¹Shaofan Che,¹Kenneth J. Domanik,^1,2Thomas J. Zega
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2023.03.010]
¹Lunar and Planetary Laboratory, University of Arizona, Tucson, AZ, United States
²Department of Materials Science and Engineering, University of Arizona, Tucson, AZ, United States
Copyright Elsevier

The microstructures and chemistry of secondary feldspars and phosphates in equilibrated ordinary chondrites (OCs) suggest that fluids were involved in the formation of these phases, challenging the conventional view that secondary alteration of equilibrated OCs occur under water-absent conditions. The newly discovered Sidi El Habib 001 (SEH 001), a halite-bearing H5 OC, provides a unique opportunity to further probe the role of fluids during thermal metamorphism on the OC parent bodies. Here we report a petrographic and mineralogic study of SEH 001, with the aim of understanding the origins of halite grains and their implications for the alteration histories of equilibrated OCs. Our investigation reveals a main halite-bearing lithology and a halite-free lithology, both of which show equilibrated textures. Except for halides, no significant textural or compositional differences were observed between halite-bearing and -free lithologies. Halite occurs at all spatial scales in the main lithology and shows clear textures of replacing albitic plagioclase and Cl-apatite. Chlorapatite grains in SEH 001 are Cl-rich and many of them contain elevated amounts of “other” anions.

Our observations suggest that halite grains in SEH 001 formed in situ on the parent body via precipitation from an aqueous fluid. The replacement of plagioclase and Cl-apatite by halite and the equilibrated textures of halite-bearing and halite-free lithologies point to a hydrothermal alteration history where halite formed during advanced thermal metamorphism before the fluid was completely lost. The two lithologies were likely affected by fluids with different Cl concentrations that resulted from heterogeneous distribution of HCl hydrate. Based on comparison to experimental data, halite in SEH 001 could have survived peak metamorphism because of its relatively high thermal stability. Collisional disruption of its original parent body could also facilitate the preservation of halite via release of heat. In the rubble pile model of the OC parent body formation, subsequent accretion of hot fragments into a rubble pile body could have resulted in the blurred boundaries between halite-free and -bearing lithologies now observed in our sample. The occurrence of halite in SEH 001 is clear evidence that aqueous fluids were involved in the alteration of equilibrated OCs.

Combined with previous reports of hydrous minerals (such as phyllosilicates) and other related aqueous products in unequilibrated OCs, our study further suggests that S-type asteroids, the parent bodies of OCs, could be more hydrated than previously thought and might serve as a potential source of water for terrestrial planets in the inner solar system. Nevertheless, whether the proposed hydrothermal history of SEH 001 can be extrapolated to other equilibrated OCs needs to be tested. The in-situ formation origin of halite in SEH 001 contrasts with the exogeneous origin of halite in Monahans (1998) and Zag, suggesting that halites with different origins occurred on the OC parent bodies. The rarity of halite in OCs could be attributed to the heterogeneous distribution of HCl hydrate in the OC parent bodies, although the fragile nature of halite in terrestrial and laboratory environments also increases the likelihood of halite being destroyed in OC samples.

¹Sarbadhikari, Amit Basu, ¹Arora, Garima,²Varela, Maria E, ¹Mahajan, Ramakant R.
Journal of Earth System Science 132, 21 Link to Article [DOI 10.1007/s12040-022-02031-8]
¹Physical Research Laboratory, Ahmedabad, 380 009, India
²ICATE-CONICET, San Juan, Argentina

We currently do not have a copyright agreement with this publisher and cannot display the abstract here

¹Guido Jonker,¹Roel van Elsas,¹Jeroen H. J. L. van der Lubbe,¹Wim van Westrenen
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13966]
¹Department of Earth Sciences, Faculty of Science, Vrije Universiteit Amsterdam, Amsterdam, the Netherlands
Published by arrangement with John Wiley & Sons

