Low-phase spectral reflectance and equivalent “geometric albedo” of meteorites powders

1,2P.Beck,1B.Schmitt,1S.Potin,3A.Pommerol,1O.Brissaud
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.114066]
1Institut de Planetologie et d’Astrophysique de Grenoble, UGA-CNRS, France
2Institut Universitaire de France, Paris, France
3Physikalisches Institute, Universität Bern, Sidlerstrasse 5, Bern CH-3012, Switzerland
Copyright Elsevier

Generally, the reflectance of a particulate surface depends on the phase angle at which it is observed. This is true for laboratory measurements on powders of natural materials as well as remote observations of Solar System surfaces. Here, we measured the dependences of reflectance spectra with phase angles, of a suite of 72 meteorites in the 400–2600 nm range. The 10–30° phase angle range is investigated in order to study the contribution of Shadow Hiding Opposition Effect (SHOE) to the phase behavior. The behavior is then extrapolated to phase angle of 0° using a polynomial fit, in order to provide grounds for comparison across meteorite groups (enabling to remove the contribution of shadows to reflectance) as well as to provide “equivalent albedo” values that should be comparable to geometric albedo values derived for small bodies. We find a general behavior of increasing strength of the SHOE with lower reflectance values (whether between samples or for a given samples with absorption features). This trend provides a first order way to correct any reflectance spectra of meteorite powders measured under standard conditions (g = 30°) from the contribution of shadows. The g = 0° calculated reflectance and equivalent albedos are then compared to typical values of albedos for main-belt asteroids. This reveals that among carbonaceous chondrites only Tagish Lake group, CI, and CM chondrites have equivalent albedo compatible with C- and D-type asteroids. On the other hand equivalent albedo derived with CO, CR and CK chondrites are compatible with L- and K-type asteroids. The equivalent albedo derived for ordinary chondrites is related to petrographic types, with low-grade petrographic type (type 3.6 and less) being generally darker that higher petrographic types. This works provides a framework for further understanding of the asteroids meteorite linkage in particular when combining with colors and spectroscopy.

The 21 μm and 30 μm emission features in carbon-rich objects

1Kevin Volk,1,2G. C. Sloan,3Kathleen E. Kraemer
Astrophysics and Space Science 365, 88 Link to Article [DOI
https://doi.org/10.1007/s10509-020-03798-2]
1Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD, 21218, USA
2Department of Physics and Astronomy, University of North Carolina, Chapel Hill, USA
3Boston College, Institute for Scientific Research, 140 Commonwealth Avenue, Chestnut Hill, MA, 02467, USA

We currently do not have a copyright agreement with this publisher and cannot display the abstract here

Mid-infrared reflectance spectroscopy of carbonaceous chondrites and Calcium–Aluminum-rich inclusions

1Andreas Morlok,1Benjamin Schiller,1Iris Weber,2Mohit Melwani Daswani,1Aleksandra N.Stojic,1Maximilian P.Reitze,1Tim Gramse,3Stephen D.Wolters,1Harald Hiesinger,3Monica M.Grady,4Joern Helbert
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2020.105078]
1Institut für Planetologie, Westfälische Wilhelms-Universität Münster, Wilhelm-Klemm-Str. 10, 48149, Münster, Germany
2Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Dr, Pasadena, CA, 91109, USA
3School of Physical Sciences, Open University, Milton Keynes, MK76AA, UK
4Institute for Planetary Research, DLR, Rutherfordstrasse 2, 12489, Berlin, Germany

We currently do not have a copyright agreement with this publisher and cannot display the abstract here

Characterizing low-temperature aqueous alteration of Mars-analog basalts from Mauna Kea at multiple scales

