Moon’s volcanic history revealed in glassy spherules from Apollo 17 soil 76501

1,2Alexander A. NEMCHIN,3Marc D. NORMAN,4Martin J. WHITEHOUSE,5Evgenia SALIN,2Nicholas E. TIMMS,6Tao LONG,6Xiaochao CHE,7Renaud MERLE,2Fred JOURDAN,8Tao LUO
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70103]
1School of Earth Sciences and Engineering, Nanjing University, Nanjing, China
2Space Science and Technology Centre, School of Earth and Planetary Sciences, Curtin University, Perth, Western Australia,Australia
3Research School of Earth Sciences, The Australian National University, Canberra, Australian Capital Territory, Australia
4Department of Geosciences, Swedish Museum of Natural History, Stockholm, Sweden
5Department of Geology and Mineralogy, ˚Abo Akademi University, Turku, Finland
6Beijing SHRIMP Center, Institute of Geology, Chinese Academy of Geological Sciences, Beijing, China
7Department of Earth Sciences, Uppsala University, Uppsala, Sweden
8State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan, China
Published by arrangement with John Wiley & Sons

Rapidly quenched droplets of pyroclastically erupted lava are common in lunar regolith at landing sites proximal to the maria. Here, we document the U-Pb chronologies, major element, and trace element compositions of picritic glassy particles from Apollo 17 regolith sample 76501. These particles are dominated by high-Ti compositions similar to those of the established Apollo 17 orange and black pyroclastic deposits, but the textures of some beads indicate slower cooling and/or equilibration at lower temperatures. Using a new approach to calibrate SIMS U-Pb isotopic analysis of vitrophyric beads, we show that their U-Pb ages are consistent with a single or closely timed multiple eruptions ~50–100 Ma younger than the 3752 ± 9 to 3758 ± 12 Ma crystalline mare basalts collected at this site. A few picritic beads with very low-Ti compositions may be younger, but their ages are not well defined and can be ~3.3–3.6 Ga.

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