^1,2Valerie Payre,¹Rajdeep Dasgupta
Geochimica et Cosmochimica acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2022.03.034]
¹Department of Earth, Environmental and Planetary Sciences, Rice University, 6100 Main Street, MS 126, Houston, Texas 77005
²Present address: Department of Physics and Planetary Sciences, Northern Arizona University, Flagstaff, Arizona
Copyright Elsevier

Phosphorus is estimated to be ten times more enriched in the martian mantle compared to the terrestrial mantle. Yet, its effects on primary melt composition and melting phase relations in martian systems is unknown. We performed piston-cylinder experiments at a constant upper mantle pressure of 2 GPa and temperatures of 1210-1450 °C using a model martian primitive mantle composition with P2O5 content of 0 and 0.5 wt.%. All experiments produced an assemblage of olivine + orthopyroxene + melt ± pigeonite ± apatite ± spinel. Our experimental results, in combination with a previous study at similar P-T conditions and major element bulk composition but containing 0.2 wt.% bulk P2O5, show that the addition of phosphorus dramatically increases the abundance of more polymerized residual mineral such as orthopyroxene while decreasing the proportion of less polymerized residual phases such as olivine, especially at low extent of melting (∼11 wt.%). Such effects lead to lower SiO2 concentrations in the near-solidus melt by up to 10 wt.% for mantle P2O5 of 0.2 and 0.5 wt.%. Increasing bulk P2O5 to 0.5 wt.% also leads to elevated CaO/Al2O3 ratio and increased FeO* concentration in mantle-derived melts with the latter likely due to formation of Fe-O-P complexes in the liquid. Our study suggests that elevated phosphorus in the martian mantle has important consequences regarding the composition and mineralogy of the crust, partly made with primary melts, and of the upper mantle. Because of elevated P, variably melt-depleted upper mantle of Mars is likely to be richer in orthopyroxene compared to the terrestrial mantle and the elevated P content is partly responsible for several geochemical attributes of martian basalts compared to those on Earth. Extrapolating our experimental results to a range of pressures, we suggest a depletion of P in the mantle through time, which likely contributed to major elemental compositional differences between ancient Gusev and Gale crater basalts and more recent martian meteorites.