¹Samuele Boschi,¹Birger Schmitz,¹Ellinor Martin,¹Fredrik Terfelt
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13539]
¹Astrogeobiology Laboratory, Division of Nuclear Physics, Department of Physics, Lund University, Lund, Sweden
Published by arrangement with John Wiley & Sons

Based on sediment‐dispersed extraterrestrial spinel grains in the Bottaccione limestone section in Italy, we reconstructed the micrometeorite flux to Earth during the early Paleocene. From a total of 843 kg of limestone, 86 extraterrestrial spinel grains (12 grains > 63 μm, and 74 in the 32–63 μm fraction) have been recovered. Our results indicate that the micrometeorite flux was not elevated during the early Paleocene. Ordinary chondrites dominated over achondritic meteorites similar to the recent flux, but H chondrites dominated over L and LL chondrites (69%, 22%, and 9%, respectively). This H‐chondrite dominance is similar to that recorded within an enigmatic ³He anomaly (70, 27, and 3%) in the Turonian, but different from just before this ³He anomaly and in the early Cretaceous, where ratios are similar to the recent flux (~45%, 45%, and 10%). The K‐Ar isotopic ages of recently fallen H chondrites indicate a small impact event on the H‐chondrite parent body ~50 to 100 Ma ago. We tentatively suggest that this event is recorded by the Turonian ³He anomaly, resulting in an H‐chondrite dominance up to the Paleocene. Our sample spanning the 20 cm above the Cretaceous–Paleogene (K–Pg) boundary did not yield any spinel grains related to the K–Pg boundary impactor.

¹Michael W. Broadley,²Peter H. Barry,¹David V. Bekaert,¹David J. Byrne,³Antonio Caracausi,⁴Christopher J. Ballentine,¹Bernard Marty
Proceedings of the National Academy of Sciences of the Unites States of America (in Press) Link to Article [https://doi.org/10.1073/pnas.200390711]
¹Centre de Recherches Pétrographiques et Géochimiques, UMR 7358 CNRS—Université de Lorraine, BP 20, F-54501 Vandoeuvre-lès-Nancy, France;
²Marine Chemistry and Geochemistry Department, Woods Hole Oceanographic Institution, Woods Hole, MA 02543;
³Instituto Nazionale di Geofisica e Vulcanologia, 90146 Palermo, Italy;
⁴Department of Earth Sciences, University of Oxford, OX1 3AN Oxford, United Kingdom

Identifying the origin of noble gases in Earth’s mantle can provide crucial constraints on the source and timing of volatile (C, N, H2O, noble gases, etc.) delivery to Earth. It remains unclear whether the early Earth was able to directly capture and retain volatiles throughout accretion or whether it accreted anhydrously and subsequently acquired volatiles through later additions of chondritic material. Here, we report high-precision noble gas isotopic data from volcanic gases emanating from, in and around, the Yellowstone caldera (Wyoming, United States). We show that the He and Ne isotopic and elemental signatures of the Yellowstone gas requires an input from an undegassed mantle plume. Coupled with the distinct ratio of 129Xe to primordial Xe isotopes in Yellowstone compared with mid-ocean ridge basalt (MORB) samples, this confirms that the deep plume and shallow MORB mantles have remained distinct from one another for the majority of Earth’s history. Krypton and xenon isotopes in the Yellowstone mantle plume are found to be chondritic in origin, similar to the MORB source mantle. This is in contrast with the origin of neon in the mantle, which exhibits an isotopic dichotomy between solar plume and chondritic MORB mantle sources. The co-occurrence of solar and chondritic noble gases in the deep mantle is thought to reflect the heterogeneous nature of Earth’s volatile accretion during the lifetime of the protosolar nebula. It notably implies that the Earth was able to retain its chondritic volatiles since its earliest stages of accretion, and not only through late additions.

¹E.B.Rampe et al. (>10)
Journal of Geophysical Research (Planets) (in Press) Link to Article [https://doi.org/10.1029/2019JE006306]
¹NASA Johnson Space Center, Houston, TX, USA
Published by arrangement with John Wiley & Son

