^1,2,3Samuel D. Crossley,²Richard D. Ash,^2,3Jessica M. Sunshine,⁴Catherine M. Corrigan,⁴Timothy J. McCoy
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13959]
¹Lunar and Planetary Institute, USRA, Houston, Texas, USA
²Department of Geology, University of Maryland, College Park, Maryland, USA
³Department of Astronomy, University of Maryland, College Park, Maryland, USA
⁴Department of Mineral Sciences, National Museum of Natural History, Smithsonian Institution, Washington, District of Columbia, USA
Published by arrangement with John Wiley & Sons

Models of planetary core formation beginning with melting of Fe,Ni metal and troilite are not readily applicable to oxidized and sulfur-rich chondrites containing only trace quantities of metal. Cores formed in these bodies must be dominated by sulfides. Siderophile trace elements used to model metallic core formation could be used to model oxidized, sulfide-dominated core formation and identify related meteorites if their trace element systematics can be quantified. Insufficient information exists regarding the behavior of these core-forming elements among sulfides during metamorphism prior to anatexis. Major, minor, and trace element concentrations of sulfides are reported in this study for petrologic type 3–6 R chondrite materials. Sulfide-dominated core-forming components in such oxidized chondrites (ƒO2 ≥ iron-wüstite) follow metamorphic evolutionary pathways that are distinct from reduced, metal-bearing counterparts. Most siderophile trace elements partition into pentlandite at approximately 10× chondritic abundances, but Pt, W, Mo, Ga, and Ge are depleted by 1–2 orders of magnitude relative to siderophile elements with similar volatilities. The distribution of siderophile elements is further altered during hydrothermal alteration as pyrrhotite oxidizes to form magnetite. Oxidized, sulfide-dominated core formation differs from metallic core formation models both physically and geochemically. Incongruent melting of pentlandite at 865°C generates melts capable of migrating along solid silicate grains, which can segregate to form a Ni,S-rich core at lower temperatures compared to reduced differentiated parent bodies and with distinct siderophile interelement proportions.

¹Patrick J. A. Hill,¹Libby D. Tunney,¹Christopher D. K. Herd
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13963]
¹Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada
Published by arrangement with John Wiley & Sons

The rapid recovery of meteorites mitigates the exposure of astromaterials to the terrestrial environment and subsequent contamination. Modern fireball observatories have enabled the more accurate triangulation of fireball trajectories, which has aided in the location of strewn fields, in the case of meteorite-producing events. Despite this advancement, most meteorite searches still use manual searching to locate any meteorite falls, which is often labor-intensive and has a slow coverage rate (km2 day−1). Recent work has begun exploring the application of drone technology to the recovery of meteorites; however, most of this work has focused on falls in arid environments. Our study examines the utilization of drones with thermal imaging technology to aid in the recovery of meteorites that have fallen on a snow-covered field. We created a simulated strewn field that included meteorite specimens as well as Earth rocks with similar properties (“meteowrongs”). Thermal imagery was utilized to determine whether the thermal contrast between meteorites and snow could aid in the identification of meteorites. We found that the thermal contrast was significant enough that meteorites were readily identifiable within thermal images; however, it was not significant enough to distinguish between the meteorites and the meteowrongs. The utilization of thermal imagery in conjunction with visible imagery has the potential to aid in the rapid recovery of meteorites in snow-covered landscapes.

