Mincy mesosiderite metallic nodules analyzed by EBSD: An approach to understanding their thermal history

1,2Laura Noel García,1María Eugenia Varela,3Shyh-Lung Hwang,4Pouyan Shen,5Raúl Bolmaro,5Martina Ávalos
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13911]
1Instituto de Ciencias Astronómicas, de la Tierra y del Espacio (ICATE), Universidad Nacional de San Juan, CONICET, J5402DSP San Juan, Argentina
2Instituto de Mecánica Aplicada, Universidad Nacional de San Juan, J5400ARL San Juan, Argentina
3Department of Materials Science and Engineering, National Dong Hwa University, 974 Hualien, Taiwan, ROC
4Department of Materials and Optoelectronic Science, National Sun Yat-sen University, 804 Kaohsiung, Taiwan, ROC
5Instituto de Física Rosario (IFIR), Universidad Nacional de Rosario, CONICET, S2000EKF Rosario, Argentina
Published by arrangement with John Wiley & Sons

Meteorites carry information about the most common processes that have been active in the early solar system. In particular, mesosiderites are meteorites with a structure considered to be composed of equal parts of iron–nickel metal and silicates. A natural delimitation in the study of such complex systems is the discrimination of the iron–nickel metallic and silicate domains. In this work, we focus on the metallic phases of the Mincy mesosiderite, a specimen available at the Instituto de Ciencias Astronómicas, de la Tierray y del Espacio repository. In Mincy, the metallic phases are iron–nickel–carbon alloys that are distributed forming metallic lumps or pebbles (referred to as metallic nodules in the article) in which kamacite and taenite are present, and taenite is found both at the kamacite/silicate interface and surrounded by kamacite, that is, isolated from the silicates. We made use of the electron backscattered diffraction technique to determine the crystallographic orientation relationships along the taenite/kamacite boundaries as well as for characterizing the (hkl)-specific grain boundaries regarding the underlying tilt, twist, or twinning mechanism to assist the interpretation of the phase transformations and mechanisms that could explain the formation of these metallic nodules. From the results, each of the metallic nodules has a unique temperature–pressure history and kinetics to undergo phase transformations (mainly partial melting, heterogeneous nucleation-controlled solidification, and possible evaporation–condensation) as well as liquid-phase sintering and recrystallization in its own way.

53Mn-53Cr chronology and ε54Cr-Δ17O genealogy of Erg Chech 002: The oldest andesite in the solar system

1Aryavart Anand,1Pascal M. Kruttasch,1Klaus Mezger
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13916]
1Institut für Geologie, Universität Bern, Baltzerstrasse 1+3, 3012 Bern, Switzerland
Published by arrangement with John Wiley & Sons

The meteorite Erg Chech (EC) 002 is the oldest felsic igneous rock from the solar system analyzed to date and provides a unique opportunity to study the formation of felsic crusts on differentiated protoplanets immediately after metal–silicate equilibration or core formation. The extinct 53Mn-53Cr chronometer provides chronological constraints on the formation of EC 002 by applying the isochron approach using chromite, metal–silicate–sulfide, and whole-rock fractions as well as “leachates” obtained by sequential digestion of a bulk sample. Assuming a chondritic evolution of its parent body, a 53Cr/52Cr model age is also obtained from the chromite fraction. The 53Mn-53Cr isochron age of 1.73 ± 0.96 Ma (anchored to D’Orbigny angrite) and the chromite model age constrained between $$ {1.46}_{-0.68}^{+0.78} $$ and $$ {2.18}_{-1.06}^{+1.32} $$ Ma after the formation of calcium-aluminium-rich inclusions (CAIs) agree with the 26Al-26Mg ages (anchored to CAIs) reported in previous studies. This indicates rapid cooling of EC 002 that allowed near-contemporaneous closure of multiple isotope systems. Additionally, excess in the neutron-rich 54Cr (nucleosynthetic anomalies) combined with mass-independent isotope variations of 17O provides genealogical constraints on the accretion region of the EC 002 parent body. The 54Cr and 17O isotope compositions of EC 002 confirm its origin in the “noncarbonaceous” reservoir and overlap with the vestoid material Northwest Africa 12217 and anomalous eucrite Elephant Moraine 92023. This indicates a common feeding zone during accretion in the protoplanetary disk between the source of EC 002 and vestoids. The enigmatic origin of iron meteorites remains still unresolved as EC 002, which is more like a differentiated crust, has an isotope composition that does not match known iron meteorite groups that were once planetesimal cores.