The scientific value of micrometeorites collected from deep-sea sediments or glacial deposits can be limited by poorly constrained accumulation times or severe alteration, coupled with a complex infrastructure of sampling expeditions. Collecting micrometeorites from rooftops has recently become a feasible alternative, but extraction methods have not been optimized or standardized to date. Here, we show that existing methods for the recovery of melted cosmic spherules (CSs) can be strongly improved by using a sequence of mineral separation techniques, including shape separation with an asymmetric vibrator and heavy liquid density separation with overflow centrifuges. We retrieved 1006 micrometeorites from the gutter of a barn in Budel, the Netherlands. Particle diameters are 80–515 μm, with the major mode at 130 μm and a slope exponent of −4.88. Differences in size distributions among various types of CSs indicate a multi-source influx, with CS textures controlled by their parent body’s mineralogy and orbital parameters. Repeated sampling of the rooftop after accumulation times of 959 and 333 days allows for a time-integrated global mass flux estimate of 472 t year−1. This estimate is notably higher than previous rooftop-based estimates but is still severely affected by micrometeorite loss from the gutter through drainage. The mass flux peaks at an equivalent particle diameter of ~200 μm. The Budel collection is the first rooftop collection to contain abundant vitreous micrometeorites and include the coarse-grained S-type CS class. Unmelted and I-type micrometeorites remain difficult to extract from rooftop samples. Vitreous micrometeorites display various stages of weathering, showing that severe alteration of glass can progress at a faster rate in populated regions than previously assumed. This study demonstrates that methodological adjustments can drastically increase the scientific potential of rooftop micrometeorite collections.

¹E.M.Hausrath et al. (>10)
Journal of Geophysical Research (Planets) (in Press) Link to Article [https://doi.org/10.1029/2022JE007433]
¹Department of Geoscience, University of Nevada, Las Vegas, Nevada, 89154 USA
Published by arrangement with John Wiley & Sons

Martian soils are critically important for understanding the history of Mars, past potentially habitable environments, returned samples, and future human exploration. This paper examines soil crusts on the floor of Jezero crater encountered during initial phases of the Mars 2020 mission. Soil surface crusts have been observed on Mars at other locations, starting with the two Viking Lander missions. Rover observations show that soil crusts are also common across the floor of Jezero crater, revealed in 45 of 101 locations where rover wheels disturbed the soil surface, 2 out of 7 helicopter flights that crossed the wheel tracks, and 4 of 8 abrasion/drilling sites. Most soils measured by the SuperCam laser-induced breakdown spectroscopy (LIBS) instrument show high hydrogen content at the surface, and fine-grained soils also show a visible/near infrared (VISIR) 1.9 µm H2O absorption feature. The Planetary Instrument for X-ray Lithochemistry (PIXL) and SuperCam observations suggest the presence of salts at the surface of rocks and soils. The correlation of S and Cl contents with H contents in SuperCam LIBS measurements suggests that the salts present are likely hydrated. On the “Naltsos” target, magnesium and sulfur are correlated in PIXL measurements, and Mg is tightly correlated with H at the SuperCam points, suggesting hydrated Mg-sulfates. Mars Environmental Dynamics Analyzer (MEDA) observations indicate possible frost events and potential changes in the hydration of Mg-sulfate salts. Jezero crater soil crusts may therefore form by salts that are hydrated by changes in relative humidity and frost events, cementing the soil surface together.

^1,2Jan-Michael Lange, ¹Peter Suhr
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13964]
¹Senckenberg Naturhistorische Sammlungen Dresden, Dresden, Germany
²Institut für Mineralogie, Technische Universität Bergakademie Freiberg, Freiberg, Germany
Published by arrangement with John Wiley & Sons

