Artificial weathering of an ordinary chondrite: Recommendations for the curation of Antarctic meteorites

1Matthias van Ginneken,2Vinciane Debaille,3Sophie Decrée,4Steven Goderis,5Alan B. Woodland,1Penelope Wozniakiewicz,3Marleen De Ceukelaire,3Thierry Leduc,3Philippe Claeys
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13818]
1Centre for Astrophysics and Planetary Science, School of Physical Sciences, Ingram Building, University of Kent, Canterbury, CT2 7NH UK
2Laboratoire G-Time, Université Libre de Bruxelles, Brussels, BE1050 Belgium
3Geological Survey of Belgium, Royal Belgian Institute of Natural Sciences, rue Vautier 29, Brussels, BE1000 Belgium
4Analytical, Environmental, and Geochemistry, Vrije Universiteit Brussel, Pleinlaan 2, Brussels, BE1050 Belgium
5Institut für Geowissenschaften, Goethe-Universität Frankfurt, Altenhöferallee 1, Frankfurt am Main, D-60438 Germany
Published by arrangement with John Wiley & Sons

Meteorites are prone to errestrial weathering not only after their fall on the Earth’s surface but also during storage in museum collections. To study the susceptibility of this material to weathering, weathering experiments were carried out on polished sections of the H5 chondrite Asuka 10177. The experiments consisted of four 100-days cycles during which temperature and humidity varied on a twelve hours basis. The first alteration cycle consisted of changing the temperature from 15 to 25 °C; the second cycle consisted of modifying both humidity and temperature from 35 to 45% and 15 to 25 °C, respectively; the third cycle consisted of varying the humidity level from 40 to 60%; and the fourth cycle maintained a fixed high humidity of 80%. Weathering products resulting from the experiments were identified and characterized using scanning electron microscopy–energy dispersive spectroscopy and Raman spectroscopy. Such products were not observed at the microscopic scale after the first cycle of alteration. Conversely, products typical of the corrosion of meteoritic FeNi metal were observed during scanning electron microscope surveys after all subsequent cycles. Important increases in the distribution of weathering products on the samples were observed after cycles 2 and 4 but not after cycle 3, suggesting that the combination of temperature and humidity fluctuations or high humidity (>60%) alone is most detrimental to chondritic samples. Chemistry of the weathering products revealed a high degree of FeNi metal corrosion with a limited contribution of troilite corrosion. No clear evidence of mafic silicate alteration was observed after all cycles, suggesting that postretrieval alteration remains limited to FeNi metal and to a lesser extent to troilite.

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