Quantitative Mineral Maps of the Lunar South Polar Region Derived From the Moon Mineralogy Mapper (M3) Data

1,2Kecheng Du,1,2Sicong Liu,1Xiaohua Tong,3Ming Jin,1,2Huan Xie,1,2Yongjiu Feng,1,2Yanmin Jin,1,2Jie Zhang
Journal of Geophysical Research: Planets (in Press) Link to Article [https://doi.org/10.1029/2024JE008842]
1College of Surveying and Geo‐Informatics, Tongji University, Shanghai, China,
2Shanghai Key Laboratory for Planetary Mapping and Remote Sensing for Deep Space Exploration, Tongji University, Shanghai, China,
3Institute of Geology,Chinese Academy of Geological Sciences, Beijing, China
Published by arrangement with John Wiley & Sons

The lunar south polar region has been a focus of human exploration due to its potential rich water-ice and mineral resources. However, scientific exploration of this area based on spectral data is limited due to challenging lighting conditions and complex topography. In this work, we used the Moon Mineralogy Mapper (M3) and Lunar Orbiter Laser Altimeter (LOLA) reflectance data to construct a hyperspectral cube in the lunar 83°–90°S region. Mineralogical abundance maps of the four major lunar minerals were derived from M3 data at a spatial resolution of ∼193 m/pixel. Quantitative mineral maps of four common lunar minerals, including high-calcium pyroxene (HCP), low-calcium pyroxene (LCP), olivine, and plagioclase, were derived from the M3 data, with abundance ranges consistent with those from the Kaguya Spectral Profiler (SP) data. The high-resolution mineral maps enhance the identification of mineral distribution details, such as purest anorthosite enrichment in the crater wall and floor of the Shackleton Crater. Comprehensive analysis of the mineral abundance maps reveals geological characteristics and potential effects of impact events, with particular emphasis on Artemis III mission landing site candidates. Pyroxene enrichment detected in the De Gerlache-Kocher Massif region may present an opportunity to collect South Pole-Aitken ejecta materials.

Duration of high temperature-pressure conditions in impact-induced plumes on the moon

1Xiaoying Liu, 1Chi Zhang, 1Zongyu Yue, 1Lixin Gu, 1Jing Li, 1Heng-Ci Tian, 1Sen Hu, 1Yangting Lin
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2026.116969]
1Key Laboratory of Planetary Science and Frontier Technology, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
Copyright Elsevier

Meteorite impact is a key process on the Moon, having profoundly reshaped the lunar surface, modified the physical properties of lunar regolith, and transported water and other volatiles on the surface. However, the temperature-pressure conditions of impact-induced plumes and their duration were poorly constrained. Here, we report the first discovery of immiscibility a FeNi-P-S bead from Chang’e-5 lunar soils, which consists of abundant spherules of metallic FeNi and sulfide both evenly dispersed in phosphide-rich matrix. The observed texture and compositions are consistent with quenching of an FeNi-P-S melt droplet, generated during an iron meteorite impact. The initial droplet was homogeneous and formed at >1800 °C and > 11–16 GPa within the impact plume, based on high-pressure experiments of the Fe-P-S system. As the plume expanding, FeNi spherules emerged from the droplet at 11–16 GPa, estimated by P partitioning between the metal and P-S-rich melt. Subsequent separation of the P-S-rich melt into immiscible sulfide-rich spherules and phosphide-rich mesostasis occurred at 1 bar–3 GPa and 1000–1100 °C. The duration of the pressure declining from >11–16 GPa to 1 bar–3 GPa was estimated to be 0.5–1 s, combining the impact plume expansion model with the cooling rate inferred from the metallic bead. This study demonstrates that high-pressure conditions of impact plumes can be retained for second timescales, which is critical for chemical reactions and water and other volatile migration on the Moon’s surface.

Reflectance spectroscopy (200-4200 nm) of the red-sloped C2 carbonaceous chondrites MET 00432, Tagish Lake, Tarda, and WIS 91600 (“CT” grouplet)

1Edward A. Cloutis et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2026.116952]
1Centre for Terrestrial and Planetary Exploration, University of Winnipeg, 515 Portage Avenue, Winnipeg, MB R3B 2E9, Canada
Copyright Elsevier

