infrared absorption places the features along the same compositional trend as the regional olivine–carbonate assemblage, and CRISM spectra resolve weak 1.9 and 2.32 µm absorptions diagnostic of hydrated/hydroxylated phases, indicating partial alteration of the intrusive olivine. We interpret these features as exhumed magmatic intrusions in a hydrated smectite basement, possibly exploiting pre-existing fault networks, and propose that they form part of a broader Jezero-Nili Fossae magmatic province. Magma-clay contact zones of this kind may provide a unique class of habitable environments in the shallow Noachian crust of Mars.

Electrostatic discharge triggers troilite-to-magnetite oxidation in Mars dust activity

1,2Xiaojia Zeng, 1,2Xiongyao Li
Geochimica et Cosmochimica Acta (in Press) Link to Article [DOI: 10.1016/j.gca.2026.10.025]
1State Key Laboratory of Critical Mineral Research and Exploration, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China
2Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China

Copyright Elsevier

Electrostatic discharge in Martian dust storms may significantly drive the chemical alteration and cycling of surface materials. Troilite is expected on Mars from magmatic and meteoritic sources but remains undetected by rovers, raising the question of possible electrostatic discharge-driven alteration. However, this hypothesis lacks direct experimental support. In this study, we experimentally simulate electrical discharge under Martian conditions by exposing troilite to such discharge in a CO2 atmosphere at low pressure. We found that electrical discharge rapidly oxidizes troilite to magnetite (Fe3O4), forming a ∼ 100 nm thick, polycrystalline, defect-rich alteration layer on the troilite surface. This oxidation is driven by reactive oxygen species attack Fe-S bonds, displace sulfur, and convert the residual iron framework into magnetite. Such an electrical discharge-driven pathway offers a new water-free mechanism for magnetite formation on Mars, specifically active during the hyper-arid Amazonian epoch. This work also provides an additional explanation for the missing troilite in Martian soils and the widespread occurrence of magnetite in Martian dust. More broadly, this study expands our understanding of Martian surface evolution beyond water-dominated scenarios and highlights oxidative role of ongoing dust activities on present-day Mars.