Insights into the mineralogy of the Rantila aubrite: A luminescence and VNIR reflectance spectroscopy study

1,4Anna-Irene Landi, 2Michael Gaft, 3Cristian Carli, 3Fabrizio Capaccioni, 4Giovanni Pratesi
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2025.116725]
1Dipartimento di Fisica, Università degli Studi di Trento, Via Sommarive, 14, 38123 Trento, Italy.
2Ariel University, Kiryat Hamada, Ariel 40700, Israel.
3INAF-IAPS, Area della Ricerca Tor Vergata, Via del Fosso del Cavaliere, 100, 00133 Roma, Italy
4Dipartimento di Scienze della Terra, Università degli Studi di Firenze, Via G. La Pira, 4, 50121 Firenze, Italy
Copyright Elsevier

Rantila aubrite fell in Rantila, Gujarat, India, in August 2022. This study aims to investigate the mineralogy and mineral-chemistry of three fragments of this meteorite and correlate them reflectance spectroscopy in the visible and near-infrared spectral range (VNIR) and Laser-Induced Time-Resolved Luminescence (LITRL). Aubrites’ very low Fe2+ content prevents luminescence quenching under UV light exposure, allowing these meteorites to exhibit well-defined luminescence. The investigated samples have different appearances. One consists of a light-coloured portion primarily composed of FeO-free enstatite, along with forsterite, diopside, plagioclase, minor sulphides (troilite, alabandite, daubréelite, and (Fe,Ca,Mn,Mg)S), and kamacite. The second sample is composed mainly of the same light-coloured portion and hosts a dark forsterite clast. The third sample is mainly made of dark glass. Minor terrestrial weathering is observed, with the detection of sporadic iron oxides/hydroxides. The chemical composition of the detected phases indicates highly reducing conditions during the formation, as expected for an aubrite. The mineral chemistry is similar between the different fragments in terms of major elements concentrations, some differences are observed for minor elements. Luminescence spectra indicate Cr3+ and Mn2+ as activators in diopside and forsterite, respectively, for two of the three samples. Ce3+ is the activator in the third sample, which lacks forsterite and has lower Cr2O3 contents in diopside compared to the other two samples. Therefore, the differences in mineral chemistry observed through electron microprobe analysis (EPMA) are further emphasized by luminescence data. Investigating the luminescence behaviour could provide a valuable contribution to the mineralogical-petrological study of these materials. VNIR reflectance spectra are consistent with low Fesingle bondCa pyroxene and forsterite. The main absorption typical of mafic minerals (~0.9 μm) is deeper than what has previously been observed in aubrites: this can be related to the slightly higher FeO concentrations, which, despite being very low (<0.4 wt%), still contribute to the absorption. Absorption features at ~1.4 μm and ~ 1.9 μm are consistent with low terrestrial weathering presence. Increasing the knowledge of the correlation between spectral properties and mineralogy/mineral chemistry on highly reduced meteorites will be useful for future investigation of Mercury with the ESA’s BepiColombo mission, specifically for the interpretation of the data expected from the Spectrometer and Imagers for MPO BepiColombo Integrated Observatory SYStem (SIMBIO-SYS)/Visible and near Infrared Hyperspectral Imager (VIHI) and Mercury Radiometer and Thermal Infrared Spectrometer (MERTIS) instruments.

Experimental study on thermal and mechanical properties of sintered glass materials: Implication for physical properties of primordial porous materials in the solar system

1Tetsushi Sakurai, 2Takuya Ishizaki, 1Akiko M. Nakamura
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116729]
1Department of Planetology, Kobe University, 1-1 Rokkodai-cho, Nada-ku, Kobe-city, Hyogo 657-8501, Japan
2Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara-city, Kanagawa 252-5210, Japan
Copyright Elsevier