Vera Rubin ridge (VRR) is an erosion‐resistant feature on the northwestern slope of Mount Sharp in Gale crater, Mars, and orbital visible/short‐wave infrared measurements indicate it contains red‐colored hematite. The Mars Science Laboratory Curiosity rover performed an extensive campaign on VRR to study its mineralogy, geochemistry, and sedimentology to determine the depositional and diagenetic history of the ridge and constrain the processes by which the hematite could have formed. X‐ray diffraction (XRD) data from the CheMin instrument of four samples drilled on and below VRR demonstrate differences in iron, phyllosilicate, and sulfate mineralogy and hematite grain size. Hematite is common across the ridge, and its detection in a gray‐colored outcrop suggested localized regions with coarse‐grained hematite, which commonly forms from warm fluids. Broad XRD peaks for hematite in one sample below VRR and the abundance of FeO_T in the amorphous component suggest the presence of nano‐crystalline hematite and amorphous Fe oxides/oxyhydroxides. Well‐crystalline akaganeite and jarosite are present in two samples drilled from VRR, indicating at least limited alteration by acid‐saline fluids. Collapsed nontronite is present below VRR, but samples from VRR contain phyllosilicate with d(001) = 9.6 Å, possibly from ferripyrophyllite or an acid‐altered smectite. The most likely cementing agents creating the ridge are hematite and opaline silica. We hypothesize late diagenesis can explain much of the mineralogical variation on the ridge, where multiple fluid episodes with variable pH, salinity, and temperature altered the rocks, causing the precipitation and crystallization of phases that are not otherwise in equilibrium.

¹R.V.Morris et al. (>10)
Journal of Geophysical Research (Planets) (in Press) Link to Article [https://doi.org/10.1029/2019JE006324]
¹NASA Johnson Space Center, Houston, TX, USA
Published by arrangement with John Wiley & Sons

Hydrothermal high sanidine and specular hematite are found within ferric‐rich and grey‐colored cemented basaltic breccia occurring within horizontal, weathering‐resistant strata exposed in an erosional gully of the Pu’u Poliahu cinder cone in the summit region of Maunakea volcano (Hawai’i). The cone was extensively altered by hydrothermal, acid‐sulfate fluids at temperatures up to ~400 °C, and, within strata, plagioclase was removed by dissolution from progenitor Hawaiitic basalt, and sanidine and hematite precipitated. Fe2O3T concentration and Fe3+/∑Fe redox state are ~12 wt. % and ~0.4 for progenitor basalt and 46‐60 wt. % and ~1.0 for cemented breccias, respectively, implying open‐system alteration and oxic precipitation. Hydrothermal high sanidine (adularia) is characterized by full Al,Si structural disorder with monoclinic unit‐cell (Rietveld refinement): a = 8.563(19) Å, b = 13.040(6) Å, c = 7.169(4) Å, β = 116.02(10)° and V = 719.4(19) Å3. Hematite (structure confirmed by Rietveld refinement) is the predominant Fe‐bearing phase detected. Coarse size fractions of powdered hematite‐rich breccia (500–1000 μm) are dark and spectrally neutral at visible wavelengths, confirming specular hematite, and SEM images show platy to polyhedral hematite morphologies with longest dimensions >10 μm. Smectite and a 10‐Å phyllosilicate, both chemically dominated by Mg as octahedral cation, are additional diagenetic hydrothermal alteration products. By analogy and as a working hypothesis, high sanidine (Kimberly formation) and specular hematite (Mt. Sharp group at Hartmann’s Valley and Vera Rubin ridge) at Gale crater are interpreted as diagenetic alteration products of martian basaltic material by hydrothermal processes.

¹D.Das et al. (>10)
Journal of Geophysical Research (Planets) (in Press) Link to Article [https://doi.org/10.1029/2019JE006301]
¹Department of Earth and Planetary Sciences, McGill University, Quebec, Canada
Published by arrangement with John Wiley & Sons

The NASA Curiosity rover’s ChemCam instrument suite has detected boron in calcium‐sulfate‐filled fractures throughout the sedimentary strata of Gale crater including Vera Rubin ridge (VRR). The presence of elevated B concentration provides insights into Martian subsurface aqueous processes. In this study we extend the dataset of B in Ca‐sulfate veins across Gale crater, comparing the detection frequency and relative abundances with Li. We report 33 new detections of B within veins analyzed between sols 1548 and 2311 where detections increase in Pettegrove Point and Jura members, which form VRR. The presence of B and Li in the Ca‐sulfate veins is possibly due to dissolution of pre‐existing B in clays of the bedrock by acids or neutral water and redistribution of the elements into the veins. Elevated frequency of B detection in veins of Gale crater correlate with presence of dehydration features such as desiccation cracks, altered clay minerals and detections of evaporites such as Mg‐sulfates, chloride salts in the host rocks. The increased observations of B also coincide with decreased Li concentration in the veins (average Li concentration of veins drops by ~15 ppm). Boron and Li have varying solubilities and Li does not form salts as readily upon dehydration as B, causing it to remain in the solution. So, the weak negative correlation between B and Li may reflect the crystallization sequence during dehydration on Vera Rubin ridge.

