New minerals tsangpoite Ca 5 (PO 4 ) 2 (SiO 4 ) and matyhite Ca 9 (Ca 0.5 □ 0.5 )Fe(PO 4 ) 7 from the D’Orbigny angrite

1Hwang, S.-L.,2Shen, P.,3Chu, H.-T.,4Yui, T.-F.,5Varela, M.-E.,4Iizuka, Y.
Mineralogical Magazine 83, 293-313 Link to Article [DOI: 10.1180/mgm.2018.125]
1Department of Materials Science and Engineering, National Dong Hwa University, Hualien, Taiwan
2Department of Materials Science and Optoelectronic Science, National Sun Yat-sen University, Kaohsiung, Taiwan
3Central Geological Survey, PO Box 968, Taipei, Taiwan
4Institute of Earth Sciences, Academia Sinica, Taipei, Taiwan
5Instituto de Ciencias Astronómicas de la Tierra y Del Espacio (ICATE), Avenida España 1512 sur, San Juan, J5402DSP, Argentina

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Interplanetary Dust, Meteoroids, Meteors and Meteorites (Review)

1,2Koschny, D. et al. (>10)
Space Science Reviews 215, 34 Link to Article [DOI: 10.1007/s11214-019-0597-7]
1SCI-S, European Space Agency, Keplerlaan 1, Noordwijk ZH, 2200 AZ, Netherlands
2Lehrstuhl für Raumfahrttechnik, Technische Universität München, Boltzmannstr. 15, Garching, 85748, Germany

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Are hypervelocity impacts able to produce chondrule-like ejecta?

1Clément Ganino,2,3Guy Libourel,4Akiko M.Nakamura,2Patrick Michel
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2019.06.008]
1Université Côte D’Azur, OCA, CNRS, Géoazur, 250 Rue Albert Einstein, Sophia-Antipolis, 06560, Valbonne, France
2Université Côte D’Azur, OCA, CNRS, Lagrange, Boulevard de L’Observatoire, CS 34229, 06304, Nice Cedex 4, France
3Hawai‘i Institute of Geophysics and Planetology, School of Ocean, Earth Science and Technology, University of Hawai‘i at Mānoa, Honolulu, Hawai‘i, 96821, USA
4Graduate School of Science, Kobe University, 1-1 Rokkoudai-cho, Nada-ku, Kobe, 657-8501, Japan

 

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Deciphering the conditions of tochilinite and cronstedtite formation in CM chondrites from low temperature hydrothermal experiments

1Lionel G. Vacher,2Laurent Truche,1François Faure,1Laurent Tissandier,3Régine Mosser‐Ruck,1Yves Marrocchi
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13317]
1CRPG, CNRS, Université de Lorraine, UMR 7358, Vandoeuvre‐les‐Nancy, F‐54501 France
2ISTerre, UMR 5275, CNRS, Université Grenoble Alpes, 1381 rue de la Piscine, BP53 38041 Grenoble, CEDEX 9, France
3GeoRessources, UMR 7359, CNRS, Université de Lorraine, Campus Aiguillettes, 54506 Vandoeuvre‐lès‐Nancy, France
Published by arrangement with John Wiley & Sons

Tochilinite/cronstedtite intergrowths are commonly observed as alteration products in CM chondrite matrices, but the conditions under which they formed are still largely underconstrained due to their scarcity in terrestrial environments. Here, we report low temperature (80 °C) anoxic hydrothermal experiments using starting assemblages similar to the constituents of the matrices of the most pristine CM chondrite and S‐rich and S‐free fluids. Cronstedtite crystals formed only in S‐free experiments under circumneutral conditions with the highest Fe/Si ratios. Fe‐rich tochilinite with chemical and structural characteristics similar to chondritic tochilinite was observed in S‐bearing experiments. We observed a positive correlation between the Mg content in the hydroxide layer of synthetic tochilinite and temperature, suggesting that the composition of tochilinite is a proxy for the alteration temperature in CM chondrites. Using this relation, we estimate the mean precipitation temperatures of tochilinite to be 120–160 °C for CM chondrites. Given the different temperature ranges of tochilinite and cronstedtite in our experiments, we propose that Fe‐rich tochilinite crystals resulted from the alteration of metal beads under S‐bearing alkaline conditions at T = 120–160 °C followed by cronstedtite crystals formed by the reaction of matrix amorphous silicates, metal beads, and water at a low temperature (50–120 °C).

