1Shun Ichimura, 1Yusuke Seto, 1Kazushige Tomeoka
Geochimica et Cosmochimica Acta (in Press) Link to Article [http://doi.org/10.1016/j.gca.2017.04.025]
1Department of Planetology, Graduate School of Science, Kobe University, Nada, Kobe 657-8501, Japan
Nepheline is present as fine grains mainly in refractory inclusions and chondrules in CV and CO carbonaceous chondrites. The nepheline has been formed primarily by replacement of melilite and plagioclase in refractory inclusions and plagioclase and glass in chondrules. The nepheline formation is thought to have occurred during aqueous alteration and thermal metamorphism in the meteorite parent bodies. To verify this hypothesis, we performed the following experiments.
Hydrothermal experiments of gehlenite (Al-rich melilite) and plagioclase (An48) were carried out at 200 °C and ∼15 bar for 168 h using solutions of pH 0, 7, 13, and 14 with a uniform Na concentration. In the gehlenite experiments, various amounts of SiO2 were added. The results revealed that a Na zeolite, analcime, was produced from 10/3 and 10/6 mixtures of gehlenite/SiO2 at pH 7, 13, and14, and from a 10/10 mixture of gehlenite/SiO2 and plagioclase at pH 13 and 14. In particular, at pH 14, in addition to analcime, significant amounts of two other zeolites, fabriesite and hydroxycancrinite, were produced from the 10/6 mixture of gehlenite/SiO2, and fabriesite from plagioclase.
Isothermal heating experiments for 24 h showed that fabriesite, hydroxycancrinite, and analcime transform to nepheline at 600–650, 550–600, and 750–800 °C, respectively. Differential thermal analysis of these zeolites revealed that fabriesite and hydroxycancrinite exhibit exothermic peaks, which correspond to transformation to nepheline, and that the temperatures of those peaks decrease steadily with decreasing heating rate. Kinetic analysis using these data revealed that fabriesite and hydroxycancrinite transform to nepheline at temperatures more than 50–100 degrees lower than determined by the isothermal experiments if heated for durations > 102 and ∼ 1 yr, respectively. Analcime heated non-isothermally at a rate of 1 °C/min transformed to nepheline at temperature higher than that determined by the isothermal experiments, suggesting that its transformation temperature also decreases if it is heated for a much longer duration. From these experiments and analyses, we conclude that fabriesite, hydroxycancrinite, and possibly analcime are capable of transforming to nepheline by heating in meteorite parent bodies.
From our results, we propose that the nepheline in refractory inclusions and chondrules in meteorites formed by a two-stage alteration process: (1) formation of the Na zeolites from melilite, plagioclase, and glass by hydrothermal alteration at low temperature (probably