Planetesimals underwent consolidation processes in the early solar system, which altered their thermal and mechanical properties. Sintering—a process that forms solid necks between particles—is considered one such process in planetesimals, influencing their filling factor, or porosity, as well as their thermal and mechanical properties.
In this study, to better constrain and understand the thermal and mechanical properties of planetesimals that evolved from initially powdery or granular bodies, as well as those of boulders on small bodies, which are considered remnant planetesimals, we prepared porous sintered samples consisting of glass particles with filling factors ranging from 0.35 to 0.75, corresponding to porosities of 65 % to 25 %. We then measured their thermal diffusivity, elastic wave velocity, and flexural strength, and derived empirical relationships for the normalized values—scaled by those at a filling factor of 1—as functions of filling factor or porosity. The normalized thermal diffusivities and elastic wave velocities of the sintered glass materials in this study showed similar dependencies on the filling factor. Moreover, the upper limits of the normalized elastic wave velocities were consistent with those of snow at corresponding filling factors, suggesting that these upper limits may be independent of the matrix material.
The derived empirical relationships apply to materials with porosities higher than those of meteorites. We estimated the porosity of a low-thermal-inertia boulder on the surface of asteroid Ryugu based on its thermal inertia, assuming no influence from internal cracks. The result suggests that the boulder’s porosity may be higher than values previously reported, and should be regarded as one of the possible porosity estimates.

A feasibility assessment of micromill sampling for Rb-Sr and Sm-Nd geochronology of shergottites

1,2,3A. I. Sheen,1C. D. K. Herd,2,3K. T. Tait
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70002]
1Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada
2Department of Natural History, Royal Ontario Museum, Toronto, Ontario, Canada
3Department of Earth Sciences, University of Toronto, Toronto, Ontario, Canada
Published by arrangement with John Wiley & Sons

Accurate dating of Martian meteorites is crucial for understanding key events in the planet’s evolution. However, not all Martian meteorites are amenable to dating techniques currently in use for these rocks. The priority of sample preservation precludes mineral separation methods for low-volume specimens, whereas the less destructive in situ SIMS U-Pb method depends on the availability of U-bearing accessory minerals. Micromilling allows for spatially guided sampling of target phases down to the sub-mm scale, therefore enabling chromatography-based analysis while preserving the overall specimen. This study presents an evaluation of micromill sampling for extracting individual mineral fractions in situ from shergottites, the most common group of Martian meteorites, for Rb-Sr and Sm-Nd geochronology. Based on trace element content in major minerals in shergottites (pyroxene, plagioclase, olivine, and merrillite) and assuming that a minimum load size of 0.25 ng Sr and 1 ng Nd is required to achieve baseline isotopic precision (2σ of ~240 ppm on 87Sr/86Sr and ~100 ppm on 143Nd/144Nd), the minimum required sample volume ranges in the orders of 105–107 μm3 for one Sr isotopic analysis and 105–109 μm3 for one Nd isotopic analysis. Considering the need for sample purity, significant limitations exist in the maximum sampling resolution of the micromill instrument (~40 μm for the conical carbide drill bit chosen for this study) with respect to shergottite petrography. Insufficient grain size, irregular morphology, and the presence of small inclusions may reduce the area that can be drilled per grain. Shock-induced fractures, which sometimes act as pathways for terrestrial alteration, are pervasive in shergottites and create additional challenges for effective high-purity sampling of the target phase. In addition, variation in trace element content in the target phases may result in the realistically required drilling volumes being orders of magnitude greater than the minimum estimates. Lastly, estimated drilling time per fraction may reach over 5 h for pyroxene (Sr, Nd), plagioclase (Nd), and olivine (Sr, Nd), increasing the susceptibility to a larger procedural blank as well as requiring constant, labor-intensive monitoring for long durations. Based on these technical and physical constraints, we do not consider micromill sampling to be currently compatible with Sr isotopic analysis of olivine and Nd isotopic analysis of pyroxene, plagioclase, and olivine in shergottites. The feasibility of geochronology applications may be improved with future advances in analytical development, such as increasing the micromill sampling resolution and reducing the load size required for isotopic analysis.