Four carbonaceous chondrite (CC) meteorites – MET 00432, Tagish Lake, Tarda, and WIS 91600 – have been proposed to be members of a CC grouplet, hereafter termed the Carbonaceous Tagish Lake Grouplet (CTG). We investigated their possible affinities via a spectral reflectance-focused study of them, as chips and variously sized powders. We also considered possible spectrum-altering effects of space weathering and composition of the organic component on such red-sloped spectra. Ultraviolet-region spectra (200-400 nm) exhibit absorption features attributable to unspecific Fe2+-O and/or Fe3+-O charge transfers, possibly due to Fe-rich phyllosilicates. Both albedo and spectral slope vary as a function of grain size. The 0.35-2.50 μm interval is characterized by dark, variably red-sloped spectra with low albedos in the visible region (<6% reflectance at 0.550 μm). Spectral slopes are redder for powders than slabs or chips. CTG spectra also exhibit shallow (<4% deep) absorption bands attributable to known components, such as magnetite and phyllosilicates, particularly in the 1 μm region. Spectral analysis of an extensive suite of phyllosilicate+opaque mixtures suggests that only a subset of CTG opaque components can cause darkening and overall red spectral slopes, in particular low H/C ratio carbonaceous compounds. Other opaque components, such as iron sulfides, magnetite and other carbonaceous materials, some of which are red-sloped when pure, cause spectral bluing or only slight spectral reddening. Albedo and spectral slopes and shapes are affected by physical properties, such as grain size, as well as the types, compositions, abundances, dispersion, and grain sizes of opaque components. At longer wavelengths (to 14 μm), CTG spectra exhibit a number of absorption features that can be related to their silicate, carbonate, and organic components. A prominent absorption feature is present in the 2.7-3.1 μm region attributable to phyllosilicates ± H2O, some of which is likely attributable to terrestrial alteration. Petrological, mineralogical, and isotopic information provide support for these meteorites having strong affinities to each other and comprising a grouplet. Additional CTG meteorites may lurk among the many tens of CCs that have been incompletely characterized.

Graphite crystallinity and thermal record in Campo del Cielo IAB iron meteorite: A window into impact processing on a chondritic body

1,2,3Xiao Tian Deng,1,2Hong Yi Chen,3Yang Li,1,2Jin Yu Zhang,1,2Lan Fang Xie,3Si Zhe Zhao,4Zhuang Guo,5Chen Li6Kai Rui Tai
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70085]
1Institution of Meteorites and Planetary Materials Research, Key Laboratory of Planetary Geological Evolution of Guangxi Provincial Universities, Guilin University of Technology, Guilin, China
2Guangxi Key Laboratory of Hidden Metallic Ore Deposits Exploration, Guilin University of Technology, Guilin, China
3Institute of Geochemistry, Chinese Academy of Sciences, Guiyang, China
4Department of Geology, Northwest University, Xi’an, China
5School of Engineering, Yunnan University, Kunming, China
6College of Earth and Planetary Sciences, Chengdu University of Technology, Chengdu, China
Published by arrangement with John Wiley & Sons

The Campo del Cielo iron meteorite (IAB-MG) provides a unique window into earlysolar system processes, particularly the formation and evolution of carbon phases innon-magmatic iron meteorites. In this study, we conducted a systematic nanostructuralinvestigation of three distinct graphite occurrences—cliftonite (type I), interstitial graphite(type II), and silicate-associated graphite (type III)—within a single meteorite sample. Using amulti-technique approach, including scanning and transmission electron microscopy, Ramanspectroscopy, X-ray diffraction, and electron probe microanalysis, we characterized theircrystallographic properties, crystallinity, crystallite size, and crystallization temperatures. Ourresults reveal that type III graphite exhibits the highest crystallinity and largest crystallite size(average La = 287.4 nm), with a peak crystallization temperature of 1112°C, while types Iand II show comparable nanostructural features and lower crystallization temperatures(991°C and 1013°C, respectively). These differences reflect a crystallization sequence fromsilicate-associated with metal-encapsulated graphite, consistent with formation inimpact-generated metallic melt pools. The absence of diamond or diaphite structures indicatespeak shock pressures below 100 GPa. Combined with mineral chemistry data indicating areduced, magnesium-rich silicate assemblage akin to CR chondrites, our findings support anorigin via impact melting on a partially differentiated, CR-like parent body. This workunderscores the role of localized, shock-induced thermal processing in shaping the carboninventory of primitive planetary bodies and provides a mineralogical framework forunderstanding the complex formation history of IAB iron meteorites.

