Isotopic evidence for volatile loss driven by South Pole-Aitken basin–forming impact

1Heng-Ci Tian,1Chi Zhang,2Wen-Jun Li,2Dingshuai Xue,2Jing Wang,1Wei Yang,2Yan-Hong Liu,1Yangting Lin,2Xian-Hua Li,2Fu-Yuan Wu
Proceedings of the National Academy of Sciences of the USA (PNAS) 123, e2515408123 Open Access Link to Article [https://doi.org/10.1073/pnas.2515408123]
1Key Laboratory of Planetary Science and Frontier Technology, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
2State Key Laboratory of Lithospheric and Environmental Coevolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China

Recent studies suggest that the lunar farside experienced a magma ocean evolution similar to that of the nearside. Thus, the nearside-farside dichotomy, such as volcanism and crustal thickness, is likely related to the South Pole-Aitken (SPA) basin–forming impact. Although the noritic clasts found in Chang’e-6 (CE6) samples may originate from crustal remelting induced by the SPA impact, how (and whether) the lunar mantle was modified by this event remains unclear. Here, we present the first high-precision iron (Fe) and potassium (K) isotopic measurements of CE6 low-Ti basalts, revealing higher δ56Fe (0.13 to 0.21‰) and δ41K (0 to 0.09‰) in these basalts compared to their Apollo and Chang’e-5 (CE5) counterparts (δ56Fe: 0 to 0.11‰; δ41K: −0.29 to −0.04‰). The heavy Fe and K isotopic signatures are unlikely to be derived from cosmogenic effects or the addition of impactor-derived materials. Instead, the heavy Fe isotopes can be explained by partial melting and fractional crystallization processes. For K isotopes, however, the data require that the mantle source beneath the SPA basin had a heavier K isotopic composition than that of the nearside mantle, most likely resulting from evaporation caused by the SPA-forming impact. Our results thus provide robust evidence for significant impact-induced modification of the lunar mantle and demonstrate that large-scale impacts may have played a key role in creating lunar asymmetry.

Ferromagnesian Clay Diversity Across Mars’ Crustal Dichotomy: A Window Into Early Aqueous Environments

1Jeremy Brossier,1Francesca Altieri,1Maria Cristina De Sanctis,1Alessandro Frigeri,1Marco Ferrari,1Simone De Angelis,1Enrico Bruschini,1Monica Rasmussen,1Janko Trisic Ponce
Journal of Geophysical Research: Planets (in Press) Open Access Link to Article [https://doi.org/10.1029/2025JE009393]
1Institute for Space Astrophysics and Planetology (IAPS), National Institute of Astrophysics (INAF), Rome, Italy
Published by arrangement with John Wiley & Sons

Extensive research over the past two decades has shown that early Mars likely had a warmer,wetter climate with widespread water activity. Ferromagnesian (Fe,Mg‐rich) clay deposits are compellingmarkers of these ancient environments, helping reconstruct Mars’ hydrologic evolution, assess past habitability,and guide future exploration. This study analyzes hyperspectral data from the Compact ReconnaissanceImaging Spectrometer for Mars (CRISM) aboard NASA’s Mars Reconnaissance Orbiter, focusing on regionsalong the Martian crustal dichotomy—where clay deposits occur at the boundary between the ancient southernhighlands and the younger northern lowlands. We systematically surveyed ∼1500 CRISM targeted observations(1–2.6 μm) to identify ferromagnesian clays, distinguish them from other hydrated minerals, and characterizecompositional differences between Fe‐ and Mg‐rich species using diagnostic absorptions around 1.4, 2.3, and2.4 μm. Results reveal spatial variations in clay mineralogy: Fe‐rich nontronites are prevalent around MawrthVallis, while Mg‐rich saponites are more locally distributed in Nili Fossae and Libya Montes. Oxia Planum—the Rosalind Franklin rover landing site—exhibits more compositionally intermediate clays such asvermiculites and ferrosaponites. These differences may reflect variations in the iron and magnesium abundanceor in the iron oxidation state. Moreover, a recurring absorption near 2.5 μm suggests co‐occurring carbonateslike magnesite and siderite, increasing the potential for biosignature preservation. These findings refine ourunderstanding of Mars’ aqueous history and offer an important mineralogical context for future rover andsample return missions. They also emphasize the need for a next‐generation orbital imaging spectrometer tosucceed CRISM and extend its legacy.