Documenting microbial populations within the University of Alberta Meteorite Curation Facility using 16S rRNA gene sequencing: Implications for the curation of astromaterials

1Libby D. Tunney,2Aaron B. Regberg,1Christopher D. K. Herd,3Richard E. Davis,4Christian L. Castro
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.70008]
1Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada
2Astromaterials Research and Exploration Science Division, NASA Johnson Space Center, Houston, Texas, USA
3Texas State University, NASA Johnson Space Center, Houston, Texas, USA
4JES Tech, NASA Johnson Space Center, Houston, Texas, USA
Published by arrangement with John Wiley & Sons

Meteorites are easily contaminated at the Earth’s surface by microbial activity. Here, DNA extracts from two meteorite specimens and samples from curation laboratory surfaces are analyzed with amplicon sequencing, to understand microbial communities that contaminate meteorites and that may be resident in curation facilities. In addition, two different DNA extraction kits, the PowerSoil DNA Isolation Kit and the QIAamp UCP Pathogen Mini Kit, are utilized to determine if certain kits are more favorable for low biomass studies of meteorites. We find that, regardless of the type of kit used, the majority of microbial taxa that dominate meteorite and meteorite curation environments include those that are prevalent in soils or in the human microbiome. Our results have implications for advanced curation methods to protect the intrinsic properties of meteorites, such as extraterrestrial organics and minerals, from microbes. Preserving meteorites in pristine states and understanding the complex relationship between meteorites and terrestrial microbes can inform our search for the origin of life or life elsewhere in the universe.

Thermal Infrared Spectra of the Moon: Results From the Lucy Thermal Emission Spectrometer Observations

1Philip R. Christensen,2Victoria E. Hamilton,1Saadat Anwar,1Greg Mehall,2John R. Spencer,3Jessica M. Sunshine,2Harold F. Levison
Journal of Geophysical Research (Planets) Open Access Link to Article [https://doi.org/10.1029/2024JE008493]
1School of Earth and Space Exploration, Arizona State University, Tempe, AZ, USA
2Southwest Research Institute, Boulder, CO, USA
3University of Maryland, College Park, MD, USA
Published by arrangement with John Wiley & Sons

The Lucy Thermal Emission Spectrometer (L’TES) instrument acquired hyperspectral thermal infrared (TIR) observations of the Earth’s Moon during Lucy’s 2022 Earth gravity assist. L’TES covers the spectral range of 100–1,750 cm−1 (100–5.8 μm) at a spectral sampling of 8.64 cm−1 (Christensen et al., 2023, https://doi.org/10.1007/s11214-023-01029-y). The field of view (FOV) is 7.3-mrad, giving a spatial resolution on the Moon of 1,650 km. Seventeen high-quality spectra of the warm disk were acquired of Oceanus Procellarum that provide the first well-calibrated TIR observations of the Moon with high spectral resolution. The lunar surface emissivity was determined by modeling the surface radiance using two different methods that gave nearly identical results. The L’TES spectra have Christiansen feature (CF) maxima at 1,226 cm−1 (8.15 μm), a spectral band depth of ∼0.04, and a downward slope at wavenumbers >1,200 cm−1 that is characteristic of <100 μm particles. Comparison with Diviner 3-point spectral data (Greenhagen et al., 2010, https://doi.org/10.1126/science.1192196) shows excellent agreement in the CF location and band shape. The L’TES spectra closely match several lunar soil laboratory spectra (Donaldson-Hanna et al., 2017, https://doi.org/10.1016/j.icarus.2016.05.034), providing excellent ground truth for the L’TES observations, validating the L’TES data processing, and demonstrating that high-spatial and spectral resolution TIR data would provide a powerful tool for remote compositional mapping. The L’TES nightside observations accurately derived surface temperatures at 110 K, even when the Moon only filled 10% of the FOV, confirming that L’TES will accurately determine the cold Trojan asteroid temperatures.