1Brandon P. Rasmussen,1Wendy M. Calvin,2,5Bethany L. Ehlmann,3Thomas F. Bristow,4Nicole Lautze,5Abigail A. Fraeman,1Joel W. DesOrmeau
American Mineralogist105, 1306-1316 Link to Article [http://www.minsocam.org/msa/ammin/toc/2020/Abstracts/AM105P1306.pdf]
1Department of Geological Sciences, University of Nevada, Reno, Nevada 89577, U.S.A.
2Division of Geological and Planetary Sciences, California Institute of Technology, Pasadena, California 91125, U.S.A.
3NASA Ames Research Center, Moffett Field, California 94035, U.S.A.
4School of Ocean and Earth Science and Technology, University of Hawaii at Manoa, Honolulu, Hawaii 96822, U.S.A.
5Jet Propulsion Laboratory, California Institute of Technology, Pasadena, California 91109, U.S.A.
Copyright: The Mineralogical Society of America

We performed a multi-scale characterization of aqueous alteration of Mars analog basaltic rock from a Mauna Kea drill core using high-resolution visible and short-wave infrared (VIS-SWIR) spectral imaging, scanning electron microscopy, X‑ray diffraction, and point VIS‑SWIR spectra. Several types of smectites, zeolites, and primary minerals were identified. Mineral classes were mapped in cut sec-tions extracted from the drill core and used to represent the range of alteration products seen in field data collected over 1000 m depth (Calvin et al. 2020). Ten distinct spectral end‑members identified in the cut sections were used to map the field point spectra. Trioctahedral Fe‑ and Mg‑rich smectites were present toward the top of the zone of analysis (972 m below the surface) and increased in abundance toward the bottom of the drill core (1763 m depth). The mineralogy demonstrates a general trend of discontinuous alteration that increases in intensity with depth, with less pervasive phyllosilicate alteration at the top, several zones of different mixtures of zeolites toward the center, followed by more abundant phyllosilicates in the lowest sections. Distinctly absent are Fe‑Mg phyllosilicates other than smectites, as well as carbonates, sulfates, and Al phyllosilicates such as kaolinite or illite. Furthermore, hematite was only detected in two of 24 samples. The suite of assemblages points to aqueous alteration at low-to-moderate temperatures at neutral to basic pH in low-oxygen conditions, with little evidence of extensive surface interaction, presenting a possible analog for an early Mars subsurface environment. We also present a library of VIS-SWIR spectra of the analyzed cut sections, including both spatial averages (i.e., unweighted linear mixtures) of spectral images of each cut section and single point spectra of the cut sections. This will allow for consideration of nonlinear mixing ef-fects in point spectra of these assemblages from natural surfaces in future terrestrial or planetary work.

Petrographic and spectral study of hydrothermal mineralization in drill core from Hawaii: A potential analog to alteration in the martian subsurface

1Wendy M. Calvin,2Nicole Lautze,3Joe Moore,2Donald Thomas,2Eric Haskins,1Brandon P. Rasmussen
American Mineralogist 105, 1297–1305 Link to Article [http://www.minsocam.org/msa/ammin/toc/2020/Abstracts/AM105P1297.pdf]
1Department of Geological Sciences, University of Nevada, Reno, Nevada 89577, U.S.A.
2Hawaii Institute of Geophysics and Planetology, University of Hawaii, Honolulu, Hawaii 96822, U.S.A.
3Energy and Geoscience Institute, University of Utah, Salt Lake City, Utah, 84108, U.S.A.
Copyright: The Mineralogical Society of America

Continuous rock core was collected for 1764 m (5786’) on the Pohakuloa Army Training base near the center of the big island of Hawaii. The core traverses basaltic lava flows from the volcano’s shield-building phase, and perched aquifers and higher temperature groundwaters were encountered. The collected samples record water-rock interactions of basaltic materials in a setting that may be a model for groundwater interactions on Mars. We collected visible and infrared point spectra of materials in the lowest portion of the core, where alteration was noted to become more prominent. We identi-fied three types of phyllosilicate spectral signatures and three types of zeolites. The phyllosilicates show similarity to those identified on Mars using data from the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM). Based on the field survey, 25 depths were selected for sampling and petrographic analysis of thin sections. The spectral data and thin section work have a strong agreement in the types of materials identified by the two different techniques. Both the spectral and petrographic data indicate low to moderate temperature geothermal alteration occurred in the lower half of the core. The field spectra are a useful reconnaissance tool for selecting mineralogic diversity for subsequent higher resolution and more time-consuming laboratory analysis.