Bombardment history of Asteroid 4 Vesta recorded by brecciated eucrites: Large impact event clusters at 4.50 Ga and discreet bombardment until 3.47 Ga

1Trudi Kennedy,1Fred Jourdan,2Ela Eroglu,1Celia Mayers
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2019.06.027]
1Western Australian Argon Isotope Facility, JdL Centre & Applied Geology, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia
2Department of Chemical Engineering, Curtin University, GPO Box U1987, Perth, Western Australia 6845, Australia
Copyright Elsevier

The thermal/impact histories of sixteen eucrite meteorites were investigated: three monomict eucrites (NWA 999, A-87272,87, and Stannern), five polymict eucrites (NWA 1000, NWA 1666, NWA 5601, Y-980066,100, and Y-980255,100), three quench-textured, eucrite melt rocks (Y-981646,21, Y-981651,105, and MIL 0766214), one eucrite dominantly comprised of quench-textured clasts (QUE 99005,11), three unclassified eucrite breccias (LAP 031316,9, LAR 06870,5, QUE 99799,4) and one unbrecciated eucrite (EET 92004,17), included here due to its shock features. We have measured fifteen high-precision new 40Ar/39Ar plateau ages on plagioclase and matrix for ten of these meteorites with a tight cluster of nine ages obtained from three different polymict breccias. These ages range from 4534 ± 56 Ma to 4491 ± 16 Ma resulting in a concordant age population (P = 0.16). The fact that such a cluster of ages is recorded in unrelated breccias which are made of a priori unrelated components, leads us to propose that those ages recorded a single heating event on a large scale, and is interpreted here as a high-energy impact event, early in the history of Vesta at 4500 ± 4 Ma. We propose that the debris was ejected and isolated from subsequent large impacts in a secondary rubble pile asteroid where the energy of the outgoing shock wave from an impact is significantly reduced as it compacts the target material (Holsapple et al., 2002, and references therein) .

The other analyses define a spread of five plateau ages ranging from 3851± 21 Ma to 3469 ± 35 Ma, over ∼380 Ma. An additional apparent plateau age of 4288 ± 38 Ma, but with a diffusion profile of cumulative 39Ar release, along with published U-Pb apatite age of ∼4.14 Ga, suggests that the data might either define a true continuum (normal background bombardment) from 4.5 Ga to 3.47 Ga or cluster between ∼3.85 Ga and ∼3.47 Ga (excavation of a fresh surface at 3.85 Ga continuously bombarded until 3.47 Ga). Both scenarios are compatible with a final ejection age of 3.47 Ga when a major impact liberates the bulk of the brecciated meteorites into another secondary rubble pile asteroid, where the brecciated eucrites stayed relatively well protected from subsequent major impacts. Based on these results and recent crater counting measurements, we propose that the excavation and bulk ejection were caused by the Rheasilvia (ca. 3.47 Ga) basin-forming impact.

Diffusion models on plagioclase crystals with different Ar age spectrum signatures, from a single breccia (NWA1666; 4501 ± 7 Ma), suggest that either: (1) the formation of the breccia is very young, or (2) different plagioclase crystals have different diffusion characteristics, and/or (3) the porosity caused heterogeneous temperatures during an impact heating event, particularly likely if the 4.5 Ga brecciated eucrites were stored in a rubble pile asteroid. Many or possibly most large asteroids being re-accumulated rubble piles with potential large porosity (Holsapple et al., 2002). Scenarios (2) and (3) preclude the usage of multi-grain aliquots to decipher the time-temperature history of most impact breccia using 40Ar/39Ar thermochronology.

