Raman Spectroscopy of High-Pressure Phases in Shocked L6 Chondrite NWA 5011

1,2Litasov, K.D.,3Badyukov, D.D.
Geochemistry International 57, 912-922 Link to Article [DOI: 10.1134/S001670291908007X]
1Sobolev Institute of Geology and Mineralogy, Siberian Branch of the Russian Academy of Sciences, prosp. Akademika Koptyuga 3, Novosibirsk, 630090, Russian Federation
2Novosibirsk State University, ul. Pirogova 2, Novosibirsk, 630090, Russian Federation
3Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, ul. Kosygina 19, Moscow, 119991, Russian Federation

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Acquisition of terrestrial Neon during accretion – a mixture of solar wind and planetary components

1,2Manfred Vogt,1Jens Hopp,3Hans-Peter Gail,4,5Ulrich Otta,1Mario Trieloff
Geochimica et Cosmochimcia Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2019.08.016]
1Institut für Geowissenschaften, Klaus-Tschira-Labor für Kosmochemie, Universität Heidelberg, INF 236, 69120 Heidelberg, Germany
2Institut für Nukleare Entsorgung (INE), Karlsruher Institut of Technologie (KIT), Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen, Germany
3Institut für Theoretische Astrophysik, Zentrum für Astronomie, Universität Heidelberg, Albert-Ueberle-Str. 2, 69120 Heidelberg, Germany
4MTA Atomki, Bem tér 18/c, 4026 Debrecen, Hungary
5Max-Planck-Institut für Chemie, Hahn-Meitner-Weg 1, 55128 Mainz, Germany
Copyright Elsevier

Earth’s mantle contains Ne resembling the solar wind implanted Ne-B component in meteorites (20Ne/22NeNe-B: ∼12.7). The atmosphere, instead, displays a “planetary” signature (20Ne/22NeAtm: 9.80). We explore the parameter space of a model that explains these isotopic variations by the contribution of late accreting volatile-rich material (e.g., carbonaceous chondrite-like) to Earth́s atmosphere, while Earth́s mantle incorporated solar wind type Ne that was previously implanted into part of the accreting material.

Analyses of the present-day terrestrial influx mass distributions show two major peaks at large bodies >1km and small ∼200 µm dust particles. The latter dominate the influx of the surface implanted Ne-B component. Ne measurements of small particles define a maximum surface flux (neon reaching the terrestrial surface) peaking at 9 µm, while larger micrometeorites experience ablation losses and isotopic fractionation upon atmospheric entry. Using these data, we reconstruct the unfractionated Ne-B upper atmosphere flux which peaks at ∼75 µm. As the extraterrestrial influx mass distribution between larger bodies and debris dust is governed by equilibrium due to collisions and fragmentation, it is an approximation of the early solar system (after nebula dissipation), where the mass distribution was similar but total fluxes were higher.

Contributions of Ne-B by small dust and planetary Ne-A from larger bodies strongly depend on formation region. Originating around the 1 AU region, early accretionary fluxes were dominated by Ne-B as large bodies likely contained only negligible amounts of Ne-A. Ne-B will be ultimately delivered to the earliest protoatmosphere by impact or thermal degassing and a significant fraction of Ne-B can enter the Earth́s interior via dissolution into a magma ocean before the Moon-forming impact. After the Moon-forming impact, Ne-B reenters the atmosphere by mantle degassing and a later meteoritic contribution modified the atmospheric composition. This meteoritic component was likely dominated by Ne-A, as the only remaining planetesimals at that time were in the asteroid belt or beyond, leading to preferential contributions of carbonaceous chondrite-type material.

In our model we take into account possible variations of several parameters, e.g. the isotopic composition of the late accretion (i.e., 20Ne/22Ne: 5.2–9.2). For example, a 20Ne/22Ne ratio of 8.2 (Ne-A composition) would imply ∼2% mass increase of Earth from CC-type material after the Moon-forming impact, and would require that todaýs atmosphere (20Ne/22Ne=9.8) formed by roughly equal mixing of late accreted Ne-A and mantle Ne-B. The amount of Ne-B added from the mantle implies a certain degree of mantle degassing (in this case 82–96%, depending on todaýs mantle neon inventory) and constrains two further parameters: the fraction of solar wind irradiated material delivered to Earth before the Moon-forming impact and the magma ocean depth. The latter determines the fraction of Ne-B dissolved from a protoatmosphere. For example, magma ocean depths between 500 and 2900 km allow 4–15% dissolution of the protoatmospheric Ne-B inventory, and would require only less than 10% of irradiated accreting material. Only unreasonable magma ocean depths lower than 200 km require several ten percent of irradiated material.

