Revisiting the particle-size constraint of the 10-μm silicate feature

1,2Ekaterina Chornaya,1Alexander M.Zakharenko,3Evgenij Zubko,1,4Aleksandr Kuchmizhak,1Kirill S.Golokhvast,5,6Gorden Videen
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113907]
1Far Eastern Federal University, 8 Sukhanova St., Vladivostok 690950, Russia
2Institute of Applied Astronomy of RAS, 10 Kutuzova Emb., Saint-Petersburg 191187, Russia
3Humanitas College, Kyung Hee University, 1732, Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, South Korea
4Institute of Automation and Control Processes FEB RAS, 5 Radio St., Vladivostok 690041, Russia
5Space Science Institute, 4750 Walnut Street, Boulder, Suite 205, CO 80301, USA
6Department of Astronomy and Space Science, Kyung Hee University, 1732, Deogyeong-daero, Giheung-gu, Yongin-si, Gyeonggi-do 17104, South Korea
Copyright Elsevier

We experimentally measure the mid-IR spectra of half-millimeter-sized olivine particles with very compact morphology and smooth surfaces. We find that the 10-μm silicate feature is present in these large, irregularly shaped samples having surface roughness that is much smaller than optical wavelengths. Based on Mie theory, which assumes the particles are spherical, this feature should not exist for such large particles. As a consequence, its presence has been taken as an indicator that the particles or grains composing such particles were micron-sized or smaller. The measurement of this feature in real, irregularly shaped particles, suggests that the assumption of sphericity may severely limit our interpretations of remote-sensing data.

A plagioclase-rich rock measured by Yutu-2 Rover in Von Kármán crater on the far side of the Moon

1Pei Ma et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113901]
1Planetary Science Institute, School of Earth Sciences, China University of Geosciences, Wuhan, China
Copyright Elsevier

The Chang’E-4 spacecraft successfully landed in Von Kármán crater inside the South Pole-Aitken basin on the lunar far side on January 3, 2019 and the Yutu-2 Rover has performed explorations on the lunar surface for nine lunar days as of September 2019. Our earlier analysis of the visible and near-infrared spectrometer measurements made by the Yutu-2 rover during the first two lunar days shows that the regolith of the landing site may have come from the nearby Finsen crater and is dominated by plagioclase with lesser amount of mafic minerals. During its third lunar day explorations, the Yutu-2 photographed a small piece of lunar rock and measured its reflectance spectra. Compared with the spectra of its surrounding regolith, this rock’s spectra have deeper absorption features, indicating its fresher nature. To obtain the mineralogy of the rock, we compared the rock’s spectra with the spectral library data of NASA’s reflectance experiment laboratory of returned lunar rocks and lunar meteorites. We found that this rock is also plagioclase-rich with a possible plagioclase abundance of 60–80 vol%. A source region analysis using the Moon Mineralogy Mapper’s remote sensing observations indicates this rock was ejected from the Zhinyu crater, about 30 km west of the landing site, rather than directly from the Finsen crater. Numerical simulations of the Zhinyu crater on the impact cratering process and ejecta thickness distribution confirmed our findings and imply that the surficial materials at the CE-4 landing site experienced a complicated evolution rather than simply retaining the pristine or primordial ejecta directly from the Finsen crater.

Origin and composition of three heterolithic boulder- and cobble-bearing deposits overlying the Murray and Stimson formations, Gale Crater, Mars

1Roger C. Wiens et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113897]
1Los Alamos National Laboratory, Los Alamos, NM, USA
Copyright Elsevier

