NWA 16813 (CK6) Records Almost Highest Oxygen Fugacity in Meteorites

1,2Lei Jin,3Tsz Wai Lo,3Ian Tong Fong
Research in Astronom and Astrophysics 25, 075008 Link to Article [DOI 10.1088/1674-4527/add8fa]
1State Key Laboratory of Lunar and Planetary Sciences, Macau University of Science and Technology, Macau 999078, China
2CNSA Macau Center for Space Exploration and Science, Macau 999078, China
3Premier School Affiliated to Hou Kong Middle School, Macau 999078, China

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Identifying LL Chondrite Near-Earth Asteroids Using LL Chondrite Reflectance Spectra

1Pengyue Wang (王鹏越),2Edward Cloutis,1Ye Su (苏烨),1Man-To Hui (许文韬)
The Astrophysical Journal Letters 985, L18 Open Access Link to Article [DOI 10.3847/2041-8213/adce6e]
1State Key Laboratory of Lunar and Planetary Sciences, Macau University of Science and Technology, Macau, People’s Republic of China
2Department of Geography, University of Winnipeg, Winnipeg, Canada

Most near-Earth objects are thought to originate from the collisional fragments of the main asteroid belt. One question that remains to be resolved is the proportion of near-Earth objects sampling the core area material of the parent body to the outer layers. In this study, we developed a method to determine the petrologic type of ordinary chondrite parent bodies based on reflectance spectroscopy. We also calculated the petrologic type of asteroid (25143) Itokawa, which is consistent with the returned samples from the JAXA Hayabusa mission. Finally, we calculate the petrologic type of 28 LL near-Earth asteroids. Our results show that the surface material of most LL chondrite near-Earth asteroids is of petrologic grade higher than 4. The ratio of LL chondrite near-Earth asteroids with high petrologic type (5 and 6) to LL chondrite near-Earth asteroids with low petrologic type is 0.79. This also means that LL chondrite near-Earth asteroids may originate primarily from the core area of the main belt parent body or bodies.

A machine-learning compositional study of exoplanetary material accreted onto five helium-atmosphere white dwarfs with cecilia 

1,2,3Mariona Badenas-Agusti,4Siyi Xu (许偲艺),2Andrew Vanderburg,2Kishalay De,5Patrick Dufour,1,4Laura K Rogers,2,6Susana Hoyos,7Simon Blouin,2Javier Viaña,1Amy Bonsor,6Ben Zuckerman
Monthly Notices of the Royal Astronomical Society 540, 746-773 Open Access Link to Article [https://doi.org/10.1093/mnras/staf777]
1Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge, CB3 0HA, UK
2Department of Earth, Atmospheric and Planetary Sciences, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
3Department of Physics and Kavli Institute for Astrophysics and Space Research, Massachusetts Institute of Technology, Cambridge, MA 02139, USA
4Gemini Observatory/NSF’s NOIRLab, 950 North Cherry Avenue, Tucson, AZ 85719, USA
5Département de Physique, Université de Montréal, Montréal, Québec H3C 3J7, Canada
6Department of Earth, Planetary, and Space Sciences, University of California, Los Angeles, CA 90095-1567, USA
7Department of Physics and Astronomy, University of Victoria, Victoria, BC V8W 2Y2, Canad

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What falls versus what we recover: Quantifying search and recovery bias for orbital meteorites

1,2Patrick M. Shober,2Jeremie Vaubaillon,3,4Hadrien A. R. Devillepoix,3,4Eleanor K. Sansom,3,4Sophie E. Deam,2,5Simon Anghel,2Francois Colas,6Pierre Vernazza,7Brigitte Zanda
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.70041]
1Astromaterials Research and Exploration Science Directorate (ARES), NASA Johnson Space Center, Houston, Texas, USA
2LTE, Observatoire de Paris, Université PSL, Sorbonne Université, Université de Lille, LNE, CNRS, Paris, France
3Space Science and Technology Centre, School of Earth and Planetary Sciences, Curtin University, Perth, WA, Australia
4International Centre for Radio Astronomy Research, Curtin University, Perth, WA, Australia
5Astronomical Institute of the Romanian Academy, Bucharest, Romania
6Institut de Minéralogie, Physique des Matériaux et Cosmochimie, Muséum National d’Histoire Naturelle, CNRS, Paris, France
7Laboratoire d’Astrophysique de Marseille, Aix Marseille Université, Aix-Marseille University, CNRS, CNES, LAM, Institut Origines, Marseille, France
Published by arrangement with John Wiley & Sons