¹Sara S. Russell et al. (>10)
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13956]
¹Planetary Materials Group, Natural History Museum, London, UK
Published by arrangement with John Wiley & Sons

The Winchcombe meteorite fell on February 28, 2021 and was the first recovered meteorite fall in the UK for 30 years, and the first UK carbonaceous chondrite. The meteorite was widely observed by meteor camera networks, doorbell cameras, and eyewitnesses, and 213.5 g (around 35% of the final recovered mass) was collected quickly—within 12 h—of its fall. It, therefore, represents an opportunity to study very pristine extra-terrestrial material and requires appropriate careful curation. The meteorite fell in a narrow (600 m across) strewn field ~8.5 km long and oriented approximately east–west, with the largest single fragment at the farthest (east) end in the town of Winchcombe, Gloucestershire. Of the total known mass of 602 g, around 525 g is curated at the Natural History Museum, London. A sample analysis plan was devised within a month of the fall to enable scientists in the UK and beyond to quickly access and analyze fresh material. The sample is stored long term in a nitrogen atmosphere glove box. Preliminary macroscopic and electron microscopic examinations show it to be a CM2 chondrite, and despite an early search, no fragile minerals, such as halite, sulfur, etc., were observed.

¹Yuma Enokido,¹Tomoki Nakamura,¹Megumi Matsumoto,²Akira Miyake,³Takazo Shibuya,⁴Changkun Park,⁵Mike Zolensky
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13961]
¹Department of Earth Science, Graduate School of Science, Tohoku University, Sendai, Japan
²Department of Geology and Mineralogy, Graduate School of Science, Kyoto University, Kyoto, Japan
³Super-cutting-edge Grand and Advanced Research (SUGAR) Program, Institute for extra-cutting-edge Science and Technology Avant-garde Research (X-Star), Japan Agency for Marine-Earth Science and Technology (JAMSTEC), Yokosuka, Japan
⁴Division of Earth-System Sciences, Korea Polar Research Institute, Incheon, Korea
⁵National Aeronautics and Space Administration, Lyndon B. Johnson Space Center, Houston, Texas, USA
Published by arrangement with John Wiley & Sons

Dmisteinbergite, a hexagonal form of CaAl2Si2O8, was found in a compact type A Ca-Al-rich inclusion (CAI) in the Allende CV3 chondrite. Scanning and transmission electron microscopic observations show that dmisteinbergite was always in contact with grossular and grossular was in contact with melilite. In addition, there is a crystallographic relationship between dmisteinbergite and anorthite. Based on the textural and crystallographic evidence, the following mineralogical alteration processes are proposed to have occurred in the CAI. (1) Melilite was replaced by grossular. High densities of vesicles in the grossular indicate that hydrogrossular might have been the primary alteration phase and dehydrated by later metamorphism. (2) Dmisteinbergite formed from (hydro)grossular through a reaction with Si-rich fluid. (3) Nano-sized minerals are formed within dmisteinbergite. (4) Dmisteinbergite was transformed to anorthite. (5) Both anorthite and dmisteinbergite were altered to nepheline. (6) Hydrogrossular was dehydrated to grossular. (Hydro)grossular, dmisteinbergite, anorthite, and nepheline in the CAI seem to have formed in the course of metasomatism that occurred in the Allende parent body. Except for the hydrogrossular dehydration, these reactions could have occurred at moderate temperature (200–250°C) in high pH fluids (pH 13–14) according to past experimental studies. Episodic changes in fluid composition seem to have occurred before reactions (2), (4), and (5), because these reactions were not completed before the next reaction started. Higher temperature is required for reactions (5) and (6) to occur. Our observation of the CAI suggests that it experienced multiple episodes of metasomatism as temperatures were rising in the Allende parent asteroid.

¹Laura B. Seifert,¹Pierre Haenecour,²Tarunika Ramprasad,³Adrian J. Brearley,^1,3Thomas J. Zega
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13958]
¹Lunar and Planetary Laboratory, University of Arizona, Tucson, Arizona, USA
²Department of Materials Science and Engineering, University of Arizona, Tucson, Arizona, USA
³Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, USA
Published by arrangement with John Wiley & Sons