¹L.Krämer-Rugiu (>10)
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13534]
¹Aix Marseille University, CNRS, Coll France, IRD, INRAE, CEREGE, Aix‐en‐Provence, France
Published by arrangement with John Wiley & Sons

Caleta el Cobre (CeC) 022 is a Martian meteorite of the nakhlite group, showing an unbrecciated cumulate texture, composed mainly of clinopyroxene and olivine. Augite shows irregular core zoning, euhedral rims, and thin overgrowths enriched in Fe relative to the core. Low‐Ca pyroxene is found adjacent to olivine. Phenocrysts of Fe‐Ti oxides are titanomagnetite with exsolutions of ilmenite/ulvöspinel. Intercumulus material consists of both coarse plagioclase and fine‐grained mesostasis, comprising K‐feldspars, pyroxene, apatite, ilmenite, Fe‐Ti oxides, and silica. CeC 022 shows a high proportion of Martian aqueous alteration products (iddingsite) in olivine (45.1 vol% of olivine) and mesostasis. This meteorite is the youngest nakhlite with a distinct Sm/Nd crystallization age of 1.215 ± 0.067 Ga. Its ejection age of 11.8 ± 1.8 Ma is similar to other nakhlites. CeC 022 reveals contrasted cooling rates with similarities with faster cooled nakhlites, such as Northwest Africa (NWA) 817, NWA 5790, or Miller Range 03346 nakhlites: augite irregular cores, Fe‐rich overgrowths, fine‐grained K‐feldspars, quenched oxides, and high rare earth element content. CeC 022 also shares similarities with slower cooled nakhlites, including Nakhla and NWA 10153: pyroxene modal abundance, pyroxenes crystal size distribution, average pyroxene size, phenocryst mineral compositions, unzoned olivine, and abundant coarse plagioclase. Moreover, CeC 022 is the most magnetic nakhlite and represents an analog source lithology for the strong magnetization of the Martian crust. With its particular features, CeC 022 must originate from a previously unsampled sill or flow in the same volcanic system as the other nakhlites, increasing Martian sample diversity and our knowledge of nakhlites.

¹Philip T.Metzger,²Daniel T.Britt
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.113904]
¹Florida Space Institute, University of Central Florida, Orlando, Florida, USA
²Department of Physics, University of Central Florida, Orlando, Florida, USA
Copyright Elsevier

When creating asteroid regolith simulant, it is necessary to have a model of asteroid regolith to guide and to evaluate the simulant. We created a model through evaluation and synthesis of the available data sets including (1) the returned sample from Itokawa by the Hayabusa spacecraft, (2) imagery from the Hayabusa and NEAR spacecraft visiting Itokawa and Eros, respectively, (3) thermal infrared observations from asteroids, (4) the texture of meteorite regolith breccias, and (5) observations and modeling of the ejecta clouds from disrupted asteroids. Comparison of the Hayabusa returned sample with other data sets suggest the surficial material in the smooth regions of asteroids is dissimilar to the bulk regolith, probably due to removal of fines by photoionization and solar wind interaction or by preferential migration of mid-sized particles into the smooth terrain. We found deep challenges interpreting and applying the thermal infrared data so we were unable to use those observations in the model. Texture of regolith breccias do not agree with other data sets, suggesting the source regolith on Vesta was coarser than typical asteroid regolith. The observations of disrupted asteroids present a coherent picture of asteroid bulk regolith in collisional equilibrium, unlike lunar regolith, HED textures, and the Itokawa returned sample. The model we adopt consists of power laws for the bulk regolith in unspecified terrain (differential power index −3.5, representing equilibrium), and the surficial regolith in smooth terrain (differential power index −2.5, representing disequilibrium). Available data do not provide adequate constraints on maximum and minimum particle sizes for these power laws, so the model treats them as user-selectable parameters for the simulant.

