^1,2Mingming Zhang,^1,2Yangting Lin,³Guoqiang Tang,³Yu Liu,⁴Ingo Leya
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2019.12.011]
¹Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
²University of Chinese Academy of Sciences, Beijing100049, China
³State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
⁴Physical Institute, Space Sciences and Planetology, University of Bern, 3012 Bern, Switzerland
Copyright Elsevier

Aluminum-rich (Al₂O₃ > 10 wt%) chondrules (ARCs) are important chondritic components that petrologically link two other major chondritic components, ferromagnesian chondrules (FMCs) and calcium-aluminum-rich inclusions (CAIs), which formed in different regions of the protoplanetary disk. They are closely related to FMCs as indicated by their similar igneous textures, mineral assemblages, and Al-Mg isotope systematics; meanwhile, they have genetic relationship with CAIs as indicated by their distinctly Al₂O₃-rich compositions and occasional occurrences of relict CAI minerals. In order to further understand their formation mechanism and genetic relationships to FMCs and CAIs, nine ARCs and three ARC-related objects from Allende (CV3 oxidized), Leoville (CV3 reduced), and the ungroup Ningqiang carbonaceous chondrites were studied for petrology, mineralogy, bulk compositions, rare earth element (REE) abundances, and in situ oxygen isotopic compositions. Our results suggest that (i) ARCs crystallized from incompletely molten droplets with crystallization sequences mainly determined based on their bulk compositions. Projection of their bulk compositions onto the forsterite-saturated tridymite-diopside-spinel diagram allows us to classify them into Al-rich [Sp], Al-rich [En], and Al-rich [Plag]; (ii) ARC precursors are mixtures of refractory materials and the precursors of FMCs, in which the refractory materials have diverse sources rather than a single type of CAI/AOA (amoeboid olivine aggregate); this is inferred from the bulk compositions, relict minerals (both coarse- and fine-grained spinel, olivine, and Al-Ti-diopside), and various CAI-like REE patterns (unfractionated Group I/ III and highly fractionated Group II/ II-like) of ARCs. The source include AOAs and igneous Type B/C CAIs; (iii) ARCs were melted in the FMC-forming region, possibly by the same heating mechanism or during the same transient heating event, which is consistent with the similar oxygen isotopic compositions of their phenocrysts (Δ¹⁷O = -5.2 ± 1.7‰, 2SD). Thus, we consider that ARCs formed by melting of mixtures of diverse refractory components with the FMC precursors in the FMC-forming region.

¹Alessandro Maltese,^1,2Klaus Mezger
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2019.12.021]
¹Institute of Geological Sciences, University of Bern, Baltzerstrasse 1+3, 3012 Bern, Switzerland
²Center for Space and Habitability, University of Bern, Gesellschaftsstrasse 6, 3012 Bern, Switzerland
Copyright Elsevier

Constraining the evolution of Pb isotopes in the bulk silicate Earth (BSE) is hampered due to the lack of a direct determination of Earth’s U/Pb and initial Pb isotope composition. All estimates of these parameters are strongly model dependent and most Pb evolution models start with a meteoritic source, i.e., the primordial Pb composition determined in troilite from the Canyon Diablo iron meteorite. During the condensation of the elements in the solar nebula, accretion of the Earth, and its subsequent chemical evolution, the U/Pb was modified. Different models make different assumptions about the timing and extent of this U-Pb fractionation during Earth’s chemical evolution that cannot always be related to known global geological processes at the time of this modification. This study explores geochemical constraints that can be related to known geological processes to derive an internally consistent model for the evolution of the U-Th-Pb systematics of the silicate Earth.

Lead is chalcophile, moderately volatile, and as a result strongly depleted in the BSE compared to primitive meteorites. Any process affecting the abundance and isotope composition of Pb in Earth throughout its early history has to be consistent with the abundance of elements with similar chemical and physical properties in the same reservoir. The abundances of refractory to moderately and highly volatile elements in the BSE imply that the proto Earth was highly depleted in volatile elements and therefore evolved with a very high U/Pb (²³⁸U/²⁰⁴Pb = µ ≥100) prior to collision with the Moon-forming giant impactor. This impactor had close to chondritic abundances of moderately to highly volatile elements and delivered most of Earth’s volatile elements, including the Pb budget. Addition of this volatile rich component caused oxidation of Earth’s mantle and allowed effective transfer of Pb into the core via sulfide melt segregation. Sequestration of Pb into the core therefore accounts for the high µ_BSE, which has affected ca. 53 % of Earth’s Pb budget. In order to account for the present-day Pb isotope composition of BSE, the giant impact must have occurred at 69 ±10 Myr after the beginning of the solar system. Using this point in time, a model-derived µ-value, and the corresponding initial Pb isotope composition of BSE, a single stage Pb isotope evolution curve can be derived. The result is a model evolution curve for BSE in ²⁰⁸Pb-²⁰⁷Pb-²⁰⁶Pb-²⁰⁴Pb-isotope space that is fully consistent with geochemical constraints on Earth’s accretionary sequence and differentiation history. This Pb-evolution model may act as a reference frame to trace the silicate Earth’s differentiation into crust and mantle reservoirs, similar to the CHUR reference line used for other radio-isotope systems. It also highlights the long-standing Th/U paradox of the ancient Earth.