Theoretical Analysis of Mg and Si Chemical and Isotopic Fractionation at Vaporization of Ca–Al Inclusions of Chondrite

1Yakovlev, O.I., 1Shornikov, S.I.
Geochemistry International 57, 851-864 Link to Article [DOI: 10.1134/S0016702919080123]
1Vernadsky Institute of Geochemistry and Analytical Chemistry (GEOKhI), Russian Academy of Sciences, Moscow, 119991, Russian Federation

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Classification of Iron Meteorites with High Frequency Ultrasonic Waves

1El Abassi, D.,1Faiz, B.,2,3Ibhi, A.,1Aboudaoud, I.
Journal of Environmental and Engineering Geophysics 24, 277-285 Link to Article [DOI: 10.2113/JEEG24.2.277]
1Laboratory of Metrology and Information Processing, Faculty of Sciences, Ibn Zohr University, Agadir, Morocco
2Laboratory of Petrology, Metallogeny and Meteorites, Department of Geology, Ibn Zohr University, Agadir, Morocco
3University Museum of Meteorites, Ibn Zohr University Complex, Agadir, Morocco

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The Yamato-type (CY) carbonaceous chondrite group: Analogues for the surface of asteroid Ryugu?

1A.J.King,1,2H.C.Bates,3D.Krietsch,3H.Busemann,4P.L.Clay,1P.F.Schofield,1S.S.Russell
Geochemistry (Chemie der Erde) (In Press) Link to Article [https://doi.org/10.1016/j.chemer.2019.08.003]
1Planetary Materials Group, Department of Earth Sciences, Natural History Museum, Cromwell Road, London, SW7 5BD, UK
2Atmospheric, Oceanic and Planetary Physics Department, Clarendon Laboratory, University of Oxford, Sherrington Road, Oxford, OX1 3P, UK
3Institute of Geochemistry and Petrology, ETH Zürich, Clausiusstrasse 25, 8092 Zürich, Switzerland
4School of Earth and Environmental Sciences, University of Manchester, Manchester, M13 9PL, UK
Copyright Elsevier

We report new mineralogical, petrographic and noble gas analyses of the carbonaceous chondrite meteorites Y-82162 (C1/2ung), Y-980115 (CI1), Y-86029 (CI1), Y-86720 (C2ung), Y-86789 (C2ung), and B-7904 (C2ung). Combining our results with literature data we show that these meteorites experienced varying degrees of aqueous alteration followed by short-lived thermal metamorphism at temperatures of >500 °C. These meteorites have similar mineralogy, textures and chemical characteristics suggesting that they are genetically related, and we strongly support the conclusion of Ikeda (1992) that they form a distinct group, the CYs (“Yamato-type”). The CY chondrites have the heaviest oxygen isotopic compositions (δ17O ˜12 ‰, δ18O ˜22 ‰) of any meteorite group, high abundances of Fe-sulphides (˜10 ‒ 30 vol%) and phosphates, and contain large grains of periclase and unusual objects of secondary minerals not reported in other carbonaceous chondrites. These features cannot be attributed to parent body processes alone, and indicate that the CYs had a different starting mineralogy and/or alteration history to other chondrite groups, perhaps because they formed in a different region of the protoplanetary disk. The short cosmic-ray exposure ages (≤1.3 Ma) of the CY chondrites suggest that they are derived from a near-Earth source, with recent observations by the Hayabusa2 spacecraft highlighting a possible link to the rubble-pile asteroid Ryugu.

Images from the surface of asteroid Ryugu show rocks similar to carbonaceous chondrite meteorites

1,2R.Jaumann et al. (>10)
Science 365, 817-820 Link to Article [DOI: 10.1126/science.aaw8627]
1German Aerospace Center (DLR), Institute of Planetary Research, Berlin, Germany.
2Free University of Berlin, Institute of Geosciences, Berlin, Germany.
Reprinted with permission from AAAS

The near-Earth asteroid (162173) Ryugu is a 900-m-diameter dark object expected to contain primordial material from the solar nebula. The Mobile Asteroid Surface Scout (MASCOT) landed on Ryugu’s surface on 3 October 2018. We present images from the MASCOT camera (MASCam) taken during the descent and while on the surface. The surface is covered by decimeter- to meter-sized rocks, with no deposits of fine-grained material. Rocks appear either bright, with smooth faces and sharp edges, or dark, with a cauliflower-like, crumbly surface. Close-up images of a rock of the latter type reveal a dark matrix with small, bright, spectrally different inclusions, implying that it did not experience extensive aqueous alteration. The inclusions appear similar to those in carbonaceous chondrite meteorites.