Carbonate formation and fluctuating habitability on Mars

1Edwin S. Kite,2Benjamin M. Tutolo,1Madison L. Turner,3Heather B. Franz,3David G. Burtt,4Thomas F. Bristow,5Woodward W. Fischer,6Ralph E. Milliken,7Abigail A. Fraeman,1Daniel Y. Zhou
Nature 643, 60-66. Open Access Link to Article [DOI https://doi.org/10.1038/s41586-025-09161-1]
1University of Chicago, Chicago, IL, USA
2University of Calgary, Calgary, Alberta, Canada
3NASA Goddard Space Flight Center, Greenbelt, MD, USA
4NASA Ames Research Center, Moffett Field, CA, USA
5California Institute of Technology, Pasadena, CA, USA
6Brown University, Providence, RI, USA
7Jet Propulsion Laboratory, California Institute of Technology, Pasadena, CA, USA

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Mineralogical and chronological records of strong shock metamorphism in pigeonite cumulate eucrite Northwest Africa 8326

1Lang Zhang, 1Ai-Cheng Zhang, 1Xiao-Wen Liu, 2Yan-Jun Guo, 1Jia-Ni Chen, 3Yuan-Yun Wen, 4Qiu-Li Li, 4Yu Liu, 4Xiao-Xiao Ling, 5Jin S. Zhang
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2025.06.032]
1State Key Laboratory for Mineral Deposits Research, School of Earth Sciences and Engineering, Nanjing University, Nanjing 210023, China
2CAS Key Laboratory of Standardization and Measurement for Nanotechnology, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing, China
3Institute of Geochemistry, Chinese Academy of Sciences, Guiyang 550081, China
4State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
5Department of Geology and Geophysics, Texas A&M University, College Station, TX 77843, USA
Copyright Elsevier

Mineralogical records of strong shock metamorphism (around or above 20 GPa) are common in L-group chondrites, Martian meteorites, and lunar meteorites, but rarely reported in Howardite-Eucrite-Diogenite (HED) meteorites. Here, we report detailed mineralogical observations of shock-induced features and ion-microprobe merrillite U-Pb ages from the pigeonite cumulate eucrite Northwest Africa (NWA) 8326. Shock-induced mineralogical features in NWA 8326 contain: (i) planar fractures in pyroxene and partial maskelynitization of plagioclase; (ii) presence of high-pressure minerals such as tissintite, stishovite, vacancy-rich augite, super-silicic garnets within melt veins, and xieite, tuite, and reidite in the host rock outside melt veins. We also observed fine-grained clinoenstatite and pigeonite at the edges of shock melt and propose they formed through metastable crystallization. Our study indicates that NWA 8326 experienced shock metamorphism of at least 20 GPa, comparable to those observed in L-group chondrites, Martian meteorites, and lunar meteorites. We propose that the relatively low shock pressures inferred for shocked eucrites in previous investigations could be due to the absence of suitable high-pressure mineralogical indicators. The ion-microprobe 207Pb/206Pb age of merrillite in NWA 8326 is 4238 ± 32 Ma (95 % confidence) and represents the timing of the shock metamorphism. The similarity of the impact ages across NWA 8326, some eucrites, lunar samples/meteorites, and chondrites suggests that there were probably widespread impact events at ∼4.2 Ga in the Solar System.

Petrographic and geochemical analysis of inversely zoned chondrules

1Fabio Joseph,2Igor Drozdovsky,1,3Malte Junge,1Joanna Brau,1,3Melanie Kaliwoda
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.14381]
1Department of Earth and Environmental Sciences, Ludwig-Maximilians-University, Munich, Germany
2Directorate of Human and Robotics Exploration, European Astronaut Centre (EAC)—European Space Agency (ESA), Troisdorf, Germany
3Mineralogical State Collection, SNSB, Bavarian State Collections of Natural History, Munich, Germany
Published by arrangement with John Wiley & Sons

Chondrules are one of the oldest objects in our solar system. Therefore, they play an important role as messengers, offering new insights into the early stage of the solar system processes and potential understanding of formation. Therefore, the investigation of all detailed structures, especially not well-known inversely zoned chondrules (IZ chondrules), is crucial. In this paper, we describe the chemical as well as the structural composition of inversely zoned chondrules with EDX, light microscopy, BSE, and Raman spectroscopy, which reveal a new process in the early solar system. Inversely zoned chondrules consist of a pyroxene core surrounded by an olivine rim. The olivines have a higher Fe content (Fa, 39%–41%) compared to those found in most other chondrules. The core displays a radial pyroxene chondrule with sometimes olivines (Fa34). These IZ chondrules have originated during the early stages of our solar system and do not show the typical known forming process of chondrules. Minor fluctuations in the SiO₂ content of chondritic melts can lead to SiO₂ depletion of the residual melt at a constant temperature due to crystallization of pyroxene, which shifts the phase equilibrium in favor of fayalite-enriched olivine, which forms a rim.