The Ries impact is the most important cosmic event in the younger geological history of Europe. Its effects reach far beyond the area considered so far and are documented in manifold evidence. In this paper, the widely scattered reports in the literature are compiled and supported with investigations by the authors. Besides well-known ejecta features like the Brockhorizont, Reuter’s blocks, and moldavites, little known or forgotten indications, like a lechatelierite and β-cristobalite occurrence in Bavaria and unusual sedimentation phenomena in northern Germany, are presented. The paleogeographic reconstruction shows that the Ries impact occurred on the southern side of the Neogene Central European mainland. Large parts of this erosional area were devastated by the impact. Pressure waves and thermal radiation had a lasting effect on the landscape within hundreds of kilometers around the impact site. Destruction of the vegetation cover by impact-induced storms, wildfires, and heavy rainfall generated intense erosion. The adjacent sedimentation area to the north (Paleo-North Sea) experienced an increased and short-term supply of terrestrial debris to the marine environment. The stratigraphic coincidence of these exceptional sediments with the Ries event leads us to conclude that the distal effects of the impact are present here, which have so far received little or no attention in this context. The paper considers the different indications and sets them in a large-scale context.

^1,2Akira Yamaguchi et al. (>10)
Nature Astronomy (in Press) Link to Article [DOI https://doi.org/10.1038/s41550-023-01925-x]
¹National Institute of Polar Research (NIPR), Tachikawa, Tokyo, Japan
²The Graduate University for Advanced Studies (SOKENDAI), Hayama, Japan

We currently do not have a copyright agreement with this publisher and cannot display the abstract here

^1,2Lucie Riu,^2,3John Carter,²François Poulet,¹Alejandro Cardesín-Moinelo,¹Patrick Martin
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2023.115537]
¹European Space Agency (ESA), European Space Astronomy Centre (ESAC), Camino Bajo del Castillo s/n, 28692 Villanueva de la Cañada, Madrid, Spain
²Institut d’Astrophysique Spatiale (IAS), Université Paris-Saclay, Orsay, France
³Aix-Marseille Université, CNRS, CNES, LAM, Marseille, France
Copyright Elsevier

Assessing the water content at the surface of Mars is key to understand the history of water and past climate of the planet but it also is very important for future exploration and potential In Situ Resource Utilization (ISRU). Numerous locations on the surface, known to harbor hydrated minerals, have been detected and their mineralogical assemblages quantified. Based on previous analyses resulting from the modelling of OMEGA near-infrared spectra, we evaluated in this paper the amount of water that could still be stored in those hydrated minerals that were previously characterized. Overall, we find that on average at the surface the hydrated silicates are composed of ~5 wt% of water with specific regions with >20 wt% localized in 100 m2 areas, that could present a higher ISRU potential. We find that the global amount of water estimated in hydrated silicates corresponds to ~10−4 Global Equivalent Layer (m) for deposits of 1 m in depth, which represents a lower bound but could still indicate that on the surface the hydrated silicates – as detected by OMEGA (< 1% of the surface) – may not globally be an important sink of water.

^1,2Thorsten Kleine,²Theodor Steller,^1,2Christoph Burkhardt,³Francis Nimmo
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2023.115519]
¹Max Planck Institute for Solar System Research, Justus-von-Liebig-Weg 3, 37077 Göttingen, Germany
²Institut für Planetologie, Wilhelm-Klemm-Str. 10, 48149 Münster, Germany
³Department of Earth and Planetary Sciences, University of California Santa Cruz, Santa Cruz, CA 95064, USA
Copyright Elsevier

The origin of volatile elements in Mars and whether these elements derive from the inner or outer solar system is unclear. Here we show that Mars exhibits nucleosynthetic zinc (Zn) isotope anomalies similar to those of non‑carbonaceous (NC) but distinct from carbonaceous (CC) meteorites. Like for non-volatile elements, Mars’ Zn isotope composition is intermediate between those of enstatite and ordinary chondrites, demonstrating that Mars acquired volatile elements predominantly from its inner solar system building blocks. The Zn isotope data limit the contribution of CI chondrite-like material to Mars to 4% by mass at most and show that Mars accreted less CC material than Earth. The origin of these disparate CC fractions is unclear, but can place constraints on how and when CC-type material was delivered to the inner solar system.