Formation Parameters of High-Pressure Minerals in the Dhofar 717 and 864 Chondrite Meteorites

1Litasov, K.D.,2Badyukov, D.D.,1Pokhilenko, N.P.
Doklady Earth Sciences 485, 327-330 Link to Article [DOI: 10.1134/S1028334X19030322]
1Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russian Federation
2Vernadsky Institute of Geochemistry and Analytical Chemistry, Russian Academy of Sciences, Moscow, 119991, Russian Federation

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(U‐Th)/He zircon dating of Chesapeake Bay distal impact ejecta from ODP site 1073

1M. B. Biren,2J.‐A. Wartho,1M. C. VAN Soest,1K. V. Hodges,3,4H. Cathey,5B. P. Glass,6,7C. Koeberl,8J. W. Horton Jr,9W. Hale
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13316]
1Group 18 Laboratories, School of Earth and Space Exploration, Arizona State University, Tempe, Arizona, 85287 USA
2GEOMAR Helmholtz Centre for Ocean Research Kiel, D‐24148 Kiel, Germany
3LeRoy Eyring Center for Solid State Science, Arizona State University, Tempe, Arizona, 84287 USA
4Central Analytical Research Facility, Queensland University of Technology, Brisbane, Queensland, 4000 Australia
5Department of Geological Sciences, University of Delaware, Newark, Delaware, 19716 USA
6Department of Lithospheric Research, University of Vienna, A‐1090 Vienna, Austria
7Natural History Museum, Burgring 7, A‐1010 Vienna, Austria
8U.S. Geological Survey, 926A National Center, Reston, Virginia, 20192 USA
9IODP Core Repository, Bremen, D‐28359 Germany
Published by arrangement with John Wiley & Sons

Single crystal (U‐Th)/He dating has been undertaken on 21 detrital zircon grains extracted from a core sample from Ocean Drilling Project (ODP) site 1073, which is located ~390 km northeast of the center of the Chesapeake Bay impact structure. Optical and electron imaging in combination with energy dispersive X‐ray microanalysis (EDS) of zircon grains from this late Eocene sediment shows clear evidence of shock metamorphism in some zircon grains, which suggests that these shocked zircon crystals are distal ejecta from the formation of the ~40 km diameter Chesapeake Bay impact structure. (U‐Th/He) dates for zircon crystals from this sediment range from 33.49 ± 0.94 to 305.1 ± 8.6 Ma (2σ), implying crystal‐to‐crystal variability in the degree of impact‐related resetting of (U‐Th)/He systematics and a range of different possible sources. The two youngest zircon grains yield an inverse‐variance weighted mean (U‐Th)/He age of 33.99 ± 0.71 Ma (2σ uncertainties n = 2; mean square weighted deviation = 2.6; probability [P] = 11%), which is interpreted to be the (U‐Th)/He age of formation of the Chesapeake Bay impact structure. This age is in agreement with K/Ar, 40Ar/39Ar, and fission track dates for tektites from the North American strewn field, which have been interpreted as associated with the Chesapeake Bay impact event.

Shock physics mesoscale modeling of shock stage 5 and 6 in ordinary and enstatite chondrites

1Juulia-Gabrielle Moreau,1,2Tomas Kohout,3Kai Wünnemann,4Patricie Halodova,5,6Jakub Haloda
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2019.06.004]
1Department of Geosciences and Geography, University of Helsinki, Finland
2Institute of Geology, The Czech Academy of Sciences, Prague, Czech Republic
3Museum für Naturkunde, Leibniz Institute for Evolution and Biodiversity Science, Berlin, Germany
4Centrum výzkumu Řež, Husinec-Řež, Czech Republic
5Czech Geological Survey, Prague, Czech Republic
6Oxford Instruments NanoAnalysis, Bucks, United Kingdom
Copyright Elsevier

