Isotopic evidence for two chondrule generations in CR chondrites and their relationships to other carbonaceous chondrites

1Yves Marrocchi,1Maxime Piralla,1Maxence Regnault,2Valentina Batanova,1Johan Villeneuve,3Emmanuel Jacquet
Earth and Planetary Science Letters 593, 117683 Link to Article [https://doi.org/10.1016/j.epsl.2022.117683]
1Université de Lorraine, CNRS, CRPG, UMR 7358, Vandœuvre-lès-Nancy 54500, France
2Université Grenoble Alpes, ISTerre, CNRS, UMR 5275, Grenoble 38000, France
3Institut de Minéralogie, de Physique des Matériaux et de Cosmochimie (IMPMC), Muséum national d’Histoire naturelle, Sorbonne Université, CNRS; CP52, 57 rue Cuvier, 75005 Paris, France
Copyright Elsevier

Among primitive meteorites, CR chondrites have peculiar isotopic compositions, the origin of which is uncertain and may have involved contributions from primordial molecular cloud material or the chondrites’ formation and agglomeration late during the evolution of the protoplanetary disk. Here, we report a comprehensive textural and isotopic characterization of type I CR chondrules and provide new insights on their formation conditions. We find that two chondrule populations characterized by different sizes and oxygen isotopic compositions co-exist in CR chondrites. The typically larger, 16O-poor (-4‰) chondrules (type I-CR chondrules) appear to have formed late out of a CR reservoir already populated by typically smaller, 16O-rich (-4‰) chondrules (type I-CO chondrules). Before formation of type I-CR chondrules, the CR reservoir was likely dominated by CI-like dust, in line with the proximity of CR with CI chondrites for many isotopic ratios. The CR reservoir thus may have largely belonged to the continuum shown by other carbonaceous chondrites, although some isotopic ratios maintain some originality and suggest isotopic variation of CI-like dust in the outer disk. Combined with literature data, our data (i) demonstrates that recycling processes are responsible for the singular compositions of CR chondrites and their chondrules for isotopic systems with drastically different geochemical behaviors (O, Cr, Te) and (ii) support the homogeneous distribution of 26Al throughout the protoplanetary disk.

Near-infrared spectroscopy of boulders with dust or patina coatings on the Moon: A two-layer radiative transfer model

1Lingzhi Sun,1Paul Lucey
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2022.115204]
1Hawai‘i Institute of Geophysics and Planetology, University of Hawai‘i at Mānoa, Honolulu, HI 96822, USA
Copyright Elsevier

Previous remote sensing studies focus on lunar surface regolith, which contains abundant mixtures of rock fragments and dust, making it hard to track the petrologic origin. Igneous boulders exposed on lunar surface, however, carry pristine mineralogy and chemistry since its formation, therefore are direct evidence of lunar thermal evolution events. High spatial-resolution remote sensing images and rover explorations of the Moon allow us to study the spectroscopy of igneous boulders. We modeled the optical scattering properties of rocks using the Legendre and Double Henyey–Greenstein phase functions, porosity parameter and grain size, and provided a modified radiative transfer model for rocks rather than powdered minerals. Considering that space weathering could generate a layer of dust or patina on the surface of boulders, we introduced a two-layer radiative transfer modeling algorithm to solve the spectroscopy of the substrate rock for dust- or patina-coated boulder. The modeled substrate rock spectra show less reddening, larger reflectance, and stronger absorption band depth compared to dust- or patina-coated rock, consistent with the measurements of Apollo rock samples. We applied this two-layer model on the dust-coated boulder detected by Yutu-2 rover and derived the spectrum of the substrate rock. Using Kaguya Multiband Imager data, we calculated the substrate rock spectra for an anorthosite boulder, and our result shows good consistency with laboratory measured anorthosite rock spectrum. This work is a beginning of understanding lunar boulder spectroscopy for a more precise interpretation of lunar thermal history.