¹Markus Patzek,²Peter Hoppe,¹Addi Bischoff,³Robbin Visser,³Timm John
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2019.12.017]
¹Institut für Planetologie, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Str. 10, D-48149 Münster, Germany
²Max Planck Institute for Chemistry, Particle Chemistry Department, P.O. Box 3060, D-55020 Mainz, Germany
³Freie Universität Berlin, Institut für Geologische Wissenschaften, Malteserstr. 74-100, D-12249 Berlin
Copyright Elsevier

Volatile-rich, CI- and CM-like clasts occur in different brecciated achondrite and chondrite groups. The CI-like clasts in HEDs, polymict ureilites, as well as ordinary, CR, and CB chondrites have a similar mineralogy, indicating a similar alteration history. However, when viewed in detail, their mineral chemistry shows some minor differences between the clasts from different meteorite groups. For CM-like clasts found in HED meteorites, the clasts are, based on their mineralogy, clearly fragments of CM chondrites. To be able to decipher whether CI- (or CM-)like clasts from different meteorite groups are related to certain meteorite classes known to contain volatiles, we obtained D/H ratios of several clasts from the meteorite groups mentioned above and compared them with those of CI and CM chondrites as well as to unique carbonaceous chondrites such as Bells, Essebi, and Tagish Lake. Considering the δD-values, CM-like clasts in HEDs span a similar range compared to bulk values of CM chondrites, further indicating that CM-like clasts are fragments of CM chondrites. For CI-like clasts a clear distinction can be made: While CI-like clasts in HEDs and ordinary chondrites show a very similar range in their δD-signatures compared to “common” CI chondrites, meaning that these clasts are likely related to CI chondrites, the CI-like clasts in polymict ureilites are enriched in D up to 3000 ‰; a similarly high enrichment is found for the CI-like clasts in CR chondrites. Thus, although the CI-like clasts in ureilites and CR chondrites likely experienced similar alteration histories as the CI-like clasts found in the other meteorite types, these clasts probably formed in a different region than the CI chondrites and, thus, are more accurately referred to as C1 clasts. Overall, the existence and isotopic signatures of the C1 clasts in several meteorite groups proves the existence of additional primitive, volatile-rich material in the (early) Solar System besides the matter we study as the CI, CM, and CR chondrites. This material was distributed throughout the Solar System very early and might have played an important role for the volatile inventory of the terrestrial planets.

Cosmochemistry Papers will be on a short break from 23.12.19 to 02.01.20. Many thanks for the interest, which made 2019 our most successful year by far. We wish all our followers a Merry Christmas and Happy New Year !

¹Yanhao Lin,^2,3Hejiu Hui,⁴Xiaoping Xia,²Sheng Shang,¹Wim van Westrenen
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13425]
¹Department of Earth Sciences, Faculty of Science, Vrije Universiteit Amsterdam, De Boelelaan 1085, 1081 HV Amsterdam, the Netherlands
²State Key Laboratory for Mineral Deposits Research & Lunar and Planetary Science Institute, School of Earth Sciences and Engineering, Nanjing University, 163 Xianlin Dadao, Nanjing, 210023 China
³CAS Center for Excellence in Comparative Planetology, Hefei, 230026 China
⁴State Key Lab of Isotope Geochemistry, Guangzhou Institute of Geochemistry, CAS, No 511, Kehua Street, Tianhe District, Guangzhou, 510640 China
Published by arrangement with John Wiley & Sons