The effect of early diagenetic processes on the quantification of fossil micrometeorite abundance and flux in the geological record

1Isabelle S. Mattia,1Matthew J. Genge,2Martin D. Suttle
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70105]
1Department of Earth Sciences, Imperial College London, London, UK
2School of Physical Sciences, The Open University, Milton Keynes, UK
Published by arrangement with John Wiley & Sons

Fossil micrometeorites (MMs) recovered from lithified sedimentary rocks, particularlyiron-rich (I-type) cosmic spherules (CSs) provide valuable insights into past dust-forming events.Their abundances, when combined with estimates of local sedimentation rates can be used toreconstruct the flux of extraterrestrial dust. However, their preservation in the geological recordis highly susceptible to postdepositional diagenetic processes, complicating their quantificationand past flux calculations. This study investigated lenticular calcitic concretions as potential sitesof enhanced preservation of fossil MMs. A total of 17–18 I-types (but no silicate dominatedspherules, S-types) were recovered from Cenomanian sediments within the Cretaceous ChalkSupergroup at Lulworth Cove, England. The I-types, identified by optical and SEM–EDXanalyses, exhibited typical dendritic textures and varying degrees of alteration, including mottledsurfaces and loss of Ni and Cr by leaching. Calcitic concretions yielded a comparableconcentration of I-types to the surrounding hosting marl, but due to the added carbonatecementation during their growth, preservation per original sediment volume was shown to beenhanced (potentially by up to ~60%). Calcitic concretions can therefore act asmicroenvironments that enhance fossil MM preservation by limiting complete dissolution andloss of I-types. To constrain possible diagenetic effects on fossil MM quantification, futurestudies should compare cosmic dust yields across multiple sites exposing the same targetedsedimentary horizon.

Isotopic evidence for volatile loss driven by South Pole-Aitken basin–forming impact

1Heng-Ci Tian,1Chi Zhang,2Wen-Jun Li,2Dingshuai Xue,2Jing Wang,1Wei Yang,2Yan-Hong Liu,1Yangting Lin,2Xian-Hua Li,2Fu-Yuan Wu
Proceedings of the National Academy of Sciences of the USA (PNAS) 123, e2515408123 Open Access Link to Article [https://doi.org/10.1073/pnas.2515408123]
1Key Laboratory of Planetary Science and Frontier Technology, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
2State Key Laboratory of Lithospheric and Environmental Coevolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China

Recent studies suggest that the lunar farside experienced a magma ocean evolution similar to that of the nearside. Thus, the nearside-farside dichotomy, such as volcanism and crustal thickness, is likely related to the South Pole-Aitken (SPA) basin–forming impact. Although the noritic clasts found in Chang’e-6 (CE6) samples may originate from crustal remelting induced by the SPA impact, how (and whether) the lunar mantle was modified by this event remains unclear. Here, we present the first high-precision iron (Fe) and potassium (K) isotopic measurements of CE6 low-Ti basalts, revealing higher δ56Fe (0.13 to 0.21‰) and δ41K (0 to 0.09‰) in these basalts compared to their Apollo and Chang’e-5 (CE5) counterparts (δ56Fe: 0 to 0.11‰; δ41K: −0.29 to −0.04‰). The heavy Fe and K isotopic signatures are unlikely to be derived from cosmogenic effects or the addition of impactor-derived materials. Instead, the heavy Fe isotopes can be explained by partial melting and fractional crystallization processes. For K isotopes, however, the data require that the mantle source beneath the SPA basin had a heavier K isotopic composition than that of the nearside mantle, most likely resulting from evaporation caused by the SPA-forming impact. Our results thus provide robust evidence for significant impact-induced modification of the lunar mantle and demonstrate that large-scale impacts may have played a key role in creating lunar asymmetry.

Ferromagnesian Clay Diversity Across Mars’ Crustal Dichotomy: A Window Into Early Aqueous Environments

1Jeremy Brossier,1Francesca Altieri,1Maria Cristina De Sanctis,1Alessandro Frigeri,1Marco Ferrari,1Simone De Angelis,1Enrico Bruschini,1Monica Rasmussen,1Janko Trisic Ponce
Journal of Geophysical Research: Planets (in Press) Open Access Link to Article [https://doi.org/10.1029/2025JE009393]
1Institute for Space Astrophysics and Planetology (IAPS), National Institute of Astrophysics (INAF), Rome, Italy
Published by arrangement with John Wiley & Sons