Shock-darkening, the melting of metals and iron sulfides into a network of veins within silicate grains, altering reflectance spectra of meteorites, was previously studied using shock physics mesoscale modeling. Melting of iron sulfides embedded in olivine was observed at pressures of 40–50 GPa. This pressure range is at the transition between shock stage 5 (CS5) and 6 (CS6) of the shock metamorphism classification in ordinary and enstatite chondrites. To characterize CS5 and CS6 better with a mesoscale modeling approach and assess post-shock heating and melting, we used multi-phase (i.e. olivine/enstatite, troilite, iron, pores, and plagioclase) meshes with realistic configurations of grains. We carried out a systematic study of shock compression in ordinary and enstatite chondrites at pressures between 30 and 70 GPa. To setup mesoscale sample meshes with realistic silicate, metal, iron sulfide, and open pore shapes, we converted backscattered electron microscope images of three chondrites. The resolved macroporosity in meshes was 3–6%. Transition from shock CS5 to CS6 was observed through (1) the melting of troilite above 40 GPa with melt fractions of ~0.7–0.9 at 70 GPa, (2) the melting of olivine and iron above 50 GPa with melt fraction of ~0.001 and 0.012, respectively, at 70 GPa, and (3) the melting of plagioclase above 30 GPa (melt fraction of 1, at 55 GPa). Post-shock temperatures varied from ~540 K at 30 GPa to ~1300 K at 70 GPa. We also constructed models with increased porosity up to 15% porosity, producing higher post-shock temperatures (~800 K increase) and melt fractions (~0.12 increase) in olivine. Additionally we constructed a pre-heated model to observe post-shock heating and melting during thermal metamorphism. This model presented similar results (melting) at pressures 10–15 GPa lower compared to the room temperature models. Finally, we demonstrated dependence of post-shock heating and melting on the orientation of open cracks relative to the shock wave front. In conclusion, the modeled melting and post-shock heating of individual phases were mostly consistent with the current shock classification scheme (Stöffler et al. 2018, 2019).

The Itokawa regolith simulant IRS-1 as an S-type asteroid surface analogue

1,3Xiaojia Zeng,1,2,3 Xiongyao Li,4 Dayl Martin,1,2,3Hong Tang,1,2,3Wen Yu,5,6 Kang Yang,5,6Zegui Wang,7Shijie Wang
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2019.06.011]
1Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
2CAS Center for Excellence in Comparative Planetology, Hefei, China
3Key Laboratory of Space Manufacturing Technology, Chinese Academy of Sciences, Beijing 100094, China
4European Space Agency, Fermi Avenue, Harwell Campus, Didcot, Oxfordshire OX11 0FD, United Kingdom
5School of Mechanics and Civil Engineering, China University of Ming and Technology, Xuzhou 221116, China
6State Key Laboratory for Geomechanics and Deep Underground Engineering, China University of Ming and Technology, Xuzhou 221116, China
7State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
Copyright Elsevier

Asteroid regolith simulants (i.e., substitute materials for asteroid surface regoliths) are useful for the preparation of asteroid landing and/or sample-return missions. In this study, we report a new Itokawa asteroid Regolith Simulant (called IRS-1) as an S-type asteroid surface analogue for China’s upcoming asteroid exploration. The IRS-1 simulant was developed from mixing terrestrial minerals with appropriate particle size distributions, based on the currently available mineralogy data of S-type asteroid 25143 Itokowa and a LL6 chondrite Sulagiri. Multiple properties of this simulant are well-characterized, including mineralogy, bulk chemistry, particle size, density, mechanical properties, reflectance spectra, thermal properties, thermogravimetry, and hygroscopicity. These results demonstrate that the IRS-1 simulant has similar mineralogy, bulk chemistry, and physical properties to the target materials (i.e., Itokowa samples and LL6 chondrite Sulagiri), making this simulant a reasonable surface analogue of S-type asteroids. Based on the investigation of mechanical properties of the IRS-1 simulant and two other prepared regolith samples (i.e., L-chondrite-like IRS-1 L and H-chondrite-like IRS1H), we found that the mineralogical variations on S-type asteroids have a relatively large influence on the mechanical properties of S-type asteroid regoliths. Our studies show that the IRS-1 simulant will be appropriate for a number of scientific and engineering-based investigations where a large amount (few kilograms to hundreds of kilograms) of sample is required (e.g., technology development, hardware testing, and drilling). This study also provides an effective production approach for the future development of asteroid regolith simulants for different types of asteroid regoliths and associated applications.