1,2Amanda Ostwald,1Arya Udry,3James M. D. Day,4,5,6,7Juliane Gross
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.14159]
1Department of Geoscience, University of Nevada, Las Vegas, Las Vegas, Nevada, USA
2Smithsonian National Museum of Natural History, Washington, DC, USA
3Scripps Institution of Oceanography, University of California San Diego, La Jolla, California, USA
4NASA Johnson Space Center, Houston, Texas, USA
5Department of Earth and Planetary Science, Rutgers University, Piscataway, New Jersey, USA
6Lunar and Planetary Institute, Houston, Texas, USA
7Department of Earth and Planetary Sciences, The American Museum of Natural History, New York, New York, USA
Published by arrangement with John Wiley & Sons
Nakhlite and chassignite meteorites are cumulate rocks thought to originate from the same location on Mars. Petrogenetic relationships between nakhlites and chassignites are not fully constrained, and the two cumulus phases in nakhlites—olivine and clinopyroxene—possibly formed either together from one magma or separately from different magmas. Primary magma compositions can potentially be determined from studies of melt inclusions (MIs) trapped within early-formed mineral phases. MIs frequently undergo post-entrapment effects, and when such processes occur, there can be significant changes to their compositions. Here, we report major, minor, and trace element abundances for MIs in cumulus phases in nakhlites and chassignites. The melt compositions that they record are variable (MgO = 2.50–13.5 wt%, K2O = 0.03–3.03 wt%, La/Yb = 2.46%–16.4%) and are likely affected by diffusive reequilibration with changing magma composition outside of their host phases. Evidence for diffusive reequilibration suggests that nakhlite and chassignite magmas were generated in an open system, and cumulus phases may have undergone magma storage and mixing. Such processes may be akin to those that occur in terrestrial intrusive magmatic systems by open-system magma recharge. MIs within the nakhlite and chassignite suite therefore provide insights into magmatic processes during magma storage and transit on Mars.
Day: March 18, 2024
Does the composition of meteoritic metal change with forging? An experimental study
1Mendy M. Ouzillou,2Christopher D. K. Herd
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.14160]
1SkyFall Meteorites, Bastrop, Texas, USA
2Department of Earth and Atmospheric Sciences, University of Alberta, Edmonton, Alberta, Canada
Published by arrangement with John Wiley & Sons
The use of meteoritic iron in the manufacture of human artifacts since the Bronze Age has been well documented, including the iron blade of Tutankhamun’s dagger. Whereas the preservation of textures and mineral inclusions suggest relatively low temperature (<950°C) working of meteoritic metal used in artifacts, higher temperature working—that is, forging—could have occurred, based on studies of Bronze Age slag. The extent to which the forging of meteoritic iron might change the bulk composition, especially the trace elements used for classification of iron meteorites, is largely unknown. Using electron microbeam methods (SEM and EPMA), and trace element analysis (ICP-MS), we analyze metal obtained at different stages during the modern forging of a set of knife blades from fragments of the Gebel Kamil meteorite, and assess the degree to which bulk element composition, mineral inclusions, and textures are modified. We find that while forging does destroy the original texture and removes mineral inclusions, it does not significantly modify the trace elements typically used in iron meteorite classification, at least for the relatively Ni-rich composition represented by Gebel Kamil. While we acknowledge that the modern method by which the knife blades were forged from Gebel Kamil would not have occurred in the Bronze Age, our results represent an upper temperature limit relative to the inferred conditions used in ancient forging. The identification of the meteorite (if still in existence) that was used for artifacts is feasible, based on our results and current literature on ancient meteoritic artifacts.