Visible–near infrared spectral indices for mapping mineralogy and chemistry with OSIRIS‐REx

1Hannah H. Kaplan et al. (>10)
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13461]
1Southwest Research Institute, Boulder, Colorado, 80302 USA
Published by arrangement with John Wiley & Sons

The primary objective of the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS‐REx) mission is to return to Earth a pristine sample of carbonaceous material from the primitive asteroid (101955) Bennu. To support compositional mapping of Bennu as part of sample site selection and characterization, we tested 95 spectral indices on visible to near infrared laboratory reflectance data from minerals and carbonaceous meteorites. Our aim was to determine which indices reliably identify spectral features of interest. Most spectral indices had high positive detection rates when applied to spectra of pure, single‐component materials. The meteorite spectra have fewer and weaker absorption features and, as a result, fewer detections with the spectral indices. Indices targeting absorptions at 0.7 and 2.7–3 μm, which are attributable to hydrated minerals, were most successful for the meteorites. Based on these results, we identified a set of 17 indices that are most likely to be useful at Bennu. These indices detect olivines, pyroxenes, carbonates, water/OH‐bearing minerals, serpentines, ferric minerals, and organics. Particle size and albedo are known to affect band depth but had a negligible impact on interpretive success with spectral indices. Preliminary analysis of the disk‐integrated Bennu spectrum with these indices is consistent with expectations given the observed absorption near 3 μm. Our study prioritizes spectral indices to be used for OSIRIS‐REx spectral analysis and mapping and informs the reliability of all index‐derived data products, including a science value map for sample site selection.

Experimental partitioning of trace elements into schreibersite with applications to IIG iron meteorites

1Nancy L. Chabot,1Rachel H. Cueva,2Andrew W. Beck,3Richard D. Ash
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13462]
1Johns Hopkins University Applied Physics Laboratory, Laurel, Maryland, 20723 USA
2Department of Petroleum Engineering & Geology, Marietta College, Marietta, Ohio, 45750 USA
3Department of Geology, University of Maryland, College Park, Maryland, 20742 USA
Published by arrangement with John Wiley & Sons

Some of the defining characteristics of the IIG iron meteorite group are their high bulk P contents and massive, coarse schreibersite, which have been calculated to make up roughly 11–14 wt% of each specimen. In this study, we produced two data sets to investigate the formation of schreibersites in IIG irons: measurements of trace elements in the IIG iron meteorite Twannberg and experimental determinations of trace element partitioning into schreibersite. The schreibersite‐bearing experiments were conducted with schreibersite in equilibrium with a P‐rich melt and with bulk Ni contents ranging from 0 to 40 wt%. The partitioning behavior for the 20 elements measured in this study did not vary with Ni content. Comparison of the Twannberg measurements with the experimental results required a correction factor to account for the fact that the experiments were conducted in a simplified system that did not contain a solid metal phase. Previously determined solid metal/P‐rich melt partition coefficients were applied to infer schreibersite/solid metal partitioning behavior from the experiments, and once this correction was applied, the two data sets showed broad similarities between the schreibersite/solid metal distribution of elements. However, there were also differences noted, in particular between the Ni and P contents of the solid metal relative to the schreibersite inferred from the experiments compared to that measured in the Twannberg sample. These differences support previous interpretations that subsolidus schreibersite evolution has strongly influenced the Ni and P content now present in the solid metal phase of IIG irons. Quantitative attempts to match the IIG solid metal composition to that of late‐stage IIAB irons through subsolidus schreibersite growth were not successful, but qualitatively, this study corroborates the striking similarities between the IIAB and IIG groups, which are highly suggestive of a possible genetic link between the groups as has been previously proposed.