Dust grains that formed around ancient stars and in stellar explosions seeded the early solar protoplanetary disk. While most of such presolar grains were destroyed during solar system formation, a fraction of such grains were preserved in primitive materials such as meteorites. These grains can provide constraints on stellar origins and secondary processing such as aqueous alteration and thermal metamorphism on their parent asteroids. Here, we report on the nature of aqueous alteration in the Miller Range (MIL) 07687 chondrite through the analysis of four presolar silicates and their surrounding material. The grains occur in the Fe-rich and Fe-poor lithologies, reflecting relatively altered and unaltered material, respectively. The O-isotopic compositions of two grains, one each from the Fe-rich and Fe-poor matrix, are consistent with formation in the circumstellar envelopes of low-mass Asymptotic Giant Branch (AGB)/Red Giant Branch (RGB) stars. The other two grains, also one each from the Fe-rich and Fe-poor matrix, have O-isotopic compositions consistent with formation in the ejecta of type-II supernovae (SNe). The grains derived from AGB/RGB stars include two polycrystalline pyroxene grains that contain Fe-rich rims. The SNe grains include a polycrystalline Ca-bearing pyroxene and a polycrystalline assemblage consistent with a mixture of olivine and pyroxene. Ferrihydrite is observed in all focused ion beam sections, consistent with parent-body aqueous alteration of the fine-grained matrix under oxidizing conditions. The Fe-rich rims around presolar silicates in this study are consistent with Fe-diffusion into the grains resulting from early-stage hydrothermal alteration, but such alteration was not extensive enough to lead to isotopic equilibration with the surrounding matrix.

¹Eric T. Parker et al. (>10)
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2023.02.017]
¹Astrobiology Analytical Laboratory, Solar System Exploration Division, NASA Goddard Space Flight Center, Greenbelt, MD 20771, U.S.A
Copyright Elsevier

The hot water and acid extracts of two different Ryugu samples collected by the Hayabusa2 mission were analyzed for the presence of aliphatic amines and amino acids. The abundances and relative distributions of both classes of molecules were determined, as well as the enantiomeric compositions of the chiral amino acids. The Ryugu samples studied here were recovered from sample chambers A and C, which were composed of surface material, and a combination of surface and possible subsurface material, respectively. A total of thirteen amino acids were detected and quantitated in these samples, with an additional five amino acids that were tentatively identified but not quantitated. The abundances of four aliphatic amines identified in the Ryugu samples were also determined in the current work. Amino acids were observed in the acid hydrolyzed and unhydrolyzed hot water extracts of asteroid Ryugu regolith using liquid chromatography with UV fluorescence detection and high-resolution mass spectrometry. Conversely, aliphatic amines were only analyzed in the unhydrolyzed hot water Ryugu extracts. Two- to six-carbon (C2-C6) amino acids with individual abundances ranging from 0.02–15.8 nmol g-1, and one- to three-carbon (C1-C3) aliphatic amines with individual abundances from 0.05–34.14 nmol g-1, were found in the hot water extracts. Several non-protein amino acids that are rare in biology, including β-amino-n-butyric acid (β-ABA) and β-aminoisobuytric acid (β-AIB), were racemic or very nearly racemic, thus indicating their likely abiotic origins. Trace amounts of select protein amino acids that were enriched in the l-enantiomer may indicate low levels of terrestrial amino acid contamination in the samples. However, the presence of elevated abundances of free and racemic alanine, a common protein amino acid in terrestrial biology, and elevated abundances of the predominately free and racemic non-protein amino acids, β-ABA and β-AIB, indicate that many of the amino acids detected in the Ryugu water extracts were indigenous to the samples. Although the Ryugu samples have been found to be chemically similar to CI type carbonaceous chondrites, the measured concentrations and relative distributions of amino acids and aliphatic amines in Ryugu samples were notably different from those previously observed for the CI1.1 carbonaceous chondrite, Orgueil. This discrepancy could be the result of differences in the original chemical compositions of the parent bodies and/or alteration conditions, such as space weathering. In addition to α-amino acids that could have been formed by Strecker cyanohydrin synthesis during a low temperature aqueous alteration phase, β-, γ-, and δ-amino acids, including C3 – C5 straight-chain n-ω-amino acids that are not formed by Strecker synthesis, were also observed in the Ryugu extracts. The suite of amino acids measured in the Ryugu samples indicates that multiple amino acid formation mechanisms were active on the Ryugu parent body. The analytical techniques used here are well-suited to search for similar analytes in asteroid Bennu material collected by the NASA OSIRIS-REx mission scheduled for Earth return in September 2023.

