Origin of nucleosynthetic isotope variability in the NC reservoir: evidence from Ti, Cr, and Mo isotopes

1,2Elias Wölfer, 1,2Christoph Burkhardt, 2Gerrit Budde, 2Christian A. Jansen, 2Jonas Pape, 1,2Thorsten Kleine
Geochimica et Cosmochimica Acta (in Press) Open Access Link to Article [DOI: 10.1016/j.gca.2026.08.021]
1Max Planck Institute for Solar System Research, Justus-von-Liebig-Weg 3, 37077 Göttingen, Germany
2Institut für Planetologie, University of Münster, Wilhelm-Klemm-Str. 10, 48149 Münster, Germany
Copyright Elsevier

Nucleosynthetic isotope anomalies allow distinguishing between non-carbonaceous (NC) and carbonaceous (CC) type meteorites, and have revealed correlated isotope variations especially among NC bodies. Understanding the origin of this NC trend is important for identifying the processes that produced the NC isotope heterogeneity, and for using these isotope anomalies to reconstruct the early evolution of the solar protoplanetary disk. We report mass-independent Ti, Cr, and Mo isotope compositions for a comprehensive set of previously not or only poorly investigated meteorites, as well as acid leachates obtained from the sequential digestion of primitive ordinary chondrites. Some of the samples investigated in this study fill previously identified apparent gaps in the NC trend, suggesting these gaps reflect unrepresentative sampling of a more continuous isotopic trend. Bulk meteorites and leachates exhibit distinct isotope systematics, indicating that the NC isotope variability does not reflect selective thermal processing of presolar carriers in the disk. The NC trend also cannot reflect the continuous addition of CC dust from the outer to the inner disk, because early- and late-formed NC meteorites display largely overlapping isotopic compositions. Instead, we find that the NC isotope heterogeneity is best accounted for by fractionation and mixing among chemically and isotopically distinct dust components, similar to the processes that produced the isotopic variability among carbonaceous chondrites. On this basis we argue for the presence of substructures in the inner disk, which facilitated fractionation and mixing among distinct dust components, and helped preserve a long-lived dust reservoir from which NC planetesimals accreted over an extended period of time.

A native sulfur deposit in Gale crater, Mars

1Scott J. VanBommel (>10)
Science, 393, 820-825 Link to Article [DOI: 10.1126/science.adu5501]
1McDonnell Center for the Space Sciences, Department of Earth, Environmental, and Planetary Sciences, Washington University in St. Louis, St. Louis, MO, USA.
Reprinted with permission from AAAS

Martian rocks are known to contain sulfur-bearing species, including sulfates and sulfides. These compounds record a sulfur cycle that operated over the geological evolution of Mars. We used the Curiosity rover to investigate a deposit of light-toned stones in Gediz Vallis within Gale crater on Mars and found that the stones are composed of native sulfur. The sulfur deposit appears to have formed in place, within a sinuous entrenched canyon cut into the floor of Gediz Vallis. The presence of native sulfur implies that a sulfur enrichment pathway involving buoyant subsurface fluids operated on ancient Mars. We propose that the primary source of this sulfur was magmatic vapor, which cooled in the near subsurface cryosphere and was released by decompression during the erosion of Gediz Vallis.