Particle size and albedo effects on emissivity spectra of lunar analog minerals and rocks in the intermediate infrared region

1,2Nandita Kumari, 1John Mustard, 3Timothy D. Glotch
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2025.116721]
1Department of Earth, Environmental and Planetary Sciences, Brown University, USA
2Planetary Science Institute, USA
3Department of Geosciences, Stony Brook University, USA
Copyright Elsevier

Visible/near-infrared (VNIR) and thermal infrared (TIR) spectroscopy have been widely used to detect and characterize the abundances of silicates across the solar system. Recently, intermediate infrared (IMIR) reflectance spectroscopy (~4 – 6 μm) has been proposed as a tool to quantify the Mg# in olivine and pyroxene with varying iron, magnesium and calcium content. The lunar surface is composed of rocks with mixed particle sizes and thus quantifying the effects of particle size is extremely important to increase the robustness of IMIR spectroscopy as a tool for lunar surface exploration. Similarly, space weathering has been known to cause optical darkening and affect the spectra of the lunar surface materials across a broad wavelength range. In this study, we have identified the emission features of lunar analog minerals/rocks and their variations with changes in particle sizes and albedo at IMIR wavelengths in simulated lunar environment (SLE). We find that the lunar analog minerals display an increase in emissivity and striking decrease in feature contrast with an increase in particle sizes or decrease in albedo. This study shows that while this wavelength range works well in reflectance space for sample characterization, using it for emissivity measurements via orbital remote sensing or in-situ rovers requires extensive study.

Multiple thermal events during 4350–3920 ma recorded in a single lunar meteorite Northwest Africa 4485

1,2Tomoko Arai, 1Takayuki Tomiyama, 2Takafumi Niihara, 3Tatsunori Yokoyama, 4Miwa Yoshitake, 2,3Hiroshi Kaiden, 2,3Keiji Misawa, 4Anthony J. Irving
Icarus (in Press) Open Access Link to Article [https://doi.org/10.1016/j.icarus.2025.116715]
1Planetary Exploration Research Center, Chiba Institute of Technology, 2-17-1 Tsudanuma, Narashino, Chiba 275-0016, Japan
2National Institute of Polar Research, 10-3 Midoricho, Tachikawa, Tokyo 190-8518, Japan
3Graduate Institute for Advanced Studies, SOKENDAI, 10-3 Midoricho, Tachikawa, Tokyo 190-8518, Japan
4Department of Earth & Space Sciences, University of Washington, Seattle, WA 98195, USA
Copyright Elsevier

A lunar meteorite Northwest Africa (NWA) 4485 is a KREEP (potassium, rare earth elements and phosphorus)-rich polymict breccia, likely paired with NWA 4472. NWA 4485 includes mm-sized lithic clasts with variable textures and modal abundances. The lithic clasts share features with KREEP basalts, and consist dominantly of moderately Mg-rich pyroxene and less calcic plagioclase than those in the Apollo 17 KREEPy basalt with zircon and phosphates. Uranium‑thorium‑lead isotopic studies on zircon and baddeleyite in the lithic clasts and matrix of NWA 4485 revealed that the 207Pbsingle bond206Pb age spectrum (4350–3920 Ma) is compatible with that for apatite in the paired NWA 4472, broadly covering the ages of zircons in Apollo polymict breccia samples from multiple landing sites. The presence of a 4160 Ma zircon in a millimeter-sized lithic clast, a core of 4210 Ma in a detrital zircon with multiple rims of ~3960 Ma, and an individual zircon grain of 4350 Ma in the matrix clearly indicates that they are products of pre-mare multiple KREEP-related magmatism, predating the lunar cataclysm (~3900–4000 Ma).