Extensive research over the past two decades has shown that early Mars likely had a warmer,wetter climate with widespread water activity. Ferromagnesian (Fe,Mg‐rich) clay deposits are compellingmarkers of these ancient environments, helping reconstruct Mars’ hydrologic evolution, assess past habitability,and guide future exploration. This study analyzes hyperspectral data from the Compact ReconnaissanceImaging Spectrometer for Mars (CRISM) aboard NASA’s Mars Reconnaissance Orbiter, focusing on regionsalong the Martian crustal dichotomy—where clay deposits occur at the boundary between the ancient southernhighlands and the younger northern lowlands. We systematically surveyed ∼1500 CRISM targeted observations(1–2.6 μm) to identify ferromagnesian clays, distinguish them from other hydrated minerals, and characterizecompositional differences between Fe‐ and Mg‐rich species using diagnostic absorptions around 1.4, 2.3, and2.4 μm. Results reveal spatial variations in clay mineralogy: Fe‐rich nontronites are prevalent around MawrthVallis, while Mg‐rich saponites are more locally distributed in Nili Fossae and Libya Montes. Oxia Planum—the Rosalind Franklin rover landing site—exhibits more compositionally intermediate clays such asvermiculites and ferrosaponites. These differences may reflect variations in the iron and magnesium abundanceor in the iron oxidation state. Moreover, a recurring absorption near 2.5 μm suggests co‐occurring carbonateslike magnesite and siderite, increasing the potential for biosignature preservation. These findings refine ourunderstanding of Mars’ aqueous history and offer an important mineralogical context for future rover andsample return missions. They also emphasize the need for a next‐generation orbital imaging spectrometer tosucceed CRISM and extend its legacy.

Shock metamorphic effects in Itokawa phosphates: A comparison with megaregolith-derived meteorites

1E. Dobrică,1A. N. Krot,2A. J. Brearley
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.70102]
1Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa, Mānoa, Hawai‘i, USA
2Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, USA
Published by arrangement with John Wiley & Sons

Returned regolith samples from the asteroid Itokawa provide a unique opportunity to compare shock metamorphic effects in unconsolidated regolith materials with those preserved in lithified meteorites, that is, megaregolith. We analyzed four Itokawa particles (Ueda—RA-QD02-0519, Narahara—RA-QD02-0573, Domon—RA-QD02-0588, Ishiuchi—RX-MD03-0212) containing phosphates (merrillite and apatite) to assess their impact history. To place these observations in context, we also describe the associated mineral assemblages (silicates and chromite). While both space weathering effects, irradiation and impact, are present, the primary focus of this study is on impact-related modifications. We identified microcratering with a density comparable to that measured for Murchison, rare comminution effects in subsurface regolith materials, localized melting and vaporization, and partial decomposition of chromite into a high-pressure Fe2Cr2O5 phase (modified ludwigite-type). The two apatite crystals analyzed lack any brittle deformation; however, one shows strong submicron-scale chlorine heterogeneity and porosity that are consistent with partial melting and volatile redistribution. In contrast, the two merrillite grains, identified in two different particles, contain dislocations. Their microstructures indicate distinct shock histories: one particle preserves only limited, localized deformation probably induced by micrometeoroid impacts, whereas the other shows extensive brittle deformation features consistent with a more pervasive shock event. The combination of ductile and brittle deformation, along with melting and comminution, reflects a more intense and spatially extensive shock metamorphic process. Dislocation densities are comparable to those observed in ordinary chondrites (OCs) of shock stage S2 (5–10 GPa). This study shows that phosphates in Itokawa regolith record highly localized and heterogeneous shock metamorphic overprints, in contrast to the more uniform relationship between shock metamorphic stage and phosphate deformation described in megaregolith OCs. Phosphates are sensitive shock metamorphic tracers in asteroidal regolith, but meteorite-based calibrations must be applied cautiously to unconsolidated materials.

Crossing boundaries: Brachinites and their diverse asteroidal origins

1B.G. Rider-Stokes, 1F.A. Davies, 2T.H. Burbine, 3E. MacLennan, 1R.C. Greenwood, 1S.L. Jackson, 1M. Anand, 4D. Sheikh, 1M.M. Grady
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2026.116965]
1School of Physical Sciences, The Open University, Milton Keynes MK7 6AA, UK.
2Department of Physics & Astronomy, Mount Holyoke College; 50 College Street, South Hadley, MA 01075, USA
3Department of Physics, University of Helsinki, Finland
4Department of Geology, Cascadia Meteorite Laboratory, Portland State University, USA
Copyright Elsevier

Brachinite meteorites are typically linked to the olivine-rich A-type asteroids. In this study, however, they appear to exhibit unexpected spectral diversity. Spectroscopic analysis of seven meteorites from the brachinite clan reveals two distinct populations in band parameters, overlapping with both the A-type and S-complex asteroids. This dual association shows that a single meteorite group can originate from multiple asteroid taxonomies. Notably, one S-complex-like specimen, Northwest Africa (NWA) 14,635, displays band parameters similar to those of asteroid (65803) Didymos, the target of the European Space Agency’s (ESA) ongoing Hera mission. These results underscore the value of spectroscopic characterization of poorly understood meteorite groups and identifying potential analogs that are highly relevant for current and future mission planning.