Antarctic micrometeorite composed of CP and CS IDP-like material: A micro-breccia originated from a partially ice-melted comet-like small body

1Takaaki Noguchi et al. (>10)
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13919]
1Division of Earth and Planetary Sciences, Kyoto University, Kitashirakawaoiwake-cho, Sakyo-ku, Kyoto, 606-8502 Japan
Published by arrangement with John Wiley & Sons

Asteroids and comets are thought to form in the inner and outer solar systems, respectively. Chondritic porous and smooth interplanetary dust particles (CP IDPs and CS IDPs, respectively) in the stratosphere are regarded as dust grains from comets and hydrated asteroids, respectively. Here, we describe an Antarctic micrometeorite (AMM) composed of lithologies of both CP and CS IDPs. In addition to the CS IDP-like compact lithology that experienced severe aqueous alteration, the CP IDP-like porous lithology shows evidence of very weak aqueous alteration. The structure of the organic matter in the porous lithology varies from that in the CP IDPs to aromatic-rich organic matter. In contrast, the structure of the organic matter in the compact lithology is homogenous, which is consistent with higher degrees of aqueous alteration. Its structure is more similar to that of CP IDPs and Wild 2 samples than that of meteoritic insoluble organic matter, suggesting that the compact lithology formed from the porous lithology. Some CP IDPs are related to cometary dust streams, such as those originating from 26P/Grigg-Skjellerup. In addition, the presence of this AMM indicates an additional origin of the CP IDPs and their equivalent AMMs. The mineralogy and organic chemistry of this AMM suggest that its parent body was composed of the same building blocks as those of the comets, and later experienced incomplete aqueous alteration. The AMM probably formed as microbreccia in the regolith layer composed of materials from a CP IDP-like crust and a hydrated interior.

Discriminating between impact or nonimpact origin of small meteorite crater candidates: No evidence for an impact origin for the Tor crater, Sweden

1Jüri Plado,2,3Ania Losiak,1Argo Jõeleht,4Jens Ormö,5Helena Alexanderson,5Carl Alwmark,6Eva Maria Wild,6Peter Steier,2Marek Awdankiewicz,3Claire Belcher
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13914]
1Department of Geology, University of Tartu, Ravila 14A, EE 50411 Tartu, Estonia
2Institute of Geological Sciences, Polish Academy of Sciences, Podwale 75, PL 50-449 Wrocław, Poland
3WildFIRE Lab, University of Exeter, Exeter, EX4 4PS UK
4Centro de Astrobiología CSIC-INTA, Instituto Nacional de Técnica Aeroespacial, 28850 Torrejon de Ardoz, Spain
5Department of Geology, Lund University, SE-22362 Lund, Sweden
6VERA Laboratory, Faculty of Physics, Isotope Physics, University of Vienna, Währinger Straße 17, A-1090 Vienna, Austria
Published by arrangement with Johne Wiley & Sons

Compared to intensive research on km-sized meteorite impact craters, fewer studies focus on smaller craters. The small craters are often hard or impossible to recognize using “classical” criteria like the presence of shatter cones, shocked quartz, and geochemical indicators. Therefore, a long list of candidate structures awaiting approval/disapproval of their origin has been formed over the last decades. One of them is the Tor structure in central Sweden. To test a hypothesis of an impact origin of this structure, we have performed topographical analysis, geophysical studies, 10Be exposure dating of boulders, and 14C dating of Tor-associated charcoal. None of the methods gave us a reason to claim the Tor structure is of impact origin. Thus, we support a recently suggested idea of Tor being formed by a grounded iceberg within a glacial lake.

Water-rich C-type asteroids as early solar system carbonate factories

1Victoria Froh,1Maitrayee Bose,2,3Martin D.Suttle,4Jacopo Nava,2,5Luigi Folco,1Lynda B.Williams,6JulieCastillo-Rogez
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2022.115300]
1School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85287, USA
2School of Physical Sciences, The Open University, Walton Hall, Milton Keynes MK7 6AA, UK
3Dipartimento di Scienze della Terra, Università di Pisa, 56126 Pisa, Italy
4University of Padova, Department of Geosciences, Via G.Gradenigo 6, 35131 Padova, Italy
5CISUP, Centro per l’Integrazione della Strumentazione dell’Università di Pisa, Lungarno Pacinotti 43, 56126 Pisa, Italy
6Jet Propulsion Laboratory, California Institute of Technology, 4800 Oak Grove Drive, Pasadena, CA 91109, USA
Copyright: Elsevier