The brecciated texture of polymict eucrites: Petrographic investigations of unequilibrated meteorites from the Antarctic Yamato collection

1Christian Vollmer,1Stella Rombeck,2Julia Roszjar,3Adam R. Sarafian,1Stephan Klemme
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13453]
1Institut für Mineralogie, Westfälische Wilhelms‐Universität Münster, Corrensstrasse 24, D‐48149 Münster, Germany
2Department of Mineralogy and Petrography, Natural History Museum Vienna, Burgring 7, 1010 Vienna, Austria
3Science and Technology Division, Corning Incorporated, 21 Lynn Morse Rd., Painted Post, New York, New York, 14870 USA
Published by arrangement with John Wiley & Sons

We report on the petrography and mineralogy of five Yamato polymict eucrites to better constrain the formation and alteration of crustal material on differentiated asteroids. Each sample consists of different lithic clasts that altogether form four dominant textures and therefore appear to originate from closely related petrological areas within Vesta′s crust. The textures range from subophitic to brecciated, porphyritic, and quench‐textured, that differ from section to section. Comparison with literature data for these samples is therefore difficult, which stresses that polymict eucrites are extremely complex in their petrography and investigation of only one thick section may not be representative for the host rock. We also show that sample Y‐793548 consists of more than one lithic unit and must therefore be classified as polymict instead of monomict. The variety and nature of lithic textures in the investigated Yamato meteorites indicate shock events, intense post‐magmatic thermal annealing, and secondary alteration. These postmagmatic features occur in different intensities, varying from clast to clast or among coexisting mineral fragments on a small, local scale. Several clasts within the eucrites studied have been modified by late‐stage alteration processes that caused deposition of Fe‐rich olivine and Fe enrichment along cracks crosscutting pyroxene crystals. However, formation of these secondary phases seems to be independent of the degree of thermal metamorphism observed within every type of clast, which would support a late‐stage metasomatism model for their formation.

Evidence of presolar SiC in the Allende Curious Marie calcium–aluminium-rich inclusion

1O. Pravdivtseva,2F. L. H. Tissot,3N. Dauphas,1S. Amari
Nature Astronomy(In Press) Link to Article [DOIhttps://doi.org/10.1038/s41550-019-1000-z]
1Physics Department and McDonnell Center for the Space Sciences, Washington University, Saint Louis, MO, USA
2The Isotoparium, Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA, USA
3Origins Laboratory, Department of the Geophysical Sciences and Enrico Fermi Institute, The University of Chicago, Chicago, IL, USA

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Chemical and physical properties of Žďár nad Sázavou L chondrite and porosity differentiation using computed tomography

1Dominika Kalasová,1Tomáš Zikmund,2Pavel Spurný,3Jakub Haloda,2Jiří Borovička,1Jozef Kaiser
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13460]
1CEITEC – Central European Institute of Technology, Brno University of Technology, Purkyňova 123, Brno, Czech Republic
2Astronomical Institute of the Czech Academy of Sciences, Fričova 298, 25165 Ondřejov, Czech Republic
3Czech Geological Survey, Geologická 6, 152 00 Prague, Czech Republic
Published by arrangement with John Wiley & Sons

A very bright and long bolide was observed over the eastern part of the Czech Republic during late local evening on December 9, 2014. This bolide was recorded by professional instruments in the Czech part of the European Fireball Network. Three meteorites weighing in total 87 g were found in the predicted area and were named Žďár nad Sázavou. The complete material composition of the meteorite was obtained from one cut‐off piece using petrography, mineralogy, and scanning electron microscopy (together with X‐ray energy dispersive spectroscopy and wavelength dispersive spectroscopy). X‐ray computed tomography (CT) was applied on all pieces for the determination of their grain and bulk density, digitization of shape, and examination of the structural homogeneity. CT has proved its important role for nondestructive exploration of brecciated meteorites formed by distinct lithologies or petrological types. In this article, we discuss its limits in terms of structural and material resolution based on the correlation of state‐of‐the‐art CT data and SEM images. Furthermore, we introduce a new way of air cavity quantification, which distinguishes the natural porosity of meteorite and cracks related to erosion processes. This helps to discuss the presence of weathering products based on comparison of the meteorite pieces found at different times after impact.

 

Amorphous silicates in the matrix of Semarkona: The first evidence for the localized preservation of pristine matrix materials in the most unequilibrated ordinary chondrites

1E. Dobrică,1A. J. Brearley
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13458]
1Department of Earth and Planetary Sciences, MSC03‐2040, 1 University of New Mexico, Albuquerque, New Mexico, 87131‐0001 USA
Published by Arrangement with John Wiley & Sons