Shock metamorphic effects in Itokawa phosphates: A comparison with megaregolith-derived meteorites

1E. Dobrică,1A. N. Krot,2A. J. Brearley
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.70102]
1Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa, Mānoa, Hawai‘i, USA
2Department of Earth and Planetary Sciences, University of New Mexico, Albuquerque, New Mexico, USA
Published by arrangement with John Wiley & Sons

Returned regolith samples from the asteroid Itokawa provide a unique opportunity to compare shock metamorphic effects in unconsolidated regolith materials with those preserved in lithified meteorites, that is, megaregolith. We analyzed four Itokawa particles (Ueda—RA-QD02-0519, Narahara—RA-QD02-0573, Domon—RA-QD02-0588, Ishiuchi—RX-MD03-0212) containing phosphates (merrillite and apatite) to assess their impact history. To place these observations in context, we also describe the associated mineral assemblages (silicates and chromite). While both space weathering effects, irradiation and impact, are present, the primary focus of this study is on impact-related modifications. We identified microcratering with a density comparable to that measured for Murchison, rare comminution effects in subsurface regolith materials, localized melting and vaporization, and partial decomposition of chromite into a high-pressure Fe2Cr2O5 phase (modified ludwigite-type). The two apatite crystals analyzed lack any brittle deformation; however, one shows strong submicron-scale chlorine heterogeneity and porosity that are consistent with partial melting and volatile redistribution. In contrast, the two merrillite grains, identified in two different particles, contain dislocations. Their microstructures indicate distinct shock histories: one particle preserves only limited, localized deformation probably induced by micrometeoroid impacts, whereas the other shows extensive brittle deformation features consistent with a more pervasive shock event. The combination of ductile and brittle deformation, along with melting and comminution, reflects a more intense and spatially extensive shock metamorphic process. Dislocation densities are comparable to those observed in ordinary chondrites (OCs) of shock stage S2 (5–10 GPa). This study shows that phosphates in Itokawa regolith record highly localized and heterogeneous shock metamorphic overprints, in contrast to the more uniform relationship between shock metamorphic stage and phosphate deformation described in megaregolith OCs. Phosphates are sensitive shock metamorphic tracers in asteroidal regolith, but meteorite-based calibrations must be applied cautiously to unconsolidated materials.

Crossing boundaries: Brachinites and their diverse asteroidal origins

1B.G. Rider-Stokes, 1F.A. Davies, 2T.H. Burbine, 3E. MacLennan, 1R.C. Greenwood, 1S.L. Jackson, 1M. Anand, 4D. Sheikh, 1M.M. Grady
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2026.116965]
1School of Physical Sciences, The Open University, Milton Keynes MK7 6AA, UK.
2Department of Physics & Astronomy, Mount Holyoke College; 50 College Street, South Hadley, MA 01075, USA
3Department of Physics, University of Helsinki, Finland
4Department of Geology, Cascadia Meteorite Laboratory, Portland State University, USA
Copyright Elsevier

Brachinite meteorites are typically linked to the olivine-rich A-type asteroids. In this study, however, they appear to exhibit unexpected spectral diversity. Spectroscopic analysis of seven meteorites from the brachinite clan reveals two distinct populations in band parameters, overlapping with both the A-type and S-complex asteroids. This dual association shows that a single meteorite group can originate from multiple asteroid taxonomies. Notably, one S-complex-like specimen, Northwest Africa (NWA) 14,635, displays band parameters similar to those of asteroid (65803) Didymos, the target of the European Space Agency’s (ESA) ongoing Hera mission. These results underscore the value of spectroscopic characterization of poorly understood meteorite groups and identifying potential analogs that are highly relevant for current and future mission planning.