Instrumentally determined pre-atmospheric orbits of meteorites offer crucial constraints on the provenance of extraterrestrial material and the dynamical pathways that deliver it to Earth. However, recovery efforts are focused on larger and slower impacts due to their higher survival probabilities and ease of detection. In this study, we investigate the prevalence of these biases in the population of recovered meteorites with known orbits. We compiled a data set of 75 meteorites with triangulated trajectories and compared their orbits to 538 potential 1 g meteorite-dropping fireballs detected by the Global Fireball Observatory, the European Fireball Network, and the Fireball Recovery and InterPlanetary Observation Network. Our results reveal that objects with small semi-major axis values (a1.8 au) appear 2–3 more often than expected. The current sample of meteorites with known orbits does not reflect the sources of meteorites in our collections, and it is essential to account for search and recovery biases to obtain a more representative understanding of meteorite source contributions.

Mineral quantitative inversion based on in-situ spectral observations from Yutu-2: Anomalous sample origin and mineral composition variations on the Rover’s path

Kecheng Dua,b et al. (>5)

Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2025.116821]
aCollege of Surveying and Geo-Informatics, Tongji University, Shanghai, China
bShanghai Key Laboratory for Planetary Mapping and Remote Sensing for Deep Space Exploration, Tongji University, Shanghai, China
Copyright Elsevier

In January 2019, China’s Chang’e-4 (CE-4) spacecraft successfully landed in Von Kármán crater on the farside of the Moon. During nearly six years of operation until November 2024, the Visible and Near-infrared Image Spectrometer (VNIS) onboard the Yutu-2 rover acquired in-situ spectral data along an approximately 1600 m traverse path, offering critical opportunities to investigate subtle mineralogical variations within the patrol region. In this study, we analyzed these spectral data using a sparse spectral decomposition method with TiO2 constraints to quantitatively estimate the abundances of six lunar minerals, including high‑calcium pyroxene, low-calcium pyroxene, olivine, plagioclase, ilmenite and agglutinate/glass. We further examined the mineralogical properties of regolith and rocks in Yutu-2’s patrol area to identify trends and correlations in compositional variations. By comparing results with Kaguya Multiband Imager data products, we identified a gradual decreasing spatial distribution in plagioclase abundance along the traverse path, likely attributable to ejecta from the Zhinyu crater. Furthermore, analysis of Moon Mineral Mapper (M3) data revealed samples with similar spectral characteristics near Zhinyu crater, supporting this hypothesis. Additionally, the impact of secondary impact craters on local regions was qualitatively and quantitatively assessed using VNIS spectral features and agglutinate/glass abundance. These findings enhance understanding of the complex origin and evolution of materials at the CE-4 landing site region.

Asteroid Itokawa … but when and how did it form exactly?

Fred Jourdana,b,c, Nicholas E. Timmsc, Tomoki Nakamurad, William D.A. Rickardb, Celia Mayersb

Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2025.09.020]
aWestern Australian Argon Isotope Facility, Curtin University, Australia
bJohn de Laeter Centre, Curtin University, Australia
cSpace Science and Technology Centre & School of Earth and Planetary Sciences, Curtin University, Australia
dLaboratory for Early Solar System Evolution, Department of Earth Science Graduate School of Science, Tohoku University Aoba, Sendai, Miyagi Japan
Copyright Elsevier

Asteroid Itokawa is made of reassembled fragments from a monolithic parent asteroid which got shattered during a collision with a large object. Data are scarce regarding the metamorphic processes that occurred on the monolithic parent body and the age and nature of the catastrophic disruption event. Here, we investigate the timing of the metamorphism inside the parent body of Asteroid Itokawa and the age and nature of the catastrophic breakup event recorded in particles returned from Itokawa. We studied three regolith dust particles recovered by the Hayabusa space craft from the rubble pile asteroid 25,143 Itokawa using electron backscatter diffraction, time-of-flight secondary ion mass spectrometry, and 40Ar/39Ar dating techniques. Our results show that none of the particles show noticeable sign of shock metamorphism. Two of the particles yielded 40Ar/39Ar age of 4559 ± 61 and 4130 ± 33 million years (Ma), while a third particle returned a maximum error age of 703 ± 53 Ma. When combined with existing data, and diffusion models, these results show that ∼4.5 billion years (Ga) ago, Itokawa’s parent monolithic body cooled down from a peak metamorphism temperature ∼800 °C to ∼300 °C in less than 64 million years at a depth of >20 km. Then at ∼4.22 Ga, Itokawa’s parent body was shattered in a collisional process involving a heterogeneous temperature distribution during the impact, with some regions escaping shock metamorphism and experiencing less than a few hundred degrees Celsius. The fragments re-agglomerated in a larger rubble pile body where they subsequently cooled down over tens of millions of years. For the next 4 billion years, Asteroid Itokawa was regularly impacted and progressively shrunk by mass wasting.

