Visible–near-infrared observations of organics and carbonates on (101955) Bennu: Classification method and search for surface context

1S.M.Ferrone et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2021.114579]
1LESIA-Observatoire de Paris, Université PSL, CNRS, Université de Paris, Sorbonne Université, Paris, France
2Department of Physics and Astronomy, Ithaca College, Ithaca, NY, USA
Copyright Elsevier

The OSIRIS-REx Visible and InfraRed Spectrometer (OVIRS) onboard the Origins, Spectral Interpretation, Resource Identification, and Security–Regolith Explorer (OSIRIS-REx) spacecraft detected ~3.4-μm absorption features indicative of carbonates and organics on near-Earth asteroid (101955) Bennu. We apply a Kolmogorov-Smirnov similarity test to OVIRS spectra of Bennu and laboratory spectra of minerals to categorize 3.4-μm features observed on Bennu as representing either carbonates or organics. Among the 15,585 spectra acquired by OVIRS during high-resolution (4 to 9 m/spectrum footprint) reconnaissance observations of select locations on Bennu’s surface, we find 544 spectral matches with carbonates and 245 spectral matches with organics (total of 789 high-confidence spectral matches). We map the locations of these matches and characterize features of Bennu’s surface using corresponding image data. Image data are used to quantitatively characterize the albedo within each spectrometer footprint. We find no apparent relationships between spectral classification and surface morphological expression, and we find no correlation between carbon species classification and other spectral properties such as slope or band depth. This suggests either that carbonates and organics are ubiquitous across the surface of Bennu, independent of surface features (consistent with findings from laboratory studies of carbonaceous chondrites), or that the observations do not have the spatial resolution required to resolve differences. However, we find more organic spectral matches at certain locations, including the site from which the OSIRIS-REx mission collected a sample, than at others. Higher concentrations of organics may be explained if these materials have been more recently exposed to surface alteration processes, perhaps by recent crater formation.

High-resolution observations of bright boulders on asteroid Ryugu: 2. Spectral properties

1Chiho Sugimoto et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2021.114591]
1The University of Tokyo, Tokyo 113-0033, Japan
Copyright Elsevier

Many small boulders with reflectance values higher than 1.5 times the average reflectance have been found on the near-Earth asteroid 162,173 Ryugu. Based on their visible wavelength spectral differences, Tatsumi et al. (2021, Nature Astronomy, 5, doi:doi:10.1038/s41550-020-1179-z) defined two bright boulder classes: C-type and S-type. These two classifications of bright boulders have different size distributions and spectral trends. In this study, we measured the spectra of 79 bright boulders and investigated their detailed spectral properties. Analyses obtained a number of important results. First, S-type bright boulders on Ryugu have spectra that are similar to those found for two different ordinary chondrites with different initial spectra that have been experimentally space weathered the same way. This suggests that there may be two populations of S-type bright boulders on Ryugu, perhaps originating from two different impactors that hit Ryugu’s parent body. Second, the model space-weathering ages of meter-size S-type bright boulders, based on spectral change rates derived in previous experimentally irradiated ordinary chondrites, are 105–106 years, which is consistent with the crater retention age (<106 years) of the ~1-m deep surface layer on Ryugu. This agreement strongly suggests that Ryugu’s surface is extremely young, implying that the samples acquired from Ryugu’s surface should be fresh. Third, the lack of a serpentine absorption in the S-type clast embedded in one of the large brecciated boulders indicates that fragmentation and cementation that created the breccias occurred after the termination of aqueous alteration. Fourth, C-type bright boulders exhibit a continuous spectral trend similar to the heating track of low-albedo carbonaceous chondrites, such as CM and CI. Other processes, such as space weathering and grain size effects, cannot primarily account for their spectral variation. Furthermore, the distribution of the spectra of general dark boulders, which constitute >99.9% of Ryugu’s volume, is located along the trend line in slope/UV-index diagram that is occupied by C-type bright boulders. These results indicate that thermal metamorphism might be the dominant cause for the spectral variety among the C-type bright boulders on Ryugu and that general boulders on Ryugu may have experienced thermal metamorphism under a much narrower range of conditions than the C-type bright boulders. This supports the hypothesis that Ryugu’s parent body experienced uniform heating due to radiogenic energy rather than impact heating.

Heating events in the nascent solar system recorded by rare earth element isotopic fractionation in refractory inclusions

1Hu, J.Y. et al. (>10)
Science Advances 7, eabc2962 Link to Article [DOI 10.1126/sciadv.abc2962]
1Origins Laboratory, University of Chicago, 5734 South Ellis Avenue, Chicago, 60637, IL, United States
2Department of the Geophysical Sciences, Enrico Fermi Institute, Chicago Center for Cosmochemistry, University of Chicago, 5734 South Ellis Avenue, Chicago, 60637, IL, United States

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Olivines in main-group pallasites: Magma-ocean cumulates or partial melting residues?

