Asteroid Itokawa … but when and how did it form exactly?

Fred Jourdana,b,c, Nicholas E. Timmsc, Tomoki Nakamurad, William D.A. Rickardb, Celia Mayersb

Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2025.09.020]
aWestern Australian Argon Isotope Facility, Curtin University, Australia
bJohn de Laeter Centre, Curtin University, Australia
cSpace Science and Technology Centre & School of Earth and Planetary Sciences, Curtin University, Australia
dLaboratory for Early Solar System Evolution, Department of Earth Science Graduate School of Science, Tohoku University Aoba, Sendai, Miyagi Japan
Copyright Elsevier

Asteroid Itokawa is made of reassembled fragments from a monolithic parent asteroid which got shattered during a collision with a large object. Data are scarce regarding the metamorphic processes that occurred on the monolithic parent body and the age and nature of the catastrophic disruption event. Here, we investigate the timing of the metamorphism inside the parent body of Asteroid Itokawa and the age and nature of the catastrophic breakup event recorded in particles returned from Itokawa. We studied three regolith dust particles recovered by the Hayabusa space craft from the rubble pile asteroid 25,143 Itokawa using electron backscatter diffraction, time-of-flight secondary ion mass spectrometry, and 40Ar/39Ar dating techniques. Our results show that none of the particles show noticeable sign of shock metamorphism. Two of the particles yielded 40Ar/39Ar age of 4559 ± 61 and 4130 ± 33 million years (Ma), while a third particle returned a maximum error age of 703 ± 53 Ma. When combined with existing data, and diffusion models, these results show that ∼4.5 billion years (Ga) ago, Itokawa’s parent monolithic body cooled down from a peak metamorphism temperature ∼800 °C to ∼300 °C in less than 64 million years at a depth of >20 km. Then at ∼4.22 Ga, Itokawa’s parent body was shattered in a collisional process involving a heterogeneous temperature distribution during the impact, with some regions escaping shock metamorphism and experiencing less than a few hundred degrees Celsius. The fragments re-agglomerated in a larger rubble pile body where they subsequently cooled down over tens of millions of years. For the next 4 billion years, Asteroid Itokawa was regularly impacted and progressively shrunk by mass wasting.

Using carbon isotopes to trace the origin of volatiles on Earth and Mars

Damanveer S. Grewala, Sujoy Mukhopadhayb

Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2025.09.014]
aDepartment of Earth and Planetary Sciences, Yale University, New Haven, CT 06511, USA
bSchool of Earth and Space Exploration, Arizona State University, Tempe, AZ 85281, USA
Copyright Elsevier

The distinct accretionary histories of Earth and Mars – with Earth experiencing protracted growth and small contributions from outer solar system (carbonaceous, CC) materials, and Mars undergoing rapid growth with building materials drawn almost exclusively from the inner solar system (non-carbonaceous, NC) – highlight key differences in planetary formation. These contrasts underscore the importance of a comparative planetology framework for understanding the origin of volatiles in terrestrial planets. In this study, we examined the relationship between the carbon (C) isotopic compositions of planetary and planetesimal reservoirs to trace the origin of volatiles on Earth and Mars. The mean δ13C value of magmatic C in Martian meteorites (−20 ‰) is significantly lower than that of the bulk silicate Earth (BSE), with a canonical value of −5 ‰. While basaltic achondrites, magmatic iron meteorites, and ordinary chondrites from the NC reservoir display δ13C values similar to Martian meteorites, the BSE δ13C value is comparable to volatile-rich CC chondrites such as CI, CM, and CR, as well as with enstatite chondrites and ureilites from the NC reservoir. If Martian magmas underwent minimal C isotopic fractionation during degassing or degassed under kinetic conditions, then the δ13C value of the Martian mantle likely reflects accretion from thermally processed undifferentiated (ordinary chondrite-like) and differentiated NC materials. In contrast, if extensive degassing occurred via Rayleigh fractionation under equilibrium conditions, the δ13C value of the Martian mantle would have a higher δ13C value (−12 to −10 ‰) than that recorded in Martian meteorites – though still lighter than that of the canonical BSE δ13C. This implies a contribution from relatively 13C-rich NC materials, potentially similar to enstatite chondrites. For BSE, although the canonical δ13C value of –5 ‰ overlaps with those of enstatite chondrites and ureilites, the late-stage delivery of volatile-rich CC materials during the main phase of Earth’s growth, which was critical for establishing its water and nitrogen inventories, likely biased its C isotopic composition towards a CC-like signature. However, a lower mean δ13C value of −8.4 ‰ of the MORB mantle, as proposed by recent studies, could mean that Earth’s mantle still preserves the signature of 13C-poor, thermally processed NC materials accreted during the early stages of the planet’s growth. The observed heterogeneity in mantle C isotopic compositions, similar to that seen in H and N isotopes, could therefore reflect a mixed contribution from both NC and CC materials. These findings suggest that the δ13C value of the BSE could be lower than the canonical estimate and may align more closely with the proposed value for the MORB mantle. Taken together, these findings suggest that the contrasting accretionary histories of Earth and Mars led to fundamentally different pathways for volatile acquisition. These divergent pathways likely shaped the long-term geochemical evolution of each planet and influenced their potential for habitability.

