Phoebe’s carbon isotope composition as evidence for self-shielding in the solar nebula

1,2,3Marc Neveu,4Christopher H.House,2,3,5Scott T.Wieman
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113714]
1Department of Astronomy, University of Maryland, 4296 Stadium Dr., College Park, MD 20742, USA
2Planetary Environments Laboratory, NASA Goddard Space Flight Center, 8800 Greenbelt Rd., Greenbelt, MD 20770, USA
3Center for Research in Space Science and Technology, NASA Goddard Space Flight Center, 8800 Greenbelt Rd., Greenbelt, MD 20770, USA
4Department of Geosciences, Pennsylvania State University, 503 Deike Building, University Park, PA 16802, USA
5Center for Space Sciences and Technology, University of Maryland, Baltimore County, 1000 Hilltop Cir., Baltimore, MD 21250, USA
Copyright Elsevier

Clark et al. [Clark, R.N., Brown, R.H., Cruikshank, D.P., Swayze, G.A., 2019. Icarus, 321, 791–802] reported an extremely low value of the 12C/13C ratio in CO2 ice on Phoebe, a likely captured moon of Saturn. Unless Phoebe did not form in the solar system, we interpret this value as indication that Phoebe accreted surface carbon from a region of the protosolar nebula where 13C was enriched due to self-shielding of 12CO from photodissociation. This could imply that Phoebe is also enriched in 17,18O relative to most solar system objects sampled to date. Phoebe and other objects that may have sampled these 13C-rich regions, such as Pallas or Triton, may provide the opportunity to directly measure isotopic fractionations in endmembers of the self-shielded solar nebula.

Sr-Nd-Pb isotope systematics of Australasian tektites: Implications for the nature and composition of target materials and possible volatile loss of Pb

1Lukáš Ackerman,1Karel Žák,1Roman Skála,1Jan Rejšek,1Šárka Křížová,2Josh Wimpenny,3Tomáš Magna
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2020.02.025]
1Institute of Geology of the Czech Academy of Sciences, Rozvojová 269, CZ-165 00 Praha 6, Czech Republic
2Lawrence Livermore National Laboratory, Livermore, CA 94550, USA
3Czech Geological Survey, Klárov 3, CZ-118 21 Praha 1, Czech Republic
Copyright Elsevier

The Australasian tektite (AAT) strewn field is the largest strewn field on the Earth with about ∼10–30% coverage, both land and ocean, but a clearly identified source impact crater is absent despite the young age of AAT of ca. 790 ka. A genetic link between the Australasian tektites and their unequivocal parental materials is therefore largely impossible to establish. Nevertheless, the nature of the parental materials and the extent of volatilization can be constrained using the splash form tektites, carrying the chemical signatures of high-temperature processes, and the layered (so-called Muong Nong-type) tektites, which are less chemically homogenized and exceptionally abundant in the AAT field. New high-precision Sr, Nd and Pb isotopic measurements were obtained for a chemically and petrographically well-characterized suite of AAT, which included the Muong Nong-type (MN-AAT) with precisely known field locations in Laos and splash forms (SF-AAT) from different parts of the strewn field. In addition, optically dark and light zones of the MN-AAT were also separately analyzed. Homogeneous εNd values from −11.8 to −11.2, combined with a narrow range of two-stage Nd model ages from 1.67 to 1.72 Ga for the entire AAT suite, point to a well-mixed source, in terms of REE, of the crustal segment from which the sedimentary material for tektites was ultimately derived. The Sr isotopic data largely overlap for SF-AAT and MN-AAT (87Sr/86Sr = 0.71636–0.72021) and indicate Paleozoic to Mesozoic sedimentary parentage. However, late Neogene to early Quaternary re-deposition and formation of a thick silt-sized sedimentary section with vertical stratification is required to comply with 10Be data. Lead isotope systematics documents at least three different components which can perhaps be represented by different mineral phases, such as feldspar, zircon, organic matter adsorbed on young sediments etc., sorted during fluvial transport and final deposition. In addition, the SF-AAT have systematically lower Pb contents than the MN-AAT, and generally show isotopically heavier Pb isotopic ratios. This is theoretically consistent with a preferential volatilization of lighter Pb isotopes during evaporation and considerably larger Pb loss from SF-AAT when compared to MN-AAT. Nevertheless, further experimental work would be necessary to unambiguously distinguish kinetic fractionation from source mixing.