^1,2Zelia Dionnet,^3,4,5Martin D. Suttle,^1,2Andrea Longobardo,^1,2Alessandra Rotundi,^3,4Luigi Folco,²Vincenzo Della Corte,⁶Andrew King
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13533]
¹Università di Napoli “Parthenope,” DIST, Centro Direzionale Isola C4, I‐80143 Naples, Italy
²INAF‐IAPS, via Fosso del Cavaliere 100, I‐00133 Rome, Italy
³Dipartimento di Scienze della Terra, Università di Pisa, V. S. Maria 53, I‐56126 Pisa, Italy
⁴Planetary Materials Group, Department of Earth Science, The Natural History Museum, Cromwell Rd, London, SW7 5BD UK
⁵Centro per l’Integrazione della Strumentazione dell’, Università di Pisa, Pisa, Italy
⁶PSICHE Beamline, Synchrotron SOLEIL, Gif‐Sur‐Yvette, France
Published by arrangement with John Wiley & Sons

Giant micrometeorites (MMs; 400–2000 µm) are exceedingly rare and scientifically valuable. Three‐dimensional nondestructive characterization by X‐ray computed tomography (X‐CT) provides information on the petrography and thus petrogenesis of MMs and serves as a guide to maximize subsequent multi‐analytical studies on such precious planetary materials. Here, we discuss the results obtained by X‐CT on 22 giant MMs and the classification based on their 3‐D density contrast images. Scoriaceous and unmelted MMs have distinct porosity ranges (10–40 vol% versus 0–25 vol%, respectively). We observe a porosity variation inside scoriaceous MMs, which allows their atmospheric entry flight history to be resolved. For the first time, spinning entry is explicitly demonstrated for four partially melted MMs. Furthermore, we are able to resolve the thermal gradient in a single particle, based on porosity variation (seen as a progressive increase in pore abundance and size with higher peak temperatures). Moreover, we explore parent body alteration through the 3‐D analysis of pores distribution, showing that shock fabrics are either absent or weakly developed in our data set. Finally, owing to the detection of pseudomorphic chondrules, we estimate that the intensively aqueously altered C1 or CI‐like material could represent 18% of the MM flux at this size fraction (400–1000 µm).

¹Christian Vollmer,¹Mandy Pelka,²Jan Leitner,³Arne Janssen
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13526]
¹Institut für Mineralogie, Westfälische Wilhelms‐Universität, Corrensstr. 24, 48149 Münster, Germany
²Particle Chemistry Department, Max Planck Institute for Chemistry, Hahn‐Meitner‐Weg 1, 55128 Mainz, Germany
³Materials Performance Centre, The University of Manchester, Oxford Road, Manchester, M13 9PL UK
Published by arrangement with John Wiley & Sons

Renazzo‐type (CR) carbonaceous chondrites belong to one of the most pristine meteorite groups containing various early solar system components such as matrix and fine‐grained rims (FGRs), whose formation mechanisms are still debated. Here, we have investigated FGRs of three Antarctic CR chondrites (GRA 95229, MIL 07525, and EET 92161) by electron microscopy techniques. We specifically focused on the abundances and chemical compositions of the amorphous silicates within the rims and matrix by analytical transmission electron microscopy. Comparison of the amorphous silicate composition to a matrix area of GRA 95229 clearly shows a compositional relationship between the matrix and the fine‐grained rim, such as similar Mg/Si and Fe/Si ratios. This relationship and the abundance of the amorphous silicates in the rims strengthen a solar nebular origin and rule out a primary formation mechanism by parent body processes such as chondrule erosion. Moreover, our chemical analyses of the amorphous silicates and their abundance indicate that the CR rims experienced progressive alteration stages. According to our analyses, the GRA 95229 sample is the least altered one based on its high modal abundance of amorphous silicates (31%) and close‐to‐chondritic Fe/Si ratios, followed by MIL 07525 and finally EET 92161 with lesser amounts of amorphous silicates (12% and 5%, respectively) and higher Fe/Si ratios. Abundances and chemical compositions of amorphous silicates within matrix and rims are therefore suitable recorders to track different alteration stages on a submicron scale within variably altered CR chondrites.

^1,2José C. Aponte,^1,2Hannah L. McLain,^1,3Danielle N. Simkus,¹Jamie E. Elsila,¹Daniel P. Glavin,¹Eric T. Parker,¹Jason P. Dworkin,⁴Dolores H. Hill,^4,5Harold C. Connolly Jr.,⁴Dante S. Lauretta
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13531]
¹Astrochemistry Laboratory, Code 691, NASA Goddard Space Flight Center, Greenbelt, Maryland, 20771 USA²Department of Chemistry, The Catholic University of America, Washington, District of Columbia, 20064 USA
³NASA Postdoctoral Program at NASA Goddard Space Flight Center, Greenbelt, Maryland, 20771 USA
⁴Lunar and Planetary Laboratory, University of Arizona, Tucson, Arizona, 85721 USA
⁵School of Earth and Environment, Rowan University, Glassboro, New Jersey, 08028 USA
Published by arrangement with John Wiley & Sons

Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.