The identification of hydrogen in a range of lunar samples and the similarity of its abundance and isotopic composition with terrestrial values suggest that water could have been present in the Moon since its formation. To quantify the effect of water on early lunar differentiation, we present new analyses of a high‐pressure, high‐temperature experimental study designed to model the mineralogical and geochemical evolution of the solidification material equivalent to 700 km deep lunar magma oceans first reported in Lin et al. (2017a). We also performed additional experiments to better quantify water contents in the run products. Water contents in the melt phases in hydrous run products spanning a range of crystallization steps were quantified directly using a secondary ion mass spectrometry (SIMS). Results suggest that a significant but constant proportion (68 ± 5%) of the hydrogen originally added to the experiments was lost from the starting material independent of run conditions and run duration. The volume of plagioclase formed during our crystallization experiments can be combined with the measured water contents and the observed crustal thickness on the Moon to provide an updated lunar interior hygrometer. Our data suggest that at least 45–354 ppm H₂O equivalent was present in the Moon at the time of crust formation. These estimates confirm the inference of Lin et al. (2017a) that the Moon was wet during its magma ocean stage, with corrected absolute water contents now comparable to estimates derived from the water content in a range of lunar samples.

¹Nicholas Castle,²Ethan Kuehl,¹John Jones,¹Allan Treiman
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13413]
¹Lunar and Planetary Institute—USRA, Houston, Texas, 77058 USA
²Washington University in St. Louis, St. Louis, Missouri, 63130 USA
Published by arrangement with John Wiley & Sons

Petrographic examination of the xenolith and xenocryst populations in the olivine‐phyric shergottite Elephant Moraine 79001 Lithology A shows more chemical heterogeneity than previously documented. Analyses of olivine grains in 18 megacrysts and in 4 lithic fragments show that these two populations either do not have the same source or that this source is heterogeneous in terms of its time–temperature history. Additionally, among the four lithic fragments analyzed, two are distinctive (1) one contains a major‐element‐equilibrated, euhedral olivine grain and (2) the second contains high‐magnesium pyroxene cores. Furthermore, two populations of ferroan olivine were identified (1) one more ferroan than any other reported in EET 79001 and (2) a slightly less ferroan, unequilibrated olivine, but with a restricted range in Mg#. We have also observed an equilibrated pyroxene grain associated with a zoned olivine megacryst. As a result, we recognize that the xenolith/xenocryst population does not represent the incorporation of a single xeno‐lithology into Lithology A, and propose that it be subdivided into a suite of seven identified lithologies, with the understanding that more are likely to be identified with further study. The abundance of Ca in olivine in the xeno‐lithologies suggests a set of crustal, rather than deep mantle, lithologies. Diffusion rates in olivine suggest that the lithologies were incorporated shortly before rapid cooling of the host magma, preserving preexisting mineral chemical zoning. These mineral chemical zones could have been preserved at lower crustal temperatures for up to 10s of Ka. Trace‐element studies of these distinct populations would be required to test whether they are related by igneous processes from a common source magma.

^1,2Xiaojia Zeng,^1,3Shijie Li,⁴Katherine H. Joy,^1,2,3 Xiongyao Li,^1,2,3Jianzhong Liu,^1,2,3Yang Li,^1,2Rui Li,⁵Shijie Wang
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13421]
¹Center for Lunar and Planetary Sciences, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081 China
²Key Laboratory of Space Manufacturing Technology, Chinese Academy of Sciences, Beijing, 100094 China
³CAS Center for Excellence in Comparative Planetology, Hefei, China
⁴Department of Earth and Environmental Sciences, University of Manchester, Manchester, M13 9PL UK
⁵State Key Laboratory of Environmental Geochemistry, Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, 550081 China
Published by arrangement with John Wiley & Sons

Lunar breccias preserve the records of geologic processes on the Moon. In this study, we report the occurrence, petrography, mineralogy, and geologic significance of the observed secondary olivine veinlets in lunar feldspathic breccia meteorite Northwest Africa (NWA) 11273. Bulk‐rock composition measurements show that this meteorite is geochemically similar to other lunar highland meteorites. In NWA 11273, five clasts are observed to host veinlets that are dominated by interconnecting olivine mineral grains. The host clasts are mainly composed of mafic minerals (i.e., pyroxene and olivine) and probably sourced from a basaltic lithology. The studied olivine veinlets (~5 to 30 μm in width) are distributed within the mafic mineral host, but do not extend into the adjacent plagioclase. Chemically, these olivine veinlets are Fe‐richer (Fo41.4–51.9), compared with other olivine grains (Fo54.3–83.1) in lithic clasts and matrix of NWA 11273. By analogy with the secondary olivine veinlets observed in meteorites from asteroid Vesta (howardite–eucrite–diogenite group samples) and lunar mare samples, our study suggests that the newly observed olivine veinlets in NWA 11273 are likely formed by secondary deposition from a lunar fluid, rather than by crystallization from a high‐temperature silicate melt. Such fluid could be sulfur‐ and phosphorous‐poor and likely had an endogenic origin on the Moon. The new occurrence of secondary olivine veinlets in breccia NWA 11273 reveals that the fluid mobility and deposition could be a previously underappreciated geological process on the Moon.