Calcium isotopic fractionation in plagioclase from mafic-ultramafic rocks: implications for magmatic processes and planetary differentiation

1,2,3,4Wei Wu, 2,3,4Yigang Xu, 5Zhaofeng Zhang
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2026.01.014]
1School of Tourism and Geography, Shaoguan University, Shaoguan 512005 Guangdong, China
2State Key Laboratory of Isotope Geochemistry, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640 Guangdong, China
3Southern Marine Science and Engineering Guangdong Laboratory (Guangzhou), 511458 Guangdong, China
4School of Earth and Planetary Science, University of Chinese Academy of Sciences, Beijing 100049, China
5Research Center for Planetary Science, College of Geosciences, Chengdu University of Technology, Chengdu 610059 Sichuan, China
Copyright Elsevier

To constrain calcium isotopic fractionation during magma differentiation and its significance for planetary geochemistry, this study analyzed δ44/40Ca compositions of whole rocks, clinopyroxene, and plagioclase in mafic–ultramafic intrusions from two major large igneous provinces: the Tarim Large Igneous Province (Xiaohaizi intrusion) and the Emeishan Large Igneous Province (Panzhihua intrusion). Whole-rock δ44/40Ca ranges from 0.75 to 1.00 ‰ for Xiaohaizi and 0.82 to 0.97 ‰ for Panzhihua, while Pl δ44/40Ca varies from 0.69 to 1.07 ‰ (Xiaohaizi) and 0.78 to 0.99 ‰ (Panzhihua). Disequilibrium in selected samples is attributed to distinct geological processes: magma replenishment (Panzhihua) and crustal material assimilation (Xiaohaizi). For equilibrium samples, the Ca isotopic fractionation factor between Pl and melt (1000lnαPl-melt) exhibits no correlation with Pl An content and remains stable under specific temperature–pressure conditions for mafic to ultramafic plagioclase. By integrating this new dataset with published Δ44/40CaCpx-Pl data (including ab initio predictions and magmatic evolution model results), we determined 1000lnαPl-melt at 1273 K is −0.07 ± 0.10 ‰ (2SD, N = 28). This study clarifies the role of Pl in magmatic Ca isotopic fractionation, providing a reliable framework for tracing magma evolution and reconstructing early crust formation processes of terrestrial planets.

Metal–silicate partitioning of Pb and implications for the accretion of moderately volatile elements to Earth

1Jesse T. Gu, 1Rebecca A. Fischer, 1Lucy Jacobsen, 1Michail I. Petaev
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2026.01.013]
1Department of Earth and Planetary Sciences, Harvard University, Cambridge, MA, USA
Copyright Elsevier

Moderately volatile elements are depleted in the Earth relative to chondrites, but it remains uncertain to what extent these depletions of siderophile volatile elements are controlled by volatility versus core formation. Here, we report new metal–silicate partitioning experiments on Pb at pressures and temperatures up to 65 GPa and 5520 K, respectively. Combined with other moderately volatile elements, we use core formation models to show that homogeneous volatile accretion results in an overabundance of volatile siderophile elements relative to lithophile elements in the bulk Earth. Late volatile addition with metal–silicate equilibration at higher pressures and temperatures could potentially resolve this discrepancy by lowering bulk Earth abundances of volatile siderophile elements to be within uncertainty of the lithophile volatility trend. However, uncertainties in core formation parameters, element volatilities, volatile loss mechanisms, and the lithophile volatility trend complicate this interpretation. Our data support a relatively larger role for volatile depletion than for core formation in establishing the Pb content of the bulk silicate Earth.

Calcium isotopes support rapid condensation of CAIs in the early solar nebula

1,2Christopher A. Parendo, 1Stein B. Jacobsen, 1Michail I. Petaev
Earth and Planetary Science Letters 678, 119825 Link to Articles [https://doi.org/10.1016/j.epsl.2026.119825]
1Department of Earth and Planetary Sciences, Harvard University, 20 Oxford Street, Cambridge, MA 02138, United Kingdom
2Department of Earth & Planetary Sciences, Northwestern University, 2145 Sheridan Rd, Evanston, IL 60208, USA
Copyright Elsevier

