The Vaca Muerta mesosiderite: The path under which Fe-Ni alloy ±C phases could have formed

1M. E. Varela,2S.-L. Hwang,3P. Shen,1,4L. N. Garcia,1M. Saavedra,5T. Maruoka,6M. Bose
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.14120]
1Instituto de Ciencias Astronómicas, de la Tierra y del Espacio (ICATE), Universidad Nacional de San Juan, CONICET, San Juan, Argentina
2Department of Materials Science and Engineering, National Dong Hwa University, Hualien, Taiwan, ROC
3Department of Materials and Optoelectronic Science, National Sun Yat-sen University, Kaohsiung, Taiwan, ROC
4Instituto de Mecánica Aplicada, Universidad Nacional de San Juan, San Juan, Argentina
5Faculty of Life and Environmental Sciences, University of Tsukuba, Tsukuba, Japan
6School of Earth and Space Exploration, Arizona State University, Tempe, Arizona, USA
Published by arrangement with John Wiley & Sons

The combined SEM and TEM studies on the metal (Fe-Ni alloy ±C) portion of the Vaca Muerta mesosiderite reveal structural and compositional evidence at micro to nanoscale, which sheds light on the solidification of taenite + graphite as a cement, and later solid-state precipitation process for the kamacite formation as grain boundary allotriomorph. Besides, it is proposed that the graphite veinlets formed through a complex partial melting process followed by a solidification toward the final eutectic transient coupled with the solid-state precipitation and later decomposition ordering of taenite. The presence of defects and taenite in graphite signal formation in a liquid environment. The δ13C values of graphite in the graphite-rich areas (e.g., ranging from −0.8 ± 1.7‰ to +15.3 ± 2.5‰) suggest a short-circuit diffusion path for C isotope fractionation.

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