Composition and origin of the volatile components released from the Pesyanoe aubrite by stepwise crushing and heating

1C.A.Lorenz,1A.I.Buikin,2,3A.A.Shiryaev,1O.V.Kuznetsova
Geochemistry [Chemie der Erde] (in Press) Link to Article [https://doi.org/10.1016/j.chemer.2020.125686]
1Vernadsky Institute of Geochemistry and Analytical chemistry RAS, Kosygin St. 19, 119999, Moscow, Russia
2A. N. Frumkin Institute of physical chemistry and electrochemistry RAS, Leninsky pr. 31 korp. 4, Moscow, 119071, Russia
3Institute of geology of ore deposits, Petrography, Mineralogy, and Geochemistry RAS, Staromonetnyi per, 35, 119017 Moscow, Russia
Copyright Elsevier

Aubrites are achondritic meteorites (enstatite pyroxenites) that were formed in highly reduced magmatic environments on a differentiated parent body sharing a common oxygen isotope reservoir with enstatite chondrites (EC), Earth and Moon, and could be considered as a geochemical model of the early proto-Earth. Some pyroxenes of the Pesyanoe aubrite have high abundance of gaseous inclusions, captured during the crystallization of the rocks. Investigation of the inclusions by IR spectroscopy reveals presence of OH− groups and C–H bonds. The former are assigned to protonated point defects in enstatite lattice and the latter to compounds occupying void walls. Molecular water and CO2 were not observed. Volatile components released from the samples of the Pesyanoe enstatite by stepwise crushing and heating are composed of CO2, H2O and a non-condensable phase. Hydrogen isotopic composition of volatiles extracted in form of molecular water in Px-separates varies in the range δD = −61 – −84‰ with mean value of δD = −73 ± 16‰ VSMOW and is within the ranges of ECs and Earth’s mantle. The total abundance of H2 in the pyroxene of Pesyanoe were estimated as at least 0.024 ppm that is too low in comparison with that of enstatite chondrites (≥30 ppm H2) and could indicate nearly complete degassing of the Pesyanoe primitive precursor material during the Pesyanoe parent body accretion or a mantle degassing in igneous differentiation process. In a last case a primitive precursor could have D/H ratio different from that of enstatite chondrites.

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