Petrogenesis and Provenance of Unique Amphibole-Bearing Carbonaceous Chondrite Almahata Sitta 202: Further Evidence for a Ceres-Sized, Water-Rich Parent Body

1Cyrena A. Goodrich et al. (>10)
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2026.02.019]
1Lunar and Planetary Institute, USRA, 3600 Bay Area Blvd, Houston, TX 77058, USA
Copyright Elsevier

Xenoliths of carbonaceous chondrites (CC) in meteoritic breccias can provide samples of primitive solar system materials that are not represented by individual meteorites and thus expand our knowledge of chemical and isotopic reservoirs in the early solar system and early geologic processes on CC parent bodies. The Almahata Sitta (AhS) polymict ureilite contains one such xenolith, referred to here as AhS 202. Hamilton et al. (2020) discovered that, unlike any other known CC, the AhS 202 xenolith contains abundant (∼12–14 vol%) amphibole, a hydrous mineral that characteristically forms in greenschist to amphibolite facies metamorphism and requires a significantly larger parent body than typically inferred (≤100 km diameter) for CC meteorite bodies. Building on that initial work, we report additional analyses of the mineralogy and petrology, and new analyses of the chemical composition, oxygen and chromium isotope compositions, and physical properties of this xenolith that further constrain its petrogenesis and provenance. Our results show that the AhS 202 precursor was chondritic and experienced aqueous alteration similar to many low petrologic type CC meteorites at temperatures of ∼ 30–100 °C and fluid pressures of PH2O < 0.1 kbar, leading to formation of serpentines, magnetite, and chlorite. However, unlike any known CC meteorite, AhS 202 was heated further under water-saturated conditions similar to prograde metamorphism of terrestrial serpentinites, leading to formation of chemically pure diopside, secondary olivine, and tremolite amphibole. Peak metamorphic conditions determined from thermodynamic modeling, constrained by olivine-magnetite oxygen isotope thermometry, were ∼ 380–430 °C and ∼ 0.5–2.25 kbar. Based on our measured density of 2.27 g/cc for AhS 202, these conditions imply parent body sizes of 600–1875 km diameter, confirming the previous estimate (640–1800 km) of Hamilton et al. (2020). The fluid-assisted metamorphic conditions experienced by AhS 202 cannot be represented in current classification systems of meteorite petrologic type, which recognize only anhydrous metamorphism; we discuss an alternative approach to the classification of such materials. Oxygen and chromium isotope compositions show an affinity between AhS 202 and CR chondrites and/or CR-related achondrites, suggesting derivation from a common reservoir. However, petrology, refractory element composition, and extremely low carbon content indicate that it did not form on the same parent body as known CR chondrites or CR-related achondrites. The existence of this sample, in combination with several even higher-pressure clasts observed in CR chondrites (Kimura et al., 2013; Hiyagon et al., 2016), suggests that this reservoir contained multiple large planetesimals.

Solar wind neon storage in vesicles in space weathered lunar samples: Implications for neon behavior in planetary materials

1Alexander M. Kling, 1Michelle S. Thompson
Geochimica et Cosmochimica Acta (in Press) Open Access Link to Article [https://doi.org/10.1016/j.gca.2026.02.016]
1Department of Earth, Atmospheric, and Planetary Sciences, Purdue University, West Lafayette, IN 47907, USA
Copyright Elsevier

Solar wind neon is incorporated into lunar regolith grains and other planetary materials via solar wind implantation. Understanding the abundance of neon relative to other solar wind gases and its trapping and storage within planetary materials can inform on both parent body processing and volatile cycling. Microstructural defects in lunar regolith grains, including vesicles formed by space weathering processes, have previously been identified to store other solar wind-derived volatiles such as hydrogen, water, and helium. Here, we use transmission electron microscopy and electron energy loss spectroscopy to identify the presence of solar wind neon and quantify its abundance in vesicles within a space weathered lunar regolith grain. The direct observation of solar wind neon trapped in vesicles offers a new understanding of the space weathering history of lunar regolith grains and other planetary materials rich in solar wind gases. The storage of solar wind neon in nanoscale vesicles also has implications for its retention, diffusivity, and fractionation which may affect interpretations of the exposure and processing histories of lunar and other planetary materials as derived from noble gas analyses.