Modification of the composition and density of mercury from late accretion

1Ryuki Hyodo,2Hidenori Genda,2Ramon Brasser
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2020.114064]
1ISAS, JAXA, Sagamihara, Japan
2Earth-Life Science Institute, Tokyo Institute of Technology, Tokyo 152-8550, Japan
Copyright Elsevier

Late accretion is a process that strongly modulated surface geomorphic and geochemical features of Mercury. Yet, the fate of the impactors and their effects on Mercury’s surface through the bombardment epoch are not clear. Using Monte-Carlo and analytical approaches of cratering impacts, we investigate the physical and thermodynamical outcomes of late accretion on Mercury. Considering the uncertainties in late accretion, we develop scaling laws for the following parameters as a function of impact velocity and total mass of late accretion: (1) depth of crustal erosion, (2) the degree of resurfacing, and (3) mass accreted from impactor material. Existing dynamical models indicate that Mercury experienced an intense impact bombardment (a total mass of ∼8 × 1018 − 8 × 1020 kg with a typical impact velocity of 30 − 40 km s−1) after 4.5 Ga. For this parameter range, we find that late accretion could remove 50 m to 10 km of the early (post-formation) crust of Mercury, but the change to its core-to-mantle ratio is negligible. Alternatively, the mantles of putative differentiated planetesimals in the early solar system could be more easily removed by impact erosion and their respective core fraction increased, if Mercury ultimately accreted from such objects. Although the cratering is notable for erasing the older geological surface records on Mercury, we show that ∼40 − 50wt. % of the impactor’s exogenic materials, including the volatile-bearing materials, can be heterogeneously implanted on Mercury’s surface as a late veneer (at least 3 × 1018 − 1.6 × 1019 kg in total). About half of the accreted impactor’s materials are vaporized, and the rest is completely melted upon the impact. We expect that the further interplay between our theoretical results and forthcoming surface observations of Mercury, including the BepiColombo mission, will lead us to a better understanding of Mercury’s origin and evolution.

The initial structure of chondrule dust rims II: Charged grains

1C.Xiang,1A.Carballido,1L.S.Matthews,1T.W.Hyde
Icarus (in Press) Linkto Article [https://doi.org/10.1016/j.icarus.2020.114053]
1Center for Astrophysics, Space Physics, and Engineering Research, Baylor University, Waco, TX 76798-7316, USA
Copyright Elsevier

In order to characterize the early growth of fine-grained dust rims (FGRs) that commonly surround chondrules, we simulate the growth of FGRs through direct accretion of monomers of various sizes onto the chondrule surfaces. Dust becomes charged to varying degrees in the radiative plasma environment of the solar nebula (SN), and the resulting electrostatic force alters the trajectories of colliding dust grains, influencing the structure of the dust rim as well as the time scale of rim formation. We compare the growth of FGRs in protoplanetary disks (PPD) with different turbulence strengths and plasma conditions to previous models which assumed neutral dust grains (Xiang, C., Carballido, A., Hanna, R.D., Matthews, L.S., Hyde, T.W., 2019). We use a combination of a Monte Carlo method and an N-body code to simulate the collision of dust monomers of radii 0.5 – m with chondrules whose radii are between 500 and m: a Monte Carlo algorithm is used to randomly select dust particles that will collide with the chondrule as well as determine the elapsed time interval between collisions; at close approach, the detailed collision process is modeled using an N-body algorithm, Aggregate Builder (AB), to determine the collision outcome, as well as any restructuring of the chondrule rim. For computational expediency, we limit accretion of dust monomers to a small patch of the chondrule surface. The collisions are driven by Brownian motion and coupling to turbulent gas motion in the protoplanetary disk. The charge distribution of the dust rim is modeled, used to calculate the trajectories of dust grains, and then analyze the resulting morphology of the dust rim. In a weakly turbulent region, the decreased relative velocity between charged particles causes small grains to be repelled from the chondrule, causing dust rims to grow more slowly and be composed of larger monomers, which results in a more porous structure. In a highly turbulent region, the presence of charge mainly affects the porosity of the rim by causing dust particles to deviate from the extremities of the rim and reducing the amount of restructuring caused by high-velocity collisions.

