Rb-Sr constraints on the age of Moon formation

Elsa Yobregat, Caroline Fitoussi, Bernard Bourdon
Icarus (in Press) Open Access
Link to Article [https://doi.org/10.1016/j.icarus.2024.116164]
Laboratoire de Géologie de Lyon, ENS Lyon, CNRS, UCBL, France

Determining the age of the Moon, which is commonly considered as the termination of Earth accretion has been a complex challenge for geochronology. A number of methods have been used to delineate the age of the Moon based either on absolute chronology of lunar rocks or have relied on more indirect methods using short-lived nuclides such as 182Hf that was present in the early history of the Solar System. Model ages usually require some assumptions that are sometimes controversial or harder to verify.

In this study, new high precision Sr isotope data (2.4 ppm, 2SD) were obtained for a well-dated lunar anorthosite (60025) in order to better constrain the initial 87Sr/86Sr of the bulk silicate Moon. This new data is then used to model the Sr isotope evolution of the Earth-Moon starting from the beginning of the Solar System. To comply with the Hfsingle bondW and stable isotope constraints, we then assume that the Earth and Moon were equilibrated at the time of Moon formation. By investigating systematically all the sources of uncertainties in our model, we show that compared with previous work on anorthosite, one can tighten the constraints on the youngest age of Moon formation to no >79 Ma after the beginning of the Solar System, i.e. the Moon cannot be younger than 4488 Ma.

Accretion of warm chondrules in weakly metamorphosed ordinary chondrites and their subsequent reprocessing

aAlex M. Ruzicka, aRichard C. Hugo, b,cJon M. Friedrich, aMichael T. Ream
Geochimica et Cosmochimica Acta (in Press)
Link to Article [https://doi.org/10.1016/j.gca.2024.05.031]
aCascadia Meteorite Laboratory, Department of Geology, Portland State University, 1721 SW Broadway, Portland, OR 97207, USA
bDepartment of Chemistry, Fordham University, Bronx, NY 10458, USA
cDepartment of Earth and Planetary Science, American Museum of Natural History, New York, NY 10024, USA
Copyright Elsevier

To better understand chondrite accretion and subsequent processes, the textures, crystallography, deformation, and compositions of some chondrite constituents in ten lithologies of different cluster texture strength were studied in seven weakly metamorphosed (Type 3) and variably shocked ordinary chondrites (Ragland—LL3 S1, Tieschitz—H/L3 S1, NWA 5421—LL3 S2, NWA 5205—LL3 S2, NWA 11905—LL3-5 S3, NWA 5781—LL3 S3, NWA 11351—LL3-6 S4) using optical and electron microscopy and microtomography techniques.

Results support a four-stage model for chondrite formation. This includes 1) limited annealing following collisions during chondrule crystallization and rapid cooling in space prior to accretion, as evidenced by olivine microstructures consistent with dislocation recovery and diffusion; 2) initial accretion of still-warm chondrules into aggregates at an effective chondrite accretion temperature of ∼900-950 °C with nearly in situ impingement deformation between adjacent chondrules in strongly clustered lithologies (NWA 5781, Tieschitz, NWA 5421, NWA 5205 Lithology A), as evidenced by intragranular lattice distortions in olivine consistent with high-temperature slip systems, and by evidence that some olivine-rich objects in Tieschitz accreted while partly molten; 3) syn- or post-accretion bleaching of chondrule mesostases, which transferred feldspathic chondrule mesostasis to an interchondrule glass deposit found in strongly clustered lithologies, as evidenced by chemical data and textures; and 4) post-bleaching weak or strong shocks that resulted in destruction of interchondrule glass and some combination of brecciation, foliation of metal and sulfide, and melting and shock-overprinting effects, as evidenced by poor cluster textures and presence of clastic texture, alignment of metal and sulfide grains caused by shock compression, presence of impact-generated glass, and changes in olivine slip systems. The data support the model of Metzler (2012), who suggested that chondrules in ordinary chondrites accreted while still warm to form cluster chondrite textures as a “primary accretionary rock” (our Stage 2), and that subsequent brecciation destroyed this texture to create chondrites with weak cluster texture (our Stage 4).

Nucleosynthetic isotope variations in chondritic meteorites and their relationship to bulk chemistry

1Herbert Palme,2,3Klaus Mezger
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.14127]
1Forschungsinstitut und Naturmuseum Senckenberg, Frankfurt am Main, Germany
2Institut für Geologie, Universität Bern, Bern, Switzerland
3Center for Space and Habitability, Universität Bern, Bern, Switzerland
Published by arrangement with John Wiley & Sons

The relationship of mass-independent stable isotope anomalies with the chemistry of chondritic meteorites provides constraints on mixing and fractionation processes in the early solar nebula. The present study emphasizes the strong correlation of nucleosynthetic isotope variations among ordinary chondrites (OC), enstatite chondrites (EC), Earth, CI-chondrites, and Ca, Al-rich inclusions (CAI) in ε50Ti versus ε54Cr space. This correlation indicates variable contamination of chondritic reservoirs with material from a single source providing neutron-rich nuclei such as 50Ti, 54Cr, and 62Ni. The well-defined linear relationship of ε50Ti versus ε54Cr indicates that all reservoirs on the correlation line (“chondrite reference line”) started with a CI-chondritic (solar) Cr/Ti ratio, irrespective of the present Cr/Ti ratio of the samples falling on the chondrite reference line. The isotope compositions of carbonaceous chondrites (CC) do not fit the chondrite reference line. Their isotope composition is consistent with a mixture of chondritic meteorites originally falling on the chondrite reference line and volatile element depleted CAIs. However, CC cannot result from addition of CAIs to OC or EC. Neither can OC and EC be produced by loss of refractory components from CI-meteorites. Also, stable isotopes are inconsistent with OC being derived from EC, and vice versa, by a chemical fractionation process. The enrichment of the Earth in refractory lithophile elements is not the result of addition of a refractory component to a chondritic reservoir. It is rather the result of internal fractionation of a chondritic reservoir.