Heterolithic, boulder-containing, pebble-strewn surfaces occur along the lower slopes of Aeolis Mons (“Mt. Sharp”) in Gale crater, Mars. They were observed in HiRISE images acquired from orbit prior to the landing of the Curiosity rover. The rover was used to investigate three of these units named Blackfoot, Brandberg, and Bimbe between sols 1099 and 1410. These unconsolidated units overlie the lower Murray formation that forms the base of Mt. Sharp, and consist of pebbles, cobbles and boulders. Blackfoot also overlies portions of the Stimson formation, which consists of eolian sandstone that is understood to significantly postdate the dominantly lacustrine deposition of the Murray formation. Blackfoot is elliptical in shape (62 × 26 m), while Brandberg is nearly circular (50 × 55 m), and Bimbe is irregular in shape, covering about ten times the area of the other two. The largest boulders are 1.5–2.5 m in size and are interpreted to be sandstones. As seen from orbit, some boulders are light-toned and others are dark-toned. Rover-based observations show that both have the same gray appearance from the ground and their apparently different albedos in orbital observations result from relatively flat sky-facing surfaces.

Chemical observations show that two clasts of fine sandstone at Bimbe have similar compositions and morphologies to nine ChemCam targets observed early in the mission, near Yellowknife Bay, including the Bathurst Inlet outcrop, and to at least one target (Pyramid Hills, Sol 692) and possibly a cap rock unit just north of Hidden Valley, locations that are several kilometers apart in distance and tens of meters in elevation. These findings may suggest the earlier existence of draping strata, like the Stimson formation, that would have overlain the current surface from Bimbe to Yellowknife Bay. Compositionally these extinct strata could be related to the Siccar Point group to which the Stimson formation belongs.

Dark, massive sandstone blocks at Bimbe are chemically distinct from blocks of similar morphology at Bradbury Rise, except for a single float block, Oscar (Sol 516). Conglomerates observed along a low, sinuous ridge at Bimbe consist of matrix and clasts with compositions similar to the Stimson formation, suggesting that stream beds likely existed nearly contemporaneously with the dunes that eventually formed the Stimson formation, or that they had the same source material. In either case, they represent a later pulse of fluvial activity relative to the lakes associated with the Murray formation.

These three units may be local remnants of infilled impact craters (especially circular-shaped Brandberg), decayed buttes, patches of unconsolidated fluvial deposits, or residual mass-movement debris. Their incorporation of Stimson and Murray rocks, the lack of lithification, and appearance of being erosional remnants suggest that they record erosion and deposition events that post-date the exposure of the Stimson formation.

A chondrule formation experiment aboard the ISS: Experimental set-up and test experiments

1Dominik Spahr et al (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113898]
1Institute of Geosciences, Goethe University Frankfurt, Altenhöferallee 1, 60438 Frankfurt, Germany
Copyright Elsevier

The formation of chondrules in the solar nebula is still an enigmatic process. In order to reconstruct this process, we performed a chondrule formation experiment aboard the International Space Station (ISS), called EXCISS. The purpose of the EXCISS experiment is to acquire new insights in chondrule formation by “nebular lightnings”. During the experiment forsterite (MgSiO4) particles were repeatedly exposed to arc discharges under long-term micro-gravity conditions. The purpose of this paper is to describe the experimental set-up and establish and benchmark approaches for the analysis of the samples once they are returned from the ISS. We produced aggregates of fused MgSiO4 particles in our Earth-based experiment which we studied by SEM and X-ray microtomography. The results of our preliminary Earth-based experiments indicate that the chosen experimental parameters will likely lead to melting of MgSiO4 particles and the formation of aggregates. The results from the first experiments aboard the ISS revealed that the EXCISS experiment is fully operational.

