1,2M. E. I. RIEBE,1H. BUSEMANN,2C. M. O’D. ALEXANDER,2L. R. NITTLER,3C. D. K. HERD,1C. MADEN,2J. WANG,1R. WIELER
Meteoritics & Planetary Science (in Press) Link to Article [doi: 10.1111/maps.13383]
1Institute of Geochemistry and Petrology, ETH Zurich, CH-8092, Zurich, Switzerland
2DTM, Carnegie Institution of Washington, 5241 Broad Branch Road, Washington, District of Columbia 20015, USA
3Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta T6G 2E3, Canada
Published by arrangement with John Wiley & Sons
Effects of aqueous alteration on primordial noble gas carriers were investigated by analyzing noble gases and determining presolar SiC abundances in insoluble organic matter (IOM) from four Tagish Lake meteorite (C2-ung.) samples that experienced different degrees of aqueous alteration. The samples contained a mixture of primordial noble gases from phase Q and presolar nanodiamonds (HL, P3), SiC (Ne-E[H]), and graphite (Ne-E[L]). The second most altered sample (11i) had a ~2–3 times higher Ne-E concentration than the other samples. The presolar SiC abundances in the samples were determined from NanoSIMS ion images and 11i had a SiC abundance twice that of the other samples. The heterogeneous distribution of SiC grains could be inherited from heterogeneous accretion or parent body alteration could have redistributed SiC grains. Closed system step etching (CSSE) was used to study noble gases in HNO3-susceptible phases in the most and least altered samples. All Ne-E carried by presolar SiC grains in the most altered sample was released during CSSE, while only a fraction of the Ne-E was released from the least altered sample. This increased susceptibility to HNO3 likely represents a step toward degassing. Presolar graphite appears to have been partially degassed during aqueous alteration. Differences in the 4He/36Ar and 20Ne/36Ar ratios in gases released during CSSE could be due to gas release from presolar nanodiamonds, with more He and Ne being released in the more aqueously altered sample. Aqueous alteration changes the properties of presolar grains so that they react similar to phase Q in the laboratory, thereby altering the perceived composition of Q.