Micrometeorites represent a major potential source of volatiles for the early Earth, although often overlooked due to their small sizes and the effects of atmospheric entry. In this study we explore an unusual ~2000 μm, fine-grained unmelted micrometeorite TAM19B-7 derived from a water-rich C-type asteroid. Previous analysis revealed a unique O-isotope composition and intensely aqueously altered geological history. We investigated its carbon isotopic composition using the NanoSIMS and characterized the carbon-bearing carriers using Raman and Near-Infrared spectroscopy. We found that TAM19B-7 has a 13C enriched bulk composition (δ13C = +3 ± 8 ‰), including a domain with 13C depletion (δ13C = −27.1 ‰). Furthermore, a few micro-scale domains show 13C enrichments (δ13C from +12.9 ‰ to +32.7 ‰) suggesting much of the particle’s carbon content was reprocessed into fine-grained carbonates, likely calcite. The heavy bulk C-isotope composition of TAM19B-7 indicates either open system gas loss during aqueous alteration or carbonate formation from isotopically heavy soluble organics. Carbonates have been detected on small body surfaces, including across dwarf planet Ceres, and on the C-type asteroids Bennu and Ryugu. The preservation of both carbonates with 13C enrichments and organic carbon with 13C depletion in TAM19B-7, despite having been flash heated to high temperatures (<1000 °C), demonstrates the importance of cosmic dust as a volatile reservoir.

Liquidus determination of the Fe-S and (Fe, Ni)-S systems at 14 and 24 GPa: Implications for the Mercurian core

1,2Allison Pease,2Jie Li
Earth and Planetary Science Letters 599, 117865 Link to Article [https://doi.org/10.1016/j.epsl.2022.117865]
1Department of Earth and Environmental Sciences, Michigan State University, East Lansing, MI, 48824, USA
2Department of Earth and Environmental Sciences, University of Michigan, Ann Arbor, MI, 48109, USA
Copyright Elsevier

Mercury has fascinated researchers for decades due to its sizable metallic core and weak magnetic field. The behavior of Fe-S and (Fe, Ni)-S systems provides constraints on core conditions and regimes of solidification to predict magnetic field strength. In this study, we investigate the melting behavior of the (Fe, Ni)-S system, a candidate composition to model the Mercurian core. We observe that the Fe-S liquidus has an inflection point at ∼10 wt.% S at 14 GPa and ∼11.5 wt.% S at 24 GPa, while (Fe, Ni)-S does not. At 24 GPa, Ni may lower the melting point of the Fe-S system by as much as 300 °C, indicating that solidification models and adiabatic calculations must account for the presence of Ni.

New methods for determination of the mass-independent and mass-dependent platinum isotope compositions of iron meteorites by MC-ICP-MS

1,2,3Poole, Graeme M.,1Stumpf, Roland,1Rehkämper, Mark
Journal of Analytical Atomic Spectrometry 37, 783-794 Open Access Link to Article [DOI 10.1039/d1ja00468a]
1Department of Earth Science and Engineering, Imperial College London, London, SW7 2AZ, United Kingdom
2School of Earth Sciences, University of Bristol, Bristol, BS8 1RJ, United Kingdom
3Imaging and Analysis Centre, Natural History Museum, London, SW7 5BD, United Kingdom

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Determination of the zirconium isotopic composition of the new isotopic standard NRC ZIRC-1 using MC-ICP-MS

1Tian, Shengyu,1Moynier, Frederic,1Inglis, Edward C.,2Jensen, Ninna K.,2Deng, Zhengbin,2Schiller, Martin,1,2Bizzarro, Martin
Journal of Analytical Atomic Spectrometry 37, 656 – 662 Link to Article [DOI 10.1039/d1ja00418b]
1Université de Paris, Institut de Physique Du Globe de Paris, CNRS, Paris cedex 05, France
2Centre for Star and Planet Formation, Globe Institute, University of Copenhagen, Copenhagen, Denmark

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Multi-collector Inductively Coupled Plasma Mass Spectrometry: New Developments and Basic Concepts for High-precision Measurements of Massdependent Isotope Signatures

1,2Greber, Nicolas D.,3Van Zuilenc, Kirsten
Chimia 76, 18-25 Open Access Link to Article [DOI 10.2533/chimia.2022.18]
1Natural History Museum of Geneva, Route de Malagnou 1, Geneva, CH-1208, Switzerland
2Institute of Geological Sciences, University of Bern, Baltzerstrasse 1+3, Bern, CH-3012, Switzerland
3Vrije Universiteit, De Boelelaan 1085, Amsterdam, 1081 HV, Netherlands

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