Searching for calcium-aluminum-rich inclusions in cometary particles with Rosetta/COSIMA

1Paquette, J. A. et al. (>10)*
1Max-Planck-Institut für Sonnensystemforschung, Göttingen, Germany
*Find the extensive, full author and affiliation list on the publishers website

The calcium-aluminum-rich inclusions (CAIs) found in chondritic meteorites are probably the oldest solar system solids, dating back to 4567.30 ± 0.16 million years ago. They are thought to have formed in the protosolar nebula within a few astronomical units of the Sun, and at a temperature of around 1300 K. The Stardust mission found evidence of CAI-like material in samples recovered from comet Wild 2. The appearance of CAIs in comets, which are thought to be formed at lower temperatures and larger distances from the Sun, is only explicable if some mechanism allows the efficient transfer of such objects from the inner solar nebula to the outer solar nebula. Such mechanisms have been proposed such as an X-wind or turbulence. In this work, particles collected from within the coma of comet 67P/Churyumov–Gerasimenko are examined for compositional evidence of the presence of CAIs. COSIMA (the Cometary Secondary Ion Mass Analyzer) uses secondary ion mass spectrometry to analyze the composition of cometary dust captured on metal targets. While CAIs can have a radius of centimeters, they are more typically a few hundred microns in size, and can be smaller than 1 μm, so it is conceivable that particles visible on COSIMA targets (ranging in size from about 10 μm to hundreds of microns) could contain CAIs. Using a peak fitting technique, the composition of a set of 13 particles was studied, looking for material rich in both calcium and aluminum. One such particle was found.

Reference
Paquette JA et al. (2016) Searching for calcium-aluminum-rich inclusions in cometary particles with Rosetta/COSIMA. Meteoritics & Planetary Science (in Press)
Link to Article [DOI: 10.1111/maps.12669]
Published by arrangement with John Wiley & Sons

CV and CM Chondrite Impact Melts

1,2Nicole G. Lunning, 1Catherine M. corrigan, 2Harry Y. McSween, 3,4Travis J. Tenner, 3Noriko T. Kita, 5Robert. J. Bodnar
1Department of Earth and Planetary Sciences and Planetary Geosciences Institute, University of Tennessee, Knoxville, TN 37996, USA
2Department of Mineral Sciences, Smithsonian Institution, National Museum of Natural History, Washington, DC 20560, USA
3Department of Geosciences, University of Wisconsin, Madison, WI 53706, USA
4Chemistry Division, Nuclear and Radiochemistry, Los Alamos National Laboratory, MSJ514, Los Alamos, NM 87545, USA
5Department of Geosciences, Virginia Tech, Blacksburg, VA 24061, USA

Volatile-rich and typically oxidized carbonaceous chondrites, such as CV and CM chondrites, potentially respond to impacts differently than do other chondritic materials. Understanding impact melting of carbonaceous chondrites has been hampered by the dearth of recognized impact melt samples. In this study we identify five carbonaceous chondrite impact melt clasts in three host meteorites: a CV3red chondrite, a CV3oxA chondrite, and a regolithic howardite. The impact melt clasts in these meteorites respectively formed from CV3red chondrite, CV3oxA chondrite, and CM chondrite protoliths. We identified these impact melt clasts and interpreted their precursors based on their texture, mineral chemistry, silicate bulk elemental composition, and in the case of the CM chondrite impact melt clast, in situ measurement of oxygen three-isotope signatures in olivine. These impact melts typically contain euhedral-subhedral olivine microphenocrysts, sometimes with relict cores, in glassy groundmasses. Based on petrography and Raman spectroscopy, four of the impact melt clasts exhibit evidence for volatile loss: these melt clasts either contain vesicles or are depleted in H2O relative to their precursors. Volatile loss (i.e., H2O) may have reduced the redox state of the CM chondrite impact melt clast. The clasts that formed from the more oxidized precursors (CV3oxA and CM chondrites) exhibit phase and bulk silicate elemental compositions consistent with higher intrinsic oxygen fugacities relative to the clast that formed from a more reduced precursor (CV3red chondrite). The mineral chemistries and assemblages of the CV and CM chondrite impact melt clasts identified here provide a template for recognizing carbonaceous chondrite impact melts on the surfaces of asteroids.

Reference
Lunning NG, Corrigan CM, McSween HY, Tenner TJ,Kita NT, Bodnar RJ (2016) CV and CM Chondrite Impact Melts. Geochmica et Cosmochimica Acta (in Press)
Link to Article [doi:10.1016/j.gca.2016.05.038]
Copyright Elsevier