¹Xiaoying Liu, ¹Chi Zhang, ¹Zongyu Yue, ¹Lixin Gu, ¹Jing Li, ¹Heng-Ci Tian, ¹Sen Hu, ¹Yangting Lin
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2026.116969]
¹Key Laboratory of Planetary Science and Frontier Technology, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
Copyright Elsevier

Meteorite impact is a key process on the Moon, having profoundly reshaped the lunar surface, modified the physical properties of lunar regolith, and transported water and other volatiles on the surface. However, the temperature-pressure conditions of impact-induced plumes and their duration were poorly constrained. Here, we report the first discovery of immiscibility a FeNi-P-S bead from Chang’e-5 lunar soils, which consists of abundant spherules of metallic FeNi and sulfide both evenly dispersed in phosphide-rich matrix. The observed texture and compositions are consistent with quenching of an FeNi-P-S melt droplet, generated during an iron meteorite impact. The initial droplet was homogeneous and formed at >1800 °C and > 11–16 GPa within the impact plume, based on high-pressure experiments of the Fe-P-S system. As the plume expanding, FeNi spherules emerged from the droplet at 11–16 GPa, estimated by P partitioning between the metal and P-S-rich melt. Subsequent separation of the P-S-rich melt into immiscible sulfide-rich spherules and phosphide-rich mesostasis occurred at 1 bar–3 GPa and 1000–1100 °C. The duration of the pressure declining from >11–16 GPa to 1 bar–3 GPa was estimated to be 0.5–1 s, combining the impact plume expansion model with the cooling rate inferred from the metallic bead. This study demonstrates that high-pressure conditions of impact plumes can be retained for second timescales, which is critical for chemical reactions and water and other volatile migration on the Moon’s surface.