Chemical and physical properties of Žďár nad Sázavou L chondrite and porosity differentiation using computed tomography

1Dominika Kalasová,1Tomáš Zikmund,2Pavel Spurný,3Jakub Haloda,2Jiří Borovička,1Jozef Kaiser
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13460]
1CEITEC – Central European Institute of Technology, Brno University of Technology, Purkyňova 123, Brno, Czech Republic
2Astronomical Institute of the Czech Academy of Sciences, Fričova 298, 25165 Ondřejov, Czech Republic
3Czech Geological Survey, Geologická 6, 152 00 Prague, Czech Republic
Published by arrangement with John Wiley & Sons

A very bright and long bolide was observed over the eastern part of the Czech Republic during late local evening on December 9, 2014. This bolide was recorded by professional instruments in the Czech part of the European Fireball Network. Three meteorites weighing in total 87 g were found in the predicted area and were named Žďár nad Sázavou. The complete material composition of the meteorite was obtained from one cut‐off piece using petrography, mineralogy, and scanning electron microscopy (together with X‐ray energy dispersive spectroscopy and wavelength dispersive spectroscopy). X‐ray computed tomography (CT) was applied on all pieces for the determination of their grain and bulk density, digitization of shape, and examination of the structural homogeneity. CT has proved its important role for nondestructive exploration of brecciated meteorites formed by distinct lithologies or petrological types. In this article, we discuss its limits in terms of structural and material resolution based on the correlation of state‐of‐the‐art CT data and SEM images. Furthermore, we introduce a new way of air cavity quantification, which distinguishes the natural porosity of meteorite and cracks related to erosion processes. This helps to discuss the presence of weathering products based on comparison of the meteorite pieces found at different times after impact.

 

Amorphous silicates in the matrix of Semarkona: The first evidence for the localized preservation of pristine matrix materials in the most unequilibrated ordinary chondrites

1E. Dobrică,1A. J. Brearley
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13458]
1Department of Earth and Planetary Sciences, MSC03‐2040, 1 University of New Mexico, Albuquerque, New Mexico, 87131‐0001 USA
Published by Arrangement with John Wiley & Sons

We have investigated the fine‐grained matrix of the least‐altered unequilibrated ordinary chondrite (UOC) Semarkona (LL3.00) using different electron microscope techniques. Unlike previous studies, which found that the matrix of Semarkona was extensively altered to phyllosilicates, we have discovered the widespread occurrence of much more pristine amorphous silicates in the sample that we have studied. Detailed TEM study shows that these materials occur pervasively in the matrix as (1) continuous groundmass; (2) distinct, circular to subrounded features, which contain nanometric‐size sulfides and carbides; or (3) distinct objects containing parallel, linear features composed of sulfides and voids. These amorphous silicates have many textural and compositional similarities to the occurrences of amorphous silicates found in pristine carbonaceous chondrites (CCs); however, minor differences were also identified. Most of the textural and chemical differences suggest that these materials formed at different times and locations in the solar nebula, compared to matrix materials in CCs. Nevertheless, their occurrence suggests that the amorphous silicates in Semarkona formed by similar processes to those proposed for amorphous silicates in CCs, that is, rapid cooling that favored disequilibrium condensation of material evaporated during chondrule‐forming events. In addition, the occurrence of minimally altered amorphous silicates in Semarkona demonstrates that the effects of aqueous alteration, which have been widely described in this meteorite, are not pervasive. Instead, our new observations demonstrate that aqueous alteration has affected Semarkona heterogeneously and that locally, regions of much more pristine matrix that have escaped extensive alteration are still preserved within this meteorite. Such materials provide significant new insights into the pristine characteristics of ordinary chondrite matrix material that has not been previously available.

Through the impact glass: Insight into the evolution of melt at the Mistastin Lake impact structure

1,2Patrick J. A. Hill,1,3Gordon R. Osinski,1,3Neil R. Banerjee
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13457]
1Department of Earth Sciences, University of Western Ontario, 1151 Richmond Street, London, Ontario, N6A 5B7 Canada
2Department of Earth and Atmospheric Sciences, University of Alberta, 1‐26 Earth Sciences Building, Alberta, T6G 2E3 Canada
3Institute for Earth and Space Exploration, University of Western Ontario, 1151 Richmond Street, London, Ontario, N6A 5B7 Canada
Published by arrangement with John Wiley & Sons

By analyzing impact glass, the evolution of the impact melt at the Mistastin Lake impact structure was investigated. Impact glass clasts are present in a range of impactites, including polymict breccias and clast‐rich impact melt rock, and from a variety of settings within the crater. From the glass clasts analyzed, three petrographic subtypes of impact glass were identified based on their clast content, prevalence of schlieren, color, texture, and habit. Several alteration phases were also observed replacing glass and infilling vesicles; however, textural observations and quantified compositional data allowed for the identification of pristine impact glass. Although the various types of glasses show significant overlap in their major oxide composition, several subtle variations in the major oxide chemistry of the glass were observed. To investigate this variation, a least‐squares mixing model was implemented utilizing the composition of the glass and the known target rock chemistry to model the initial melt composition. Additionally, image analysis of the glass clasts was used to investigate whether the compositional variations correlated to textural difference in the lithologies. We propose that the textural and compositional dichotomy observed is a product of the evolution, assimilation, and emplacement of the glass. The dichotomy is reflective of the melt either being ballistically emplaced (group 2 glasses: occurring in melt‐poor polymict breccias at lowermost stratigraphic position outside the transient crater) or the result of late‐stage melt flows (group 1 glasses, occurring in melt‐bearing polymict breccias and impact melt rocks at higher stratigraphic positions outside the transient crater).