Abundant presolar silicates of the CM chondrite Asuka 12169: Implications for the thermal and aqueous alteration of the CM parent body

1Yuchen Xu,2Yangting Lin,2Jialong Hao,3Makoto Kimura,2Sen Hu,2Wei Yang,1Yang Liu,1Yongliao Zou
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2022.07.016]
1State Key Laboratory of Space Weather, National Space Science Center, Chinese Academy of Sciences, Beijing 100190, China
2Key Laboratory of Earth and Planetary Physics, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China
3National Institute of Polar Research, Tokyo 190-8518, Japan
Copyright Elsevier

The solar system could be separated into two zones based on the isotopic dichotomy between non-carbonaceous and carbonaceous groups, with the latter likely accreted in the outer solar system. Among carbonaceous groups, the CM chondrite contains high abundances of organic carbon and water. They have undergone aqueous alteration, thermal metamorphism and brecciation to different degrees (e.g., Rubin et al., 2007; Rubin et al., 2009; Tonui et al., 2014, Zolensky et al., 1997), which contributed to erasing most of the solar nebular records. Asuka 12169 was reported as the most primitive CM chondrite based on petrological and geochemical results, with little aqueous alteration (Kimura et al., 2020). In this paper, we report a survey of presolar grains in the fine-grained matrix and the accetionary rims of chondrules and CAIs in this meteorite, based on NanoSIMS mapping of C-, O-, and Si-isotopes. A total of 158 presolar grains were identified, including 119 silicates/oxides (208±20 ppm), 38 SiC (73±12 ppm) and 1 carbonaceous grain (2+5 -2 ppm). These abundances are within the maximum abundance ranges of primitive chondrites (80-280 ppm for O-rich grains and 10-180 ppm for C-rich grains). In comparison with most CM chondrites (<40 ppm), Asuka 12169 is uniquely rich in presolar silicates (185±18 ppm), with a high presolar silicate/oxide ratio of ∼8, therefore providing robust evidence for little aqueous alteration. The high abundances of presolar SiC and silicates in Asuka 12169 clearly show its pristine properties regarding both thermal and aqueous alteration. Group 1, 2, 3 and 4 subtypes of presolar O-rich grains account for 84%, 2.5%, 0.8% and 12.6%, respectively. One O-rich grain shows a high enhancement in 17O/16O and a subsolar 18O/16O ratio (17O/16O = 6.45±0.09×10-3 and 18O/16O = 1.90±0.02×10-3), indicating a stellar origin in binary star systems or novae. Most identified presolar SiC are mainstream grains of AGB origins. One with 28Si-excess is classified as an X grain, suggesting a supernova origin. There are two SiC grains that have 12C/13C <10 but close-to-solar Si isotopic ratios, and are therefore classified as AB type. The pristine features of Asuka 12169 suggest that it was probably located in the outermost few kilometers of the CM asteroid, where temperature was high enough for sublimation of water ice under vacuum, but where no aqueous alteration occurred, and where the depth was enough for lithification. The high abundances of various types of presolar grains, together with the petrographic information of Asuka 12169, provide crucial constrains on the original properties and subsequent evolution of the CM asteroids.

Slow cooling during crystallisation of barred olivine chondrules

1François Faure,1Marion Auxerre,1Valentin