¹Zachary A. Torrano,²Gregory A. Brennecka,¹Cameron M. Mercer,¹Stephen J. Romaniello,¹Vinai K. Rai,¹Rebekah R. Hines,¹Meenakshi Wadhwa
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2023.03.018]
¹School of Earth and Space Exploration, Arizona State University, Tempe, AZ, 85287
²Lawrence Livermore National Laboratory, Livermore, CA, 94550
Copyright Elsevier

As the earliest-dated solids in our Solar System, calcium-aluminum-rich inclusions (CAIs) provide a record of their formation environment near the young Sun and hold clues to the formation of planetary-scale isotopic reservoirs in the solar protoplanetary disk. Although CAIs from several CV, CK, CM, CO, and ordinary chondrites have been analyzed previously for their Ti isotopic compositions, CAIs from just three CV chondrites have been analyzed for their Cr isotopic compositions, and only a handful of CAIs have been measured for both their Ti and Cr isotopic compositions. We report mass-independent Ti and Cr isotopic anomalies in several CAIs from CV and CK chondrites; this is the first report of the Cr isotopic composition of a CAI from a CK chondrite. With these additional data, we aim to better constrain the compositional range of CAIs in ε50Ti versus ε54Cr space, thereby facilitating the isotopic characterization of the material inherited by the solar protoplanetary disk and the role of CAIs in the formation of distinct planetary-scale isotopic reservoirs in our early Solar System. The narrow range in isotopic anomalies in CAIs when compared to other early-formed refractory inclusions such as platy hibonite crystals (PLACs) and spinel-hibonite inclusions (SHIBs) suggests that CAIs record the mixing of these precursor materials and the averaging of their larger isotopic anomalies. The isotopic composition of CAIs is therefore likely the result of a combination of factors, including mixing of material inherited from their formation region, heterogeneous carrier phase distribution, and thermal processing in the disk. The ε50Ti and ε54Cr isotopic compositions of CAIs are not correlated, further demonstrating that these isotopic anomalies have different carrier phases. The Ti and Cr isotopic compositions of CAIs additionally show that CAIs alone cannot be responsible for the compositional difference between the non-carbonaceous chondritic (NC) and carbonaceous chondritic (CC) isotopic reservoirs but nevertheless do play a role in the formation of these large-scale isotopic reservoirs in the early Solar System.

^1,2Kaitlyn R. Goss,^2,3Mabel L. Gray,^2,3,4Michael K. Weisberg,^2,3Denton S. Ebel
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13962]
¹Department of Geology, Mount Holyoke College, South Hadley, Massachusetts, USA
²Department of Earth and Planetary Sciences, American Museum of Natural History (AMNH), New York, New York, USA
³Department of Earth and Environmental Sciences, City University (CUNY) of New York Graduate Center, New York, New York, USA
⁴Department of Physical Sciences, Kingsborough Community College—CUNY, Brooklyn, New York, USA
Published by arrangement with John Wiley & Sons

We studied a thin section of Lewis Cliff (LEW) 87223, an unusual EL3-related, enstatite chondrite (EC) that has primary and secondary features not observed in other ECs. We studied its metal-rich nodules, possible shock features, and chondrules, eight of which are Al-rich chondrules (ARCs). LEW 87223 has petrologic and compositional features similar to EL3s. Enstatite is the dominant mineral; chondrule boundaries are well defined; Si content of metal (0.5–0.6 wt%) is consistent with typical EL3; it has Cr-bearing troilite, oldhamite, and alabandite; and its O-isotopic composition is similar to other ECs. However, metal abundance in LEW 87223 (~13 vol%) is slightly higher than in other EL3s and its metal nodules are texturally and mineralogically different from other ECs. Both high and low Ni metals are present, and its alabandite has higher Fe (27.8 wt% Fe) than in other EL3s. Silicates appear darkened in plane polarized light, largely due to reduction of Fe from silicate. A remarkable feature of LEW 87223 is the high abundance of ARCs, which contain Ca-rich plagioclase and varying amounts of Na-rich plagioclase along chondrule edges and as veins. This suggests Na metasomatism and the possibility of hydrothermal fluids, potentially related to an impact event. LEW 87223 expands the range of known EC material. It shows that ECs are more diverse and record a wider range of parent body processes than previously known. LEW 87223 is an anomalous EL3, potentially the first member of a new EC group should similar samples be discovered.