Calcium-aluminum-rich inclusions (CAIs), the oldest dated solids in the Solar System, preserve elemental and isotopic records of the thermal evolution of the early solar nebula—but some aspects, such as the processes driving large Ca-isotope variations, remain ambiguous. Previous studies observed isotopically light Ca in some CAIs, but whether these signatures arose from evaporation or condensation remains unresolved. We report new Ca-isotope and elemental data for 19 CAIs and 2 AOAs from the Allende meteorite and apply kinetic modeling to evaluate whether evaporation or condensation can account for the observed signatures. Our data confirm that CAIs exhibiting volatility-related REE fractionation have lighter Ca-isotope compositions than those with unfractionated REEs. Modeling demonstrates that evaporation cannot produce materials with both isotopically light Ca and near-chondritic Al/Ca ratios, requiring condensation as the cause of the observed Ca-isotope variations. Notably, modeled rates indicate that condensation occurred rapidly, over ∼10-1000 days, much faster than secular cooling of the solar nebula. These results constrain CAI thermal histories and offer insight into high-temperature processes in the early Solar System.

The CAI Database: 26Al–26Mg Isotope Systematics

1,2,3Emilie T. Dunham,1Ming-Chang Liu,3,4Aman Burman,3Fatima Jorge-Chavez,3Danielle Leuer,5Ashley K. Herbst,6François L. H. Tissot,3Kevin D. McKeegan
The Astrophysical Journal Supplement Series, 282, 11 Open Access Link to Article [DOI 10.3847/1538-4365/ae1835]
1Lawrence Livermore National Laboratory, Livermore, CA 94550, USA​; dunham12@llnl.gov
2Earth, Planetary, and Space Sciences Department, University of California Los Angeles, Los Angeles, CA 90025, USA​
3Earth and Planetary Sciences Department, University of California Santa Cruz, Santa Cruz, CA 95064, USA​
4The California Institute of Technology, Pasadena, CA 91125, USA​
5School of Earth and Space Exploration, Arizona State University, Tempe, AZ 85281, USA
6The Isotoparium, Division of Geological and Planetary Sciences, The California Institute of Technology, Pasadena, CA 91125, USA

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New evidence on the formation conditions of the Libyan Desert Glass (Western Egypt): Clues from a dendritic zircon inclusion

1,2Niccolò Magnani,2,3Enrico Mugnaioli,2Sofia Lorenzon,4Lidia Pittarello,5Tatiana E. Gorelik,2,3Matteo Masotta,2,3Luigi Folco
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70094]
1Dipartimento di Scienze dell’Ambiente e della Terra, Universita di Milano-Bicocca, Milan, Italy
2Dipartimento di Scienze della Terra, Universita di Pisa, Pisa, Italy
3Centre for Instrument Sharing of the University of Pisa, Pisa, Italy
4Mineralogisch-Petrographische Abteilung, Naturhistorisches Museum, Vienna, Austria
5Ernst Ruska-Centre for Microscopy and Spectroscopy with Electrons, Forschungszentrum Juelich, Juelich, Germany
Published by arrangemetn with John Wiley & Sons

Libyan Desert Glass (LDG) is an ~29 million years old, silica-rich glass found inWestern Egypt. Whether this glass formed in an impact cratering context associated withthe hypervelocity collision of a cometary/asteroidal body or radiative heating during anairburst is debated. Determination of the formation temperatures and pressures of raremineral components in LDG can provide key petrogenetic constraints on its origin. Here,we report the occurrence of a zircon inclusion, whose textural, chemical, andcrystallographic features point to a rapid formation during solidification of the silica-richLDG melt. The study was conducted combining dual beam microscopy, transmissionelectron microscopy, energy-dispersive X-ray spectroscopy, and three-dimensional electrondiffraction. The inclusion is a few tens of micrometer in size and consists of dendriticbranches of zircon arranged in a reticulate-cruciform texture. The high-silica glass fillinginterstices between dendrites have longer chemical bonds compared to matrix glass, asindicated by electron pair distribution function analysis, and is enriched in Al 2 O 3 . The lackof incongruent melt products (ZrO 2 , SiO 2 ) suggests that the inclusion formed during coolingfrom supraliquidus conditions, by dynamic crystallization from an (immiscible) undercooledliquid droplet. Such droplet would derive from shock-induced melting of a precursor zircongrain, possibly mixed with the SiO 2 -rich liquid formed by melting of the LDG precursormaterial. The formation model proposed for this inclusion does not allow us to discriminatebetween the two genetic processes proposed for LDG, but sets a new minimum to theliquidus temperature of the corresponding chemical system of ~2250°C.