Excess 40Ar in Chang’e-5 lunar soils suggests a possible origin from Earth wind

Li Zhaoa,b,e, Liwu Lia,c, Chunhui Caoa,c, Qingyan Tangd, Xianbin Wanga

Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116803]
aInstitut für Planetologie, Universität Münster, Wilhelm-Klemm-Str. 10, 48149 Münster, Germany
bDepartment of Earth, Environmental and Planetary Sciences, Brown University, Providence, RI 02912, USA
aApollo 15 Commander, USA
Copyright Elsevier

The abundance of 40Ar in lunar soils is significantly higher than the expected values from solar wind implantation and 40K decay, a phenomenon known as 40Ar excess. Traditionally, this excess is attributed to 40Ar generated by the decay of 40K within the Moon. This radiogenic 40Ar degasses to the lunar surface, where it is ionized by solar radiation and subsequently captured by lunar soils. However, stepwise heating (200 °C–1300 °C) and degassing analyses of noble gas isotopes in Chang’e-5 lunar soils samples reveal the presence of two types of 40Ar: one unrelated to 36Ar, likely originating from in situ 40K decay in the soils, and another correlated with 36Ar, which may primarily derive from Earth wind. Earth wind, an ion flux formed by the escape of Earth’s atmosphere, is thought to be injected onto the lunar surface under the regulation of Earth’s magnetosphere. The study proposes that the excess 40Ar in lunar soils may primarily stem from the continuous escape of Earth’s atmosphere and be injected onto the lunar surface through both the inner and outer regions of Earth’s magnetosphere, offering a new perspective for understanding volatile exchange between the Earth-Moon system.

Sound velocities of Anorthite at high pressures and temperatures: Implications for estimating porosity in upper lunar crust

Peng Chena et al. (>5)

Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116808]
aHigh Pressure Science Experiment Center, College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Copyright Elsevier

The porosity of the lunar crust serves as the key to deciphering crucial geological processes such as the Moon’s impact history, volcanic activity, space weathering, and the formation and evolution of its internal structure. In this study, we conducted ultrasonic interferometry experiments on polycrystalline anorthite samples under high pressures and temperatures (up to 5.7 GPa and 873 K) using synchrotron radiation technology. We obtained the relationships between the compressional wave velocity (VP) and shear wave velocity (VS) of anorthite with varying pressure and temperature. The elastic properties of anorthite were fitted as follows: . By integrating these results with the lunar velocity model derived from the Apollo missions, we constructed a porosity model for the upper lunar crust, using anorthite as a representative mineral. The results indicate that the thickness of the lunar regolith (weathered surface layer) is approximately 30 km. Within the top 1 km of the lunar surface, porosity ranges from 30 % to 90 %. At the depth of 1–30 km, porosity ranges from 0 % to 50 %. At the depth of 30–50 km, porosity is less than 10 %. This study provides constraints on the porosity of the lunar surface and offers scientific guidance for the safety and design of future lunar exploration missions.

