^1,2,3Xuhang Zhang et al. (>10)
Earth and Planetary Science Letters 637, 118725 Open Access Link to Article [https://doi.org/10.1016/j.epsl.2024.118725]
¹State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
²Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
³College of Earth and Planetary Sciences, University of Chinese Academy of Sciences, Beijing 100049, China
Copyright Elsevier

The extent of volatile elements on the surface and interior of the Moon remains a highly debated topic. Previous studies conducted on bulk lunar soil samples and solar wind samples collected by the Genesis mission indicate a discernible isotope mass- or non-mass-dependent fractionation of krypton and xenon. However, a detailed investigation of these processes is missing, particularly in determining the possible incorporation of cometary volatiles in the lunar regolith. New lunar soil samples returned by the Chang’e-5 mission provide a chance to answer these key questions. In this study, noble gas isotopes of nine subsamples from a Chang’e-5 scooped sample were analysed through stepwise-heating and total fusion laser extraction. The results reveal that a simple binary mixture of solar wind and cosmogenic components did not explain alone the isotopic composition of these samples. The Xe data shows insignificant amounts of atmospheric Xe and presents clear evidence of cometary contributions to the lunar regolith, with a significant depletion of 134,136Xe compared to that in the solar wind. Additionally, a meteoritic component is identified. Compared to the Apollo results, our findings further validate the theory of Earth’s atmospheric escape, substantiate the plausibility of these exogenous admixtures to elucidate the isotopic fractionation mechanisms of Kr and Xe within the lunar regolith, and provide novel insights into long-term constancy in the solar wind composition.