Using carbon isotopes to trace the origin of volatiles on Earth and Mars

Damanveer S. Grewala, Sujoy Mukhopadhayb

Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2025.09.014]
aDepartment of Earth and Planetary Sciences, Yale University, New Haven, CT 06511, USA
bSchool of Earth and Space Exploration, Arizona State University, Tempe, AZ 85281, USA
Copyright Elsevier

The distinct accretionary histories of Earth and Mars – with Earth experiencing protracted growth and small contributions from outer solar system (carbonaceous, CC) materials, and Mars undergoing rapid growth with building materials drawn almost exclusively from the inner solar system (non-carbonaceous, NC) – highlight key differences in planetary formation. These contrasts underscore the importance of a comparative planetology framework for understanding the origin of volatiles in terrestrial planets. In this study, we examined the relationship between the carbon (C) isotopic compositions of planetary and planetesimal reservoirs to trace the origin of volatiles on Earth and Mars. The mean δ13C value of magmatic C in Martian meteorites (−20 ‰) is significantly lower than that of the bulk silicate Earth (BSE), with a canonical value of −5 ‰. While basaltic achondrites, magmatic iron meteorites, and ordinary chondrites from the NC reservoir display δ13C values similar to Martian meteorites, the BSE δ13C value is comparable to volatile-rich CC chondrites such as CI, CM, and CR, as well as with enstatite chondrites and ureilites from the NC reservoir. If Martian magmas underwent minimal C isotopic fractionation during degassing or degassed under kinetic conditions, then the δ13C value of the Martian mantle likely reflects accretion from thermally processed undifferentiated (ordinary chondrite-like) and differentiated NC materials. In contrast, if extensive degassing occurred via Rayleigh fractionation under equilibrium conditions, the δ13C value of the Martian mantle would have a higher δ13C value (−12 to −10 ‰) than that recorded in Martian meteorites – though still lighter than that of the canonical BSE δ13C. This implies a contribution from relatively 13C-rich NC materials, potentially similar to enstatite chondrites. For BSE, although the canonical δ13C value of –5 ‰ overlaps with those of enstatite chondrites and ureilites, the late-stage delivery of volatile-rich CC materials during the main phase of Earth’s growth, which was critical for establishing its water and nitrogen inventories, likely biased its C isotopic composition towards a CC-like signature. However, a lower mean δ13C value of −8.4 ‰ of the MORB mantle, as proposed by recent studies, could mean that Earth’s mantle still preserves the signature of 13C-poor, thermally processed NC materials accreted during the early stages of the planet’s growth. The observed heterogeneity in mantle C isotopic compositions, similar to that seen in H and N isotopes, could therefore reflect a mixed contribution from both NC and CC materials. These findings suggest that the δ13C value of the BSE could be lower than the canonical estimate and may align more closely with the proposed value for the MORB mantle. Taken together, these findings suggest that the contrasting accretionary histories of Earth and Mars led to fundamentally different pathways for volatile acquisition. These divergent pathways likely shaped the long-term geochemical evolution of each planet and influenced their potential for habitability.

Excess 40Ar in Chang’e-5 lunar soils suggests a possible origin from Earth wind

Li Zhaoa,b,e, Liwu Lia,c, Chunhui Caoa,c, Qingyan Tangd, Xianbin Wanga

Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116803]
aInstitut für Planetologie, Universität Münster, Wilhelm-Klemm-Str. 10, 48149 Münster, Germany
bDepartment of Earth, Environmental and Planetary Sciences, Brown University, Providence, RI 02912, USA
aApollo 15 Commander, USA
Copyright Elsevier

The abundance of 40Ar in lunar soils is significantly higher than the expected values from solar wind implantation and 40K decay, a phenomenon known as 40Ar excess. Traditionally, this excess is attributed to 40Ar generated by the decay of 40K within the Moon. This radiogenic 40Ar degasses to the lunar surface, where it is ionized by solar radiation and subsequently captured by lunar soils. However, stepwise heating (200 °C–1300 °C) and degassing analyses of noble gas isotopes in Chang’e-5 lunar soils samples reveal the presence of two types of 40Ar: one unrelated to 36Ar, likely originating from in situ 40K decay in the soils, and another correlated with 36Ar, which may primarily derive from Earth wind. Earth wind, an ion flux formed by the escape of Earth’s atmosphere, is thought to be injected onto the lunar surface under the regulation of Earth’s magnetosphere. The study proposes that the excess 40Ar in lunar soils may primarily stem from the continuous escape of Earth’s atmosphere and be injected onto the lunar surface through both the inner and outer regions of Earth’s magnetosphere, offering a new perspective for understanding volatile exchange between the Earth-Moon system.