Magnesium, iron, and calcium isotope signatures of Chicxulub impact spherules: Isotopic fingerprint of the projectile and plume thermodynamics

Courtney Jean Rundhauga, Martin Schillera, Martin Bizzarroa, Zhengbin Denga,b, Hermann Dario Bermúdezc,d,e
Earth and Planetary Science Letters 669, 119592 Open Access Link to Article [https://doi.org/10.1016/j.epsl.2025.119599]
aCentre for Star and Planet Formation, Globe Institute, University of Copenhagen, Øster Voldgade 5–7, 1350 Copenhagen K, Denmark
bDeep Space Exploration Laboratory/CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, China
cDepartment of Earth and Environmental Studies, Montclair State University, Montclair, NJ 07043, USA
dGrupo de Investigación Paleoexplorer, 1400-37 Trexlertown Rd, PA 18062, USA
eDepartamento de Geociencias, Universidad Nacional de Colombia, Bogotá 11001, Colombia

The Cretaceous-Paleogene boundary (KPB) represents a massive extinction event in Earth’s history, probably triggered by the Chicxulub asteroid impact ∼66 Ma. The event dispersed vast volumes of ejecta materials including exceptionally preserved impact spherules in the Gorgonilla Island KPB section. Previous work identified three populations of spherules at Gorgonilla: 1) ballistically transported molten spherules, 2) a mixture of molten and condensed spherules dispersed by the expansion of a high-temperature, turbulent cloud (the “pyrocloud”), and 3) tiny droplets condensed from the plume (the “fireball layer”). We determine the Mg, Fe, and Ca isotopic compositions of pristine spherules to better understand the evaporation and condensation thermodynamics within the pyrocloud. We detect enrichment in mass bias corrected µ48Ca and µ26Mg* isotope signatures from the terrestrial value corresponding to an impactor contribution of ∼17–25%, most likely from a CM or CO chondrite-like asteroid. The mass-dependent δ25Mg and δ56Fe compositions are generally light or unfractionated, suggesting incomplete recondensation as the pyrocloud cooled and expanded. Combined δ25Mg and δ56Fe signatures reveal decoupling of these isotope systems, likely due to differing condensation rates. Thus, we calculate a higher average condensation rate of Fe than Mg, reflecting the thermodynamic decoupling and more complete recondensation signatures of Fe in the pyrocloud vapor. While we uncover information about the evaporation and condensation thermodynamics in the pyrocloud, the exact formation mechanisms of the complete suite of spherules remain complex with some spherules potentially forming from multiple mechanisms, including recondensation and splash–melting.

Delivery of carbonaceous materials to the Moon

Linxi Lia,b,d, et al. (>10)

Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116802]
aState Key Laboratory of Lithospheric and Environmental Coevolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
Copyright Elsevier

Asteroidal impacts play an important role in creating new lithology, shaping the morphology, and transporting water to the inner Solar System planets. Massive impact records have been preserved on the Moon; however, exogenous impactors have not been adequately identified in lunar samples. Here we carried out petrological and geochemical investigations on the newly lunar samples returned by Chang’e-6 (6CE) to estimate the source of impactors to the Moon. One spinel-bearing troctolite-like clast was identified in the 6CE soils. This clast displays porphyritic texture and is mainly composed of olivine (32 %), plagioclase (31 %), and mesostasis (34 %) with minor troilite (2 %) and spinel (1 %), and rare Fesingle bondNi metal, in area%. The sample olivines have a forsterite variation range of 75–85 and a Fe/Mn atomic ratio of 55–80. The trace element concentrations of Co (113–223 μg.g−1), Ni (121–938 μg.g−1), Cr (1191–4832 μg.g−1), and P (827–1645 μg.g−1) in olivines are notable higher than the typical lunar samples. Furthermore, these olivines exhibit notable 16O depletion features (δ18O: +10.7 ‰ to +16.7 ‰ and δ17O: +5.9 ‰ to +9.5 ‰). The investigated clast has a bulk Ir content of 51 ng.g−1, significantly higher than local lunar materials. The unusual texture, mineral chemistry, trace element concentrations, and oxygen isotopic compositions suggest this clast was likely derived from an impact event created by a CI- or CY-like carbonaceous chondrite. Such chemical and isotopic features are correlated with textures, indicating that some olivine have relict cores originated from the impactor. Such an impact event could have produced a new lithology of spinel-bearing troctolite on the Moon. Meanwhile, the carbonaceous chondritic impactor would have delivered a great amount of water and volatiles to the Moon.