We have investigated the fine‐grained matrix of the least‐altered unequilibrated ordinary chondrite (UOC) Semarkona (LL3.00) using different electron microscope techniques. Unlike previous studies, which found that the matrix of Semarkona was extensively altered to phyllosilicates, we have discovered the widespread occurrence of much more pristine amorphous silicates in the sample that we have studied. Detailed TEM study shows that these materials occur pervasively in the matrix as (1) continuous groundmass; (2) distinct, circular to subrounded features, which contain nanometric‐size sulfides and carbides; or (3) distinct objects containing parallel, linear features composed of sulfides and voids. These amorphous silicates have many textural and compositional similarities to the occurrences of amorphous silicates found in pristine carbonaceous chondrites (CCs); however, minor differences were also identified. Most of the textural and chemical differences suggest that these materials formed at different times and locations in the solar nebula, compared to matrix materials in CCs. Nevertheless, their occurrence suggests that the amorphous silicates in Semarkona formed by similar processes to those proposed for amorphous silicates in CCs, that is, rapid cooling that favored disequilibrium condensation of material evaporated during chondrule‐forming events. In addition, the occurrence of minimally altered amorphous silicates in Semarkona demonstrates that the effects of aqueous alteration, which have been widely described in this meteorite, are not pervasive. Instead, our new observations demonstrate that aqueous alteration has affected Semarkona heterogeneously and that locally, regions of much more pristine matrix that have escaped extensive alteration are still preserved within this meteorite. Such materials provide significant new insights into the pristine characteristics of ordinary chondrite matrix material that has not been previously available.

Through the impact glass: Insight into the evolution of melt at the Mistastin Lake impact structure

1,2Patrick J. A. Hill,1,3Gordon R. Osinski,1,3Neil R. Banerjee
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13457]
1Department of Earth Sciences, University of Western Ontario, 1151 Richmond Street, London, Ontario, N6A 5B7 Canada
2Department of Earth and Atmospheric Sciences, University of Alberta, 1‐26 Earth Sciences Building, Alberta, T6G 2E3 Canada
3Institute for Earth and Space Exploration, University of Western Ontario, 1151 Richmond Street, London, Ontario, N6A 5B7 Canada
Published by arrangement with John Wiley & Sons

By analyzing impact glass, the evolution of the impact melt at the Mistastin Lake impact structure was investigated. Impact glass clasts are present in a range of impactites, including polymict breccias and clast‐rich impact melt rock, and from a variety of settings within the crater. From the glass clasts analyzed, three petrographic subtypes of impact glass were identified based on their clast content, prevalence of schlieren, color, texture, and habit. Several alteration phases were also observed replacing glass and infilling vesicles; however, textural observations and quantified compositional data allowed for the identification of pristine impact glass. Although the various types of glasses show significant overlap in their major oxide composition, several subtle variations in the major oxide chemistry of the glass were observed. To investigate this variation, a least‐squares mixing model was implemented utilizing the composition of the glass and the known target rock chemistry to model the initial melt composition. Additionally, image analysis of the glass clasts was used to investigate whether the compositional variations correlated to textural difference in the lithologies. We propose that the textural and compositional dichotomy observed is a product of the evolution, assimilation, and emplacement of the glass. The dichotomy is reflective of the melt either being ballistically emplaced (group 2 glasses: occurring in melt‐poor polymict breccias at lowermost stratigraphic position outside the transient crater) or the result of late‐stage melt flows (group 1 glasses, occurring in melt‐bearing polymict breccias and impact melt rocks at higher stratigraphic positions outside the transient crater).

Unique achondrite Northwest Africa 11042: Exploring the melting and breakup of the L chondrite parent body

1,2Zoltán Váci,1,2Carl B. Agee,3Munir Humayun,1,2Karen Ziegler,2Yemane Asmerom,2Victor Polyak,4Henner Busemann,4Daniela Krietsch,5Matthew Heizler,6Matthew E. Sanborn,6Qing‐Zhu Yin
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13456]
1Institute of Meteoritics, University of New Mexico, Albuquerque, New Mexico, 87131 USA
2Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, 87131 USA
3National High Magnetic Field Laboratory, Department of Earth Ocean & Atmospheric Science, Florida State University, Tallahassee, Florida, 32310 USA
4Institute of Geochemistry and Petrology, ETH Zürich, 8092 Zurich, Switzerland
5New Mexico Bureau of Geology, New Mexico Institute of Mining and Technology, Socorro, New Mexico, 87801 USA
6Department of Earth and Planetary Sciences, University of California, Davis, Davis, California, 95616 USA
Published by arrangement with John Wiley & Sons

