Relationships between unit-cell parameters and composition for rock-forming minerals on Earth, Mars, and other extraterrestrial bodies

1Shaunna M. Morrison et al. (>10)
American Mineralogist 103, 848-856 Link to Article [DOI:]
1University of Arizona, 1040 E 4th Street, Tucson, Arizona 85721, U.S.A.
1Geophysical Laboratory, Carnegie Institution, 5251 Broad Branch Road NW, Washington, D.C. 20015, U.S.A.
Copyright: The Mineralogical Society of America

Mathematical relationships between unit-cell parameters and chemical composition were developed for selected mineral phases observed with the CheMin X-ray diffractometer onboard the Curiosity rover in Gale crater. This study presents algorithms for estimating the chemical composition of phases based solely on X-ray diffraction data. The mineral systems include plagioclase, alkali feldspar, Mg-Fe-Ca C2/c clinopyroxene, Mg-Fe-Ca P21/c clinopyroxene, Mg-Fe-Ca orthopyroxene, Mg-Fe olivine, magnetite, and other selected spinel oxides, and alunite-jarosite. These methods assume compositions of Na-Ca for plagioclase, K-Na for alkali feldspar, Mg-Fe-Ca for pyroxene, and Mg-Fe for olivine; however, some other minor elements may occur and their impact on measured unit-cell parameters is discussed. These crystal-chemical algorithms can be applied to material of any origin, whether that origin is Earth, Mars, an extraterrestrial body, or a laboratory.


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