Effects of micrometer-scale surface roughness on thermal infrared emittance spectra of silica glass

1Jeff A.Berger,2Sherry L.Cady,3Victoria E.Hamilton
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113868]
1NASA Johnson Space Center, Houston, TX, USA
2Pacific Northwest National Laboratory, USA
3Southwest Research Institute, Boulder, CO, USA
Copyright Elsevier

Surface roughness is known to decrease thermal infrared (TIR) absorption band intensity, but studies of the effect on geologically relevant samples are relatively limited. To determine the effect of surface roughness (with features smaller than ~2/3 of the wavelength) on TIR spectra, we investigated two glass compositions with prepared roughened surfaces: (1) high purity fused silica and (2) soda-lime glass (73 wt% SiO2). We roughened the surfaces of the glasses by sandblasting and polishing with grit paper. The surfaces were characterized with scanning electron microscopy and stylus profilometry. We then analyzed the roughened glasses with TIR emittance spectroscopy. Micrometer-scale roughness causes a decrease in TIR absorption band intensity, relative to a specular surface. No significant changes in band shape or shifts in wavelength were detected. As roughness increases, empirical results show a logarithmic decrease in TIR absorption band intensity. The logarithmic trends of the two glass compositions are different; empirical roughness calibrations do not translate across different compositions. A linear, least-squares spectral deconvolution using two endmembers, specular and blackbody, predicts model spectra of roughened glass surfaces with relatively low error. This is of consequence to orbital TIR measurements of poorly constrained targets, such as the Martian surface, because micrometer-scale roughness is adequately modeled by the addition of a blackbody spectrum to the deconvolution endmember matrix.

Spatiotemporal evolution, mineralogical composition, and transport mechanisms of long-runout landslides in Valles Marineris, Mars

1,2Jessica A.Watkins,2,3Bethany L.Ehlmann,1An Yin
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113836]
1Department of Earth, Planetary, and Space Sciences and Institute of Planets and Exoplanets (iPLEX), University of California, Los Angeles, CA 90095-1567, USA
2Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, CA 91125, USA
3Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA 91109, USA
Copyright Elsevier

Long-runout landslides with transport distances of >50 km are ubiquitous in Valles Marineris (VM), yet the transport mechanisms remain poorly understood. Four decades of studies reveal significant variation in landslide morphology and emplacement age, but how these variations are related to landslide transport mechanisms is not clear. In this study, we address this question by conducting systematic geological mapping and compositional analysis of VM long-runout landslides using high-resolution Mars Reconnaissance Orbiter imagery and spectral data. Our work shows that: (1) a two-zone morphological division (i.e., an inner zone characterized by rotated blocks and an outer zone expressed by a thin sheet with a nearly flat surface) characterizes all major VM landslides; (2) landslide mobility is broadly dependent on landslide mass; and (3) the maximum width of the outer zone and its transport distance are inversely related to the basal friction that was estimated from the surface slope angle of the outer zone. Our comprehensive Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) compositional analysis indicates that hydrated silicates are common in landslide outer zones and nearby trough-floor deposits. Furthermore, outer zones containing hydrated minerals are sometimes associated with longer runout and increased lateral spreading compared to those without detectable hydrated minerals. Finally, with one exception we find that hydrated minerals are absent in the inner zones of the investigated VM landslides. These results as whole suggest that hydrated minerals may have contributed to the magnitude of lateral spreading and long-distance forward transport of major VM landslides.

An unusual compound object in Yamato 793408 (H3.2‐an): The missing link between compound chondrules and macrochondrules?

1Jens Barosch,1,2Dominik C. Hezel,3Yves Marrocchi,3Andrey Gurenko,1,4Christoph Lenting
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13496]
1Department of Geology and Mineralogy, University of Cologne, Zülpicher Str. 49b, 50674 Köln, Germany
2Department of Mineralogy, Natural History Museum, Cromwell Road, London, SW7 5BD UK
3CRPG, CNRS, Université de Lorraine, UMR 7358, Vandoeuvre‐lès‐Nancy, 54501 France
4Institute of Geoscience, University of Bonn, Meckenheimer Allee 169, 53111 Bonn, Germany
Published by arrangement with John Wiley & Sons