Northwest Africa (NWA) 11042 is a heavily shocked achondrite with medium‐grained cumulate textures. Its olivine and pyroxene compositions, oxygen isotopic composition, and chromium isotopic composition are consistent with L chondrites. Sm‐Nd dating of its primary phases shows a crystallization age of 4100 ± 160 Ma. Ar‐Ar dating of its shocked mineral maskelynite reveals an age of 484.0 ± 1.5 Ma. This age coincides roughly with the breakup event of the L chondrite parent body evident in the shock ages of many L chondrites and the terrestrial record of fossil L chondritic chromite. NWA 11042 shows large depletions in siderophile elements (<0.01×CI) suggestive of a complex igneous history involving extraction of a Fe‐Ni‐S liquid on the L chondrite parent body. Due to its relatively young crystallization age, the heat source for such an igneous process is most likely impact. Because its mineralogy, petrology, and O isotopes are similar to the ungrouped achondrite NWA 4284 (this work), the two meteorites are likely paired and derived from the same parent body.

In situ analysis of platinum group elements in equilibrated ordinary chondrite kamacite and taenite

1Cosette M. Gilmour,1Christopher D. K. Herd
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13436]
1Department of Earth and Atmospheric Sciences, University of Alberta, 1‐26 Earth Sciences Building, Edmonton, AB, T6G 2E3 Canada
Published by arrangement with John Wiley & Sons

Platinum group element (PGE) concentrations have been determined in situ in ordinary chondrite kamacite and taenite grains via laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS). Results demonstrate that PGE concentrations in ordinary chondrite metal (kamacite and taenite) are similar among the three ordinary chondrite groups, in contrast to previous bulk metal studies in which PGE concentrations vary in the order H < L < LL. PGE concentrations are higher in taenite than kamacite, consistent with preferential PGE partitioning into taenite. PGE concentrations vary between and within metal grains, although average concentrations in kamacite broadly agree with results from bulk studies. The variability of PGE concentrations in metal decreases with increasing petrologic type; however, variability is still evident in most type six ordinary chondrites, suggesting that equilibration of PGEs does not occur between metal grains, but rather within individual metal grains via self‐diffusion during metamorphism. The constant average PGE concentrations within metal grains across different ordinary chondrite groups are consistent with the formation of metal via nebular condensation prior to the accretion of ordinary chondrite parent bodies. Post‐condensation effects, including heating during chondrule‐formation events, may have affected some element ratios, but have not significantly affected average metal PGE concentrations.

Characterizing organic particle impacts on inert metal surfaces: Foundations for capturing organic molecules during hypervelocity transits of Enceladus plumes

1,2J. S. New,1,3R. A. Mathies,2M. C. Price,2M. J. Cole,1,3M. Golozar,2V. Spathis,2M. J. Burchell,1A. L. Butterworth
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13448]
1Space Sciences Laboratory, University of California, Berkeley, 7 Gauss Way, Berkeley, California, 94720 USA
2School of Physical Sciences, University of Kent, Canterbury, Kent, CT2 7NH UK
3Department of Chemistry, University of California, Berkeley, California, 94720 USA
Published by arrangement with John Wiley & Sons

The presence and accessibility of a sub‐ice‐surface saline ocean at Enceladus, together with geothermal activity and a rocky core, make it a compelling location to conduct further, in‐depth, astrobiological investigations to probe for organic molecules indicative of extraterrestrial life. Cryovolcanic plumes in the south polar region of Enceladus enable the use of remote in situ sampling and analysis techniques. However, efficient plume sampling and the transportation of captured organic materials to an organic analyzer present unique challenges for an Enceladus mission. A systematic study, accelerating organic ice‐particle simulants into soft inert metal targets at velocities ranging 0.5–3.0 km s−1, was carried out using a light gas gun to explore the efficacy of a plume capture instrument. Capture efficiency varied for different metal targets as a function of impact velocity and particle size. Importantly, organic chemical compounds remained chemically intact in particles captured at speeds up to ~2 km s−1. Calibration plots relating the velocity, crater, and particle diameter were established to facilitate future ice‐particle impact experiments where the size of individual ice particles is unknown.