Sound velocities of Anorthite at high pressures and temperatures: Implications for estimating porosity in upper lunar crust

Peng Chena et al. (>5)

Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116808]
aHigh Pressure Science Experiment Center, College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Copyright Elsevier

The porosity of the lunar crust serves as the key to deciphering crucial geological processes such as the Moon’s impact history, volcanic activity, space weathering, and the formation and evolution of its internal structure. In this study, we conducted ultrasonic interferometry experiments on polycrystalline anorthite samples under high pressures and temperatures (up to 5.7 GPa and 873 K) using synchrotron radiation technology. We obtained the relationships between the compressional wave velocity (VP) and shear wave velocity (VS) of anorthite with varying pressure and temperature. The elastic properties of anorthite were fitted as follows: . By integrating these results with the lunar velocity model derived from the Apollo missions, we constructed a porosity model for the upper lunar crust, using anorthite as a representative mineral. The results indicate that the thickness of the lunar regolith (weathered surface layer) is approximately 30 km. Within the top 1 km of the lunar surface, porosity ranges from 30 % to 90 %. At the depth of 1–30 km, porosity ranges from 0 % to 50 %. At the depth of 30–50 km, porosity is less than 10 %. This study provides constraints on the porosity of the lunar surface and offers scientific guidance for the safety and design of future lunar exploration missions.

Magnesium, iron, and calcium isotope signatures of Chicxulub impact spherules: Isotopic fingerprint of the projectile and plume thermodynamics

Courtney Jean Rundhauga, Martin Schillera, Martin Bizzarroa, Zhengbin Denga,b, Hermann Dario Bermúdezc,d,e
Earth and Planetary Science Letters 669, 119592 Open Access Link to Article [https://doi.org/10.1016/j.epsl.2025.119599]
aCentre for Star and Planet Formation, Globe Institute, University of Copenhagen, Øster Voldgade 5–7, 1350 Copenhagen K, Denmark
bDeep Space Exploration Laboratory/CAS Key Laboratory of Crust-Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei, China
cDepartment of Earth and Environmental Studies, Montclair State University, Montclair, NJ 07043, USA
dGrupo de Investigación Paleoexplorer, 1400-37 Trexlertown Rd, PA 18062, USA
eDepartamento de Geociencias, Universidad Nacional de Colombia, Bogotá 11001, Colombia

The Cretaceous-Paleogene boundary (KPB) represents a massive extinction event in Earth’s history, probably triggered by the Chicxulub asteroid impact ∼66 Ma. The event dispersed vast volumes of ejecta materials including exceptionally preserved impact spherules in the Gorgonilla Island KPB section. Previous work identified three populations of spherules at Gorgonilla: 1) ballistically transported molten spherules, 2) a mixture of molten and condensed spherules dispersed by the expansion of a high-temperature, turbulent cloud (the “pyrocloud”), and 3) tiny droplets condensed from the plume (the “fireball layer”). We determine the Mg, Fe, and Ca isotopic compositions of pristine spherules to better understand the evaporation and condensation thermodynamics within the pyrocloud. We detect enrichment in mass bias corrected µ48Ca and µ26Mg* isotope signatures from the terrestrial value corresponding to an impactor contribution of ∼17–25%, most likely from a CM or CO chondrite-like asteroid. The mass-dependent δ25Mg and δ56Fe compositions are generally light or unfractionated, suggesting incomplete recondensation as the pyrocloud cooled and expanded. Combined δ25Mg and δ56Fe signatures reveal decoupling of these isotope systems, likely due to differing condensation rates. Thus, we calculate a higher average condensation rate of Fe than Mg, reflecting the thermodynamic decoupling and more complete recondensation signatures of Fe in the pyrocloud vapor. While we uncover information about the evaporation and condensation thermodynamics in the pyrocloud, the exact formation mechanisms of the complete suite of spherules remain complex with some spherules potentially forming from multiple mechanisms, including recondensation and splash–melting.