The rio do pires chondrite: Petrographic and minaral chemistry Features [O Condrito Rio do Pires: Aspectos petrográficos e mineraloquímicos]

1,2De Carvalho, W.P.,1,2Rios, D.C.,3Zucolotto, M.E.,1,2,4Conceição, H.,5Tosi, A.A.,2Gomes, M.M.
Pesquisas em Geosciencias 45, e0666 Link to Article [DOI: 10.22456/1807-9806.88647]
1Universidade Federal da Bahia, Rua Barão de Jeremoabo, 147, Salvador, BA CEP 40.170-115, Brazil
2Grupo de Pesquisa Laboratório de Petrologia Aplicada à Pesquisa Mineral, Rua Barão de Jeremoabo, 147, Salvador, BA CEP 40.170-115, Brazil
3Museu Naciona, Universidade Federal do Rio de Janeiro, Quinta da Boa Vista. São Cristóvão, Rio de Janeiro, RJ CEP 20940-040, Brazil
4Universidade Federal de Sergipe, Av. Marechal Rondon, Jardim Rosa Elze, São Cristóvão, SE CEP 49.100-000, Brazil
5Labsonda, Instituto de Geociências, Universidade Federal do Rio de Janeiro, Av. Athos da Silveira Ramos, 274, Cidade Universitária, Ilha do Fundão, Rio de Janeiro, RJ CEP 21044-020, Brazil

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La Réunion Island dunites as analogs of the Martian chassignites: Tracking trapped melts with incompatible trace elements

1Barrat, J.-A.,2Bachèlery, P.
Lithos 344-345, 452-463 Link to Article [DOI: 10.1016/j.lithos.2019.07.009]
1Univ Brest, CNRS, UMR 6538 (Laboratoire Géosciences Océan), Institut Universitaire Européen de la Mer (IUEM), Place Nicolas Copernic, Plouzané, 29280, France
2Université Clermont Auvergne, CNRS, IRD, OPGC, Laboratoire Magmas et Volcans, 6 avenue Blaise Pascal, Aubière, 63178, France

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Cr isotopes in physically separated components of the Allende CV3 and Murchison CM2 chondrites: Implications for isotopic heterogeneity in the solar nebula and parent body processes

1Yogita Kadlag,1Harry Becker,1Andreas Harbott
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13375]
1Institut für Geologische Wissenschaften, Freie Universität Berlin, Malteserstr. 74‐100, 12249 Berlin, Germany
Published by arrangement with John Wiley & Sons

Chromium isotopic data of physically separated components (chondrules, CAIs, variably magnetic size fractions) of the carbonaceous chondrites Allende and Murchison and bulk rock data of Allende, Ivuna, and Orgueil are reported to evaluate the origin of isotopic heterogeneity in these meteorites. Allende components show ε53Cr and ε54Cr from −0.23 ± 0.07 to 0.37 ± 0.05 and from −0.43 ± 0.08 to 3.7 ± 0.1, respectively. In components of Murchison, ε53Cr and ε54Cr vary from −0.06 ± 0.08 to 0.5 ± 0.1 and from 0.7 ± 0.2 to 1.7 ± 0.1, respectively. The non‐systematic variations of ε53Cr and 55Mn/52Cr in the components of Allende and Murchison were likely caused by small‐scale, alteration‐related redistribution of Mn >20 Ma after formation of the solar system. Chondrule fractions show the lowest 55Mn/52Cr and ε54Cr values of all components, consistent with evaporation of Mn and ε54Cr‐rich carrier phases from chondrule precursors. Components other than the chondrules show higher Mn/Cr and ε54Cr, suggestive of chemical and isotopic complementarity between chondrules and matrix‐rich fractions. Bulk rock compositions calculated based on weighted compositions of components agree with measured Cr isotope data of bulk rocks, in spite of the Cr isotopic heterogeneity reported by the present and previous studies. This indicates that on a sampling scale comprising several hundred milligrams, these meteorites sampled isotopically and chemically homogeneous nebular reservoirs. The linear correlation of 55Mn/52Cr with ε53Cr in bulk rocks likely was caused by variable fractionation of Mn/Cr, subsequent mixing of phases in nebular domains, and radiogenic ingrowth of 53Cr.