1,2Barrat J.-A.,3Ferriere L.
Geochemical Perspective Letters 16, 47-52 Link to Article [DOI 10.7185/GEOCHEMLET.2103]
1Univ. Brest, CNRS, UMR 6538, Laboratoire Géosciences Océan, Institut Universitaire Européen de la Mer (IUEM), Place Nicolas Copernic, Plouzané, 29280, France
2Univ. Brest, CNRS, UMR 6539, Laboratoire des Sciences de l’Environnement Marin, LIA, BeBEST, Institut Universitaire Européen de la Mer (IUEM), Place Nicolas Copernic, Plouzané, 29280, France
3Natural History Museum, Burgring 7, Vienna, A-1010, Austria

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Equation of State of TiN at High Pressures and Temperatures: A Possible Host for Nitrogen in Planetary Mantles

1,2,3Daviau K.,1Fischer R.A.,1Brennan M.C.,1Dong J.,1Sure T.-A.,4Couper S.,5Meng Y.,6Prakapenka V.B.
Journal of Geophysical Research: Solid Earth 126, e2020JB020074 Link to Article [DOI
10.1029/2020JB020074]
1Department of Earth and Planetary Sciences, Harvard University, Cambridge, MA, United States
2Now at School of Science, University of Waikato, Tauranga, New Zealand
3Now at Toi-Ohomai Institute of Technology, Tauranga, New Zealand
4Department of Geology and Geophysics, University of Utah, Salt Lake City, UT, United States
5HPCAT, X-Ray Science Division, Argonne National Laboratory, Argonne, IL, United States
6Center for Advanced Radiation Sources, University of Chicago, Chicago, IL, United States

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Dendritic reidite from the Chesapeake Bay impact horizon, Ocean Drilling Program Site 1073 (offshore northeastern USA): A fingerprint of distal ejecta?

1Cavosie A.J.,2Biren M.B.,2Hodges K.V.,cWartho J.-A.,4Horton Jr. J.W.,5Koeberl C.
Geology 49, 201-205 Link to Article [DOI 10.1130/G47860.1]
1Space Science and Technology Centre, Institute for Geoscience Research, School of Earth and Planetary Science, Curtin University, Perth, 6102, Western Australia, Australia
2School of Earth and Space Exploration, Arizona State University, Tempe, 85287, Arizona, United States
3GEOMAR Helmholtz Centre for Ocean Research Kiel, Kiel, 24148, Germany
4U.S. Geological Survey, 926A National Center, Reston, 20192, Virginia, United States
5Department of Lithospheric Research, University of Vienna, Althanstrasse 14, Vienna, A-1090, Austria

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Exafs determination of clay minerals in martian meteorite allan hills 84001 and its implication for the noachian aqueous environment

1Nakada R.,2Tanabe G.,2,3Kajitani I.,3,4Usui T.,2Shidare M.,2Yokoyama T.
Minerals 11, 176 Link to Article [DOI 10.3390/min11020176]
1Kochi Institute for Core Sample Research, Japan Agency for Marine-Earth Science and Technology (JAMSTEC), 200 Monobe, Kochi, Nankoku, 783-8501, Japan
2Department of Earth and Planetary Sciences, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo, 152-8551, Japan
3Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo, Kanagawa, Sagamihara, 252-5210, Japan
4Earth-Life Science Institute, Tokyo Institute of Technology, 2-12-1 Ookayama, Meguro, Tokyo, 152-8551, Japan

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New constraints on the formation of main group pallasites derived from in situ trace element analysis and 2D mapping of olivine and phosphate

1Chernonozhkin S.M.,2McKibbin S.J.,3Goderis S.,1Van Malderen S.J.M.,3Claeys P.,1Vanhaecke F.
Chemical Geology 562, 119996 Link to Article [DOI 10.1016/j.chemgeo.2020.119996]
1Ghent University, Department of Chemistry, Atomic & Mass Spectrometry – A&MS Research Unit, Campus Sterre, Krijgslaan, 281 – S12, Ghent, 9000, Belgium
2Geowissenschaftliches Zentrum, Abteilung Isotopengeologie, Georg-August-Universität Göttingen, Goldschmidtstraße 1, Göttingen, 37073, Germany
3Vrije Universiteit Brussel, Analytical, Environmental, and Geo-Chemistry, Pleinlaan 2, Brussels, 1050, Belgium

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The effects of terrestrial weathering on samarium‑neodymium isotopic composition of ordinary chondrites

1,2Pourkhorsandi H.,1,3Debaille V.a,Armytage R.M.G.,1,4van Ginneken M.,2Rochette P.,2Gattacceca J.
Chemical Geology 562, 120056 Link to Article [DOI 10.1016/j.chemgeo.2020.120056]
1Laboratoire G-Time, Université Libre de Bruxelles, 160/02, 50, Av. F.D. Roosevelt, Brussels, 1050, Belgium
2Aix-Marseille Univ, CNRS, IRD, INRAE, CEREGE, Aix-en-Provence, France
3Jacobs/JETS, NASA Johnson Space Center, 2101 NASA Parkway, Mailcode XI3, Houston, 77058, United States
4Royal Belgium Institute of Natural Sciences, rue Vautier 29, Bruxelles, B-1000, Belgium

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Development of innovative non-destructive analytical strategies for Mars Sample Return tested on Dar al Gani 735 Martian Meteorite

1Garcia-Florentino C.,1Torre-Fdez I.,1Ruiz-Galende P.,1Aramendia J.,1Castro K.,1Arana G.,2Maguregui M.,1Ortiz de Vallejuelo S.F.,1Madariaga J.M.
Talanta 224, 121863 Link to Article [DOI 10.1016/j.talanta.2020.121863]
1Department of Analytical Chemistry, Faculty of Science and Technology, University of the Basque Country UPV/EHU, Barrio Sarriena S/n, Leioa, 48940, Spain
2Department of Analytical Chemistry, Faculty of Pharmacy, University of the Basque Country UPV/EHU, P.O. Box 450, Vitoria-Gasteiz, 01080, Spain

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