Organic contamination on the surface of meteorites as a function of space and time: A case study of the Buzzard Coulee H4 chondrite

1Libby D. Tunney,1Christopher D. K. Herd,1,2Robert W. Hilts
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13551]
1Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, T6G 2E3 Canada
2Department of Physical Sciences, MacEwan University, Edmonton, Alberta, T6J 4S2 Canada
Published by arrangement with John Wiley & Sons

The study of organic compounds in astromaterials represents a unique window into organic matter in the interstellar medium, the solar nebula, and asteroid parent bodies, and insights into pathways that may relate organic matter in these diverse environments. Unfortunately, the Earth’s surface is awash in organic material, which forms a significant source of contamination, especially for specimens of meteorite falls. Here, we employ specimens of the Buzzard Coulee H4 ordinary chondrite, the fall of which in western Saskatchewan, Canada, on November 20, 2008 was widely documented, and from which meteorites were recovered starting shortly after the fall and continuing to over 10 years later. The low intrinsic organic matter content of these H4 specimens enables their use as “blanks” for terrestrial contamination. Using dichloromethane rinses of meteorite specimen exteriors, and analysis of organic compounds by gas chromatograph‐mass spectrometry, we document the sources of terrestrial contamination as a function of location, time of collection relative to the fall, and curation and handling since collection. We find numerous terrestrial organic compounds, most of which can be attributed to the terrestrial surface on which the meteorite specimens were collected, and we consider a variety of factors that may influence the degree of contamination. To determine the source of each contaminant more accurately, we advocate for the collection of terrestrial materials (e.g., soil, vegetation) alongside meteorites. Our results have implications for how specimens from meteorite falls—especially for meteorites expected to have high intrinsic organic content—are collected, documented, and curated.

Earth’s water may have been inherited from material similar to enstatite chondrite meteorites

1Laurette Piani,1Yves Marrocchi,1Thomas Rigaudier,1,2Lionel G. Vacher,1Dorian Thomassin,1Bernard Marty
Science 369, 1110-1113 Link to Article [DOI: 10.1126/science.aba1948
Article]
1Centre de Recherches Pétrographiques et Géochimiques (CRPG), Centre National de Recherche Scientifique (CNRS)–Université de Lorraine, Vandoeuvre-les-Nancy, F-54500, France.
2Department of Physics, Washington University in St. Louis, St. Louis, MO 63130, USA.
Reprinted with permission from AAAS

The origin of Earth’s water remains unknown. Enstatite chondrite (EC) meteorites have similar isotopic composition to terrestrial rocks and thus may be representative of the material that formed Earth. ECs are presumed to be devoid of water because they formed in the inner Solar System. Earth’s water is therefore generally attributed to the late addition of a small fraction of hydrated materials, such as carbonaceous chondrite meteorites, which originated in the outer Solar System where water was more abundant. We show that EC meteorites contain sufficient hydrogen to have delivered to Earth at least three times the mass of water in its oceans. EC hydrogen and nitrogen isotopic compositions match those of Earth’s mantle, so EC-like asteroids might have contributed these volatile elements to Earth’s crust and mantle.