Regolith without age? High-resolution regolith depth measurements across lunar maria

Elizabeth F.M. Atang
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116790]
University of Idaho, Department of Physics, 875 Perimeter Dr. MS 0903, Moscow, ID 83844-0903, USA
Copyright Elsevier

In this work, we test the established hypothesis that lunar regolith depth increases with time because the surface is continually exposed to meteorite bombardment. If this hypothesis is correct, younger surfaces should have thinner regolith than older surfaces. Because many of the regolith depth studies in the literature are for surfaces older than 3 Gy, in this paper, we study Mare regions with a wide range of ages between 1.33 Gy and 3.88 Gy. To measure regolith depths, we used the small crater morphology method based on the work by Oberbeck & Quaide. We found median regolith depths between 1.6 m to 4.0 m across our study sites. Importantly, we did not find any correlation between the thickness of the regolith and the age of the surface within the Mare units we studied. We conclude by discussing whether this result represents a true lack of correlation, which would imply an incomplete understanding of regolith formation.

Condensation of major and trace elements in dust-rich environments

Marwane Mokhtari, Bernard Bourdon

Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2025.116801]
Laboratoire de Géologie de Lyon, Terre Planètes Environnement, ENS de Lyon, CNRS, Université Lyon 1. 46 Allée d’Italie, 69007 Lyon, France
Copyright Elsevier

Recent astronomical observations have shown that dust can get locally concentrated in protoplanetary disks, forming ring structures. The thermal processing of such regions could lead to dust evaporation and local enrichment of the solar gas in condensable elements. Previous studies focusing on major element behavior have shown that condensation of such dust-enriched gas could lead to the formation of a silicate melt with compositions resembling that of chondrules. However, previous studies focusing on dust-enriched environments were restricted to a limited set of elements. To study the mineralogical and chemical composition of condensates in these conditions, we have performed equilibrium calculations using the FactSage™ software for a dust-enriched solar gas. The calculations were done with dust-enrichment factors of 1 (solar composition), 10 and 100 at pressures ranging from 10−6 bar to 10−3 bar, for a CI-chondrite dust and a H-chondrite dust. The trace element condensation was accurately modelled with newly calculated activity coefficients in different solid and melt solutions. The available gas phase database was completed with new trace element species that are important to consider in oxidized conditions. The mineralogical sequence, melt composition and condensation temperature for all condensable elements were then quantified.
Our calculations show that the iron contents of olivine in equilibrium with a gas that is x100 enriched in CI-dust is consistent with that of amoeboid olivine aggregates and chondrules. Furthermore, our estimated temperature at which fayalite can form in these conditions is higher than what was previously proposed, enabling diffusion and homogenization of iron in olivine. The calculated composition of refractory metals for a x10 and x100 CI-dust enriched gas at 10−4 bar is consistent with the measured compositions of refractory metal nuggets. The possibility for these grains to have fractionated in an H2O ice-enriched gas can be ruled out as the calculated fractionation patterns in this case did not match the observed compositions.

Trends in planetary science research in the Puna and Atacama Desert regions: Underrepresentation of local scientific institutions?