^1,2N.M.Curran,^1,3M.Nottingham,^3,4L.Alexander,^3,4I.A.Crawford,⁵E.Füri,¹K.H.Joy
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2019.104823]
¹School of Earth and Environmental Sciences, University of Manchester, Oxford Road, Manchester, M13 9PL, UK
²NASA Goddard Space Flight Center, 8800 Greenbelt Road, Greenbelt, MD, 20771, USA
³Department of Earth and Planetary Science, Birkbeck College, University of London, London, UK
⁴The Centre for Planetary Sciences at UCL-Birkbeck, London, UK
⁵Centre de Recherches Pétrographiques et Géochimiques, CNRS-UL, 15 rue Notre Dame des Pauvres, BP20, 54501, Vandoeuvre-lès-Nancy Cedex, France

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¹Y.Langevin,²S.Merouane,²M.Hilchenbach,¹M.Vincendon,³K.Hornung,⁴C.Engrand,⁵ R.Schulz,²J.Kissel,⁶J.Ryno
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2019.104815]
¹Institut d’Astrophysique Spatiale, CNRS/Univ. Paris Saclay, Orsay, France
²Max-Planck Institut für Sonnensystemforschung, Göttingen, Germany
³Universität der Bundeswehr, Neubiberg, Germany
⁴CSNSM, CNRS/Univ. Paris-Sud, Orsay, France
⁵European Space Agency Scientific Support Office, Noordwijk, the Netherlands
⁶Finnish Meteorological Institute, Helsinki, Finland

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¹Yoko Kebukawa,²Michael E.Zolensky,³Motoo Ito,⁴Nanako O.Ogawa, ⁴Yoshinori Takano,⁴ Naohiko Ohkouchi,⁵Aiko Nakato,⁶Hiroki Suga,⁷ Yasuo Takeichi,⁶Yoshio Takahashi,¹Kensei Kobayashi
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2019.12.012]
¹Faculty of Engineering, Yokohama National University, 79-5 Tokiwadai, Hodogaya-ku, Yokohama 240-8501, Japan
²Astromaterials Research and Exploration Science, NASA Johnson Space Center, 2101 NASA Parkway, Houston, TX 77058, USA
³Kochi Institute for Core Sample Research, Japan Agency for Marine-Earth Science and Technology, B200 Monobe, Nankoku, Kochi 783-8502, Japan
⁴Biogeochemistry Program, Japan Agency for Marine-Earth Science and Technology, 2-15 Natsushima-Cho, Yokosuka 237-0061, Japan
⁵Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Sagamihara 252-5210, Japan
⁶Department of Earth and Planetary Science, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan
⁷Institute of Materials Structure Science, High-Energy Accelerator Research Organization, 1-1 Oho, Tsukuba, Ibaraki 305-0801, Japan
Copyright Elsevier

Some xenolithic clasts in meteorites may have originated from unique primitive Solar System bodies. These clasts would provide novel insights into the early evolution of the Solar System. We conducted multiple analyses of organic matter (OM) in a CI-like xenolithic clast in the Zag (H5) meteorite including bulk elemental and isotopic analysis, FTIR, STXM/XANES, and NanoSIMS. The bulk C and N abundances in the Zag clast were +5.1 ± 0.4 wt.% and +0.26 ± 0.01 wt.%, respectively, which were the highest observed among various chondrite groups. The bulk δ¹³C value of the Zag clast was +23.0 ± 4.1 ‰ which was close to the value of the Tagish Lake meteorite; the δ¹⁵N value was +300 ± 3 ‰ which was close to the values of CR chondrites and Bells (a unique CM). The δD values of C-rich regions obtained by NanoSIMS were approximately +600 to +2000‰ which were close to the values of IOM from CI, CM and Tagish Lake. Some isotopic “hot spots” were observed with δD values up to ≈ +4000‰ and δ¹⁵N values up to ≈ +5500‰. The infrared transmission spectrum of the Zag clast was consistent with the abundant phyllosilicates and carbonates observed in the clast. The STXM showed abundant OM in various forms. C-XANES spectra from the OM were generally similar to CI/CM/CR chondrites. However, some variations existed in the molecular structures. OM in the Zag clast was partially associated with carbonates. The functional group, elemental and isotopic signatures of the OM in the Zag clast support the idea that the Zag clast is unique among known carbonaceous chondrite groups and originated from the outer Solar System such as aqueously-altered D/P type asteroids.