1Yogita Kadlag,1Harry Becker,1Andreas Harbott
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13375]
1Institut für Geologische Wissenschaften, Freie Universität Berlin, Malteserstr. 74‐100, 12249 Berlin, Germany
Published by arrangement with John Wiley & Sons
Chromium isotopic data of physically separated components (chondrules, CAIs, variably magnetic size fractions) of the carbonaceous chondrites Allende and Murchison and bulk rock data of Allende, Ivuna, and Orgueil are reported to evaluate the origin of isotopic heterogeneity in these meteorites. Allende components show ε53Cr and ε54Cr from −0.23 ± 0.07 to 0.37 ± 0.05 and from −0.43 ± 0.08 to 3.7 ± 0.1, respectively. In components of Murchison, ε53Cr and ε54Cr vary from −0.06 ± 0.08 to 0.5 ± 0.1 and from 0.7 ± 0.2 to 1.7 ± 0.1, respectively. The non‐systematic variations of ε53Cr and 55Mn/52Cr in the components of Allende and Murchison were likely caused by small‐scale, alteration‐related redistribution of Mn >20 Ma after formation of the solar system. Chondrule fractions show the lowest 55Mn/52Cr and ε54Cr values of all components, consistent with evaporation of Mn and ε54Cr‐rich carrier phases from chondrule precursors. Components other than the chondrules show higher Mn/Cr and ε54Cr, suggestive of chemical and isotopic complementarity between chondrules and matrix‐rich fractions. Bulk rock compositions calculated based on weighted compositions of components agree with measured Cr isotope data of bulk rocks, in spite of the Cr isotopic heterogeneity reported by the present and previous studies. This indicates that on a sampling scale comprising several hundred milligrams, these meteorites sampled isotopically and chemically homogeneous nebular reservoirs. The linear correlation of 55Mn/52Cr with ε53Cr in bulk rocks likely was caused by variable fractionation of Mn/Cr, subsequent mixing of phases in nebular domains, and radiogenic ingrowth of 53Cr.