1Paolo A. Sossi, 1Frédéric Moynier, 1Kirsten van Zuilen
Proceedings of the National Academy of Sciences of the United States of America (in Press) Link to Article [https://doi.org/10.1073/pnas.1809060115]
1Institut de Physique du Globe de Paris, Université Paris Diderot, Université Sorbonne Paris Cité, CNRS UMR 7154, 75238 Paris Cedex 05, France
With the exception of volatile elements, which are strongly depleted and isotopically fractionated, the Moon has chemical and isotopic signatures that are indistinguishable from Earth’s mantle. Reconciliation of these properties with Moon formation in a high-energy giant impact invokes evaporative loss of volatile elements, but at conditions that are poorly known. Chromium isotopic fractionation is sensitive to temperature variations and liquid–gas equilibration during evaporation. We measure an isotopic difference between Earth’s mantle and the Moon, consistent with the loss of a Cr-bearing, oxidized vapor phase in equilibrium with the proto-Moon. Temperatures of vapor loss required are much lower than predicted by recent models, implying that volatile elements were removed from the Moon following cooling rather than during a giant impact.