We found a large (~2 mm) compound object in the primitive Yamato 793408 (H3.2‐an) chondrite. It consists mostly of microcrystalline material, similar to chondrule mesostasis, that hosts an intact barred olivine (BO) chondrule. The object contains euhedral pyroxene and large individual olivine grains. Some olivine cores are indicative of refractory forsterites with very low Fe‐ and high Ca, Al‐concentrations, although no 16O enrichment. The entire object is most likely a new and unique type, as no similar compound object has been described so far. We propose that it represents an intermediate stage between compound chondrules and macrochondrules, and formed from the collision between chondrules at low velocities (below 1 m s−1) at high temperatures (around 1550 °C). The macrochondrule also trapped and preserved a smaller BO chondrule. This object appears to be the first direct evidence for a genetic link between compound chondrules and macrochondrules. In accordance with previous suggestions and studies, compound chondrules and macrochondrules likely formed by the same mechanism of chondrule collisions, and each represents different formation conditions, such as ambient temperature and collision speed.

Petrogenesis, alteration, and shock history of intermediate shergottite Northwest Africa 7042: Evidence for hydrous magmatism on Mars?

1,2T.V.Kizovski et al. (>10)
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2020.05.030]
1Centre for Applied Planetary Mineralogy, Department of Natural History, Royal Ontario Museum, 100 Queen’s Park, Toronto, Ontario, M5S 2C6, Canada
2Department of Earth Sciences, University of Toronto, 22 Russell Street, Toronto, Ontario, M5S 3B1, Canada
Copyright Elsevier

Northwest Africa (NWA) 7042 is an intermediate, permafic shergottite consisting of two generations of olivine (early zoned olivine Fo41-76, and late-stage fayalitic olivine Fo46-56), complexly zoned pyroxene (En35-64Fs22-46Wo5-34), shock-melted or maskelynitized feldspar (An5-30Ab16-61Or1-47), and accessory merrillite, apatite, ilmenite, titanomagnetite, Fe-Cr-Ti spinels, pyrrhotite, and baddeleyite. The zoned olivine grains have been pervasively modified, containing conspicuous brown Mg-rich cores surrounded by colorless, unaltered Fe-rich overgrowth rims. This textural relationship suggests that the cores were altered at magmatic temperatures prior to crystallization of the rims on Mars. Launch-generated shock veins in NWA 7042 also crosscut and displace several of the altered olivine grains indicating that alteration occurred before ejection of the meteorite. While this type of olivine alteration is rare in shergottites, it is similar to deuterically altered olivine in basalts and gabbros on Earth, caused by residual water-rich magmatic fluids. Transmission electron microscopy analysis of the olivine alteration did not reveal the high-temperature phases expected from this process; however, NWA 7042 has also been subjected to extensive terrestrial weathering which may explain their absence. The potential presence of deuterically altered olivine in NWA 7042 has significant implications, as it is the third martian meteorite where deuteric alteration of olivine has been observed (the others being NWA 10416, and ALH 77005). The different mantle sources for the parental melts of these three meteorites would suggest many, if not all martian mantle reservoirs have the potential to produce water-rich magmas.

The stability of divalent Ge in silicate melts and its geochemical properties

1Mare, E.R.,1O’Neill, H.S.C.,1Berry, A.J.,2Glover, C.J.
Chemical Geology 532, 119306 Link to Article [DOI: 10.1016/j.chemgeo.2019.119306]
1Research School of Earth Sciences, Australian National University, Canberra, ACT 2601, Australia
2Australian Synchrotron, 800 Blackburn Rd, Clayton, VIC 3168, Australia

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The U/Th production ratio from extended independent model

1Bahadoran, M.,2,3Amiri, I.S.
European Physical Journal Plus 135, 205 Link to Article [DOI: 10.1140/epjp/s13360-020-00107-2]
1Department of Physics, Shiraz University of Technology, Shiraz, Fars 31371555, Iran
2Computational Optics Research Group, Advanced Institute of Materials Science, Ton Duc Thang University, District 7, Ho Chi Minh City, 700000, Viet Nam
3Faculty of Applied Sciences, Ton Duc Thang University, District 7, Ho Chi Minh City, 700000, Viet Nam

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