¹Tetsuya Yokoyama et al. (>10)
Science 379, 6634 Link to Article [DOI: 10.1126/science.abn78]
¹Department of Earth and Planetary Sciences, Tokyo Institute of Technology, Tokyo 152-8551, Japan.
Reprinted with permission from AAAS

Carbonaceous meteorites are thought to be fragments of C-type (carbonaceous) asteroids. Samples of the C-type asteroid (162173) Ryugu were retrieved by the Hayabusa2 spacecraft. We measured the mineralogy and bulk chemical and isotopic compositions of Ryugu samples. The samples are mainly composed of materials similar to those of carbonaceous chondrite meteorites, particularly the CI (Ivuna-type) group. The samples consist predominantly of minerals formed in aqueous fluid on a parent planetesimal. The primary minerals were altered by fluids at a temperature of 37° ± 10°C, about 5.2+0.8−0.7 million (statistical) or 5.2+1.6−2.1
million (systematic) years after the formation of the first solids in the Solar System. After aqueous alteration, the Ryugu samples were likely never heated above ~100°C. The samples have a chemical composition that more closely resembles that of the Sun’s photosphere than other natural samples do.

¹Ryuji Okazaki et al. (>10)
Science 379, 6634 Link to Article [DOI: 10.1126/science.abo0431]
¹Department of Earth and Planetary Sciences, Kyushu University, Fukuoka 819-0395, Japan.
Reprinted with permission AAAS

The near-Earth carbonaceous asteroid (162173) Ryugu is expected to contain volatile chemical species that could provide information on the origin of Earth’s volatiles. Samples of Ryugu were retrieved by the Hayabusa2 spacecraft. We measured noble gas and nitrogen isotopes in Ryugu samples and found that they are dominated by presolar and primordial components, incorporated during Solar System formation. Noble gas concentrations are higher than those in Ivuna-type carbonaceous (CI) chondrite meteorites. Several host phases of isotopically distinct nitrogen have different abundances among the samples. Our measurements support a close relationship between Ryugu and CI chondrites. Noble gases produced by galactic cosmic rays, indicating a ~5 million year exposure, and from implanted solar wind record the recent irradiation history of Ryugu after it migrated to its current orbit.

¹T.Nakamura et al. (>10)
Science 379, 6634 Link to Article [DOI: 10.1126/science.abn86]
¹Department of Earth Sciences, Tohoku University, Sendai 980-8578, Japan.
Reprinted with permission from AAAS

Samples of the carbonaceous asteroid Ryugu were brought to Earth by the Hayabusa2 spacecraft. We analyzed 17 Ryugu samples measuring 1 to 8 millimeters. Carbon dioxide–bearing water inclusions are present within a pyrrhotite crystal, indicating that Ryugu’s parent asteroid formed in the outer Solar System. The samples contain low abundances of materials that formed at high temperatures, such as chondrules and calcium- and aluminum-rich inclusions. The samples are rich in phyllosilicates and carbonates, which formed through aqueous alteration reactions at low temperature, high pH, and water/rock ratios of <1 (by mass). Less altered fragments contain olivine, pyroxene, amorphous silicates, calcite, and phosphide. Numerical simulations, based on the mineralogical and physical properties of the samples, indicate that Ryugu’s parent body formed ~2 million years after the beginning of Solar System formation.

¹Srivastava, Y. et al. (>10)
Current Science 124, 152-154 Link to Article [ISSN 00113891]
¹Physical Research Laboratory, Ahmedabad, 380 009, India

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