1A. Tavernier,2,3G. A. Pinto,4,5,6M. Valenzuela,1A. Garcia,1C. Ulloa,7R. Oses,8,9,10,11B. H. Foing
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13972]
1Instituto de Investigaciones Científicas y Tecnológicas, IDICTEC, Laboratorio de Investigacion de la Criosfera y Aguas, Universidad de Atacama, UDA, Copiapó, Chile
2Instituto de Investigación en Astronomía y Ciencias Planetarias, INCT, Universidad de Atacama, UDA, Copiapó, Chile
3Centre de Recherches Pétrographiques et Géochimiques, CRPG, Université de Lorraine, Nancy, France
4Departamento de Ciencias Geológicas, Universidad Católica del Norte, UCN, Antofagasta, Chile
5Millennium Institute of Astrophysics, MAS, Santiago, Chile
6Center for Excellence in Astrophysics and Associated Technologies, CATA, Santiago, Chile
7Centro Regional de Investigacion y Desarrollo Sustentable de Atacama, CRIDESAT, Universidad de Atacama, UDA, Copiapó, Chile
8Instituto de Investigación en Astronomía y Ciencias Planetarias, INCT, Universidad de Atacama, UDA, Copiapó, Chile
9International Lunar Exploration Working Group, ILEWG, EuroMoonMars, Noordwijk, The Netherlands
10Vrije Universiteit Amsterdam, VUA, Amsterdam, The Netherlands
11Universiteit Leiden, Leiden, The Netherlands
Published by arrangement with John Wiley & Sons

In 2019, while launching a multidisciplinary research project aimed at developing the Puna de Atacama region as a natural laboratory, investigators at the University of Atacama (Chile) conducted a bibliographic search identifying previously studied geographic points of the region and of potential interest for planetary science and astrobiology research. This preliminary work highlighted a significant absence of local institutional involvement in international publications. In light of this, a follow-up study was conducted to confirm or refute these first impressions, by comparing the search in two bibliographic databases: Web of Science and Scopus. The results show that almost 60% of the publications based directly on data from the Puna, the Altiplano, or the Atacama Desert with objectives related to planetary science or astrobiology do not include any local institutional partner (Argentina, Bolivia, Chile, and Peru). Indeed, and beyond the ethical questioning of international collaborations, Latin-American planetary science deserves a strategic structuring, networking, as well as a road map at national and continental scales, not only to enhance research, development, and innovation, but also to protect an exceptional natural heritage sampling extreme environmental niches on Earth. Examples of successful international collaborations such as the field of meteorites, terrestrial analogs, and space exploration in Chile or astrobiology in Mexico are given as illustrations and possible directions to follow to develop planetary science in South America. To promote appropriate scientific practices involving local researchers, possible responses at academic and institutional levels will eventually be discussed.

A comprehensive study of comet 67P/Churyumov-Gerasimenko in the 2021/2022 apparition. I. Photometry, spectroscopy, morphology

Vera Rosenbusha,b, et al. (>5)

Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116799]
aAstronomical Observatory of Taras Shevchenko National University of Kyiv, 3 Observatorna St., Kyiv 04053, Ukraine
Copyright Elsevier

We present observations of comet 67P/Churyumov–Gerasimenko during its 2021/22 apparition, aiming to investigate its dust and gas environment and compare the results with those obtained in 2015/16 using the same telescope. Quasi-simultaneous photometric, spectroscopic, and polarimetric observations were carried out at the 6-m BTA SAO telescope. The comet was observed on 6 October 2021, 31 days before perihelion, with g-sdss and r-sdss filters, and on 6 February 2022, 96 days after perihelion, using narrowband cometary filters: BC (λ4450/62 Å), RC (λ6839/96 Å), and CN(λ3870/58 Å). These were complemented by images from the 2-m Liverpool Telescope (La Palma). On 6 October 2021, a sunward jet and long dust tail were detected. By 6 February 2022, the dust coma morphology had changed noticeably, revealing a bright sunward neckline structure superimposed on the projected dust tail, along with two jets at position angles of 133° and 193°. Spectra showed strong CN emission, with relatively weak C₂, C₃, and NH₂ emissions. The dust production rate Afρ did not exceed 200 cm (uncorrected for phase angle) in both epochs. An unusual CN coma morphology was observed, with evidence of an additional CN source associated with dust jets. Geometric modeling of the jets’ dynamics indicated an active area at latitude −70° ± 4° with a jet opening angle of 20° ± 6° on 6 October 2021, and two active areas at latitudes −58° ± 5° and − 53° ± 10°, separated by longitude 150° ± 20°, producing the observed jets on 6 February 2022. The average particle velocity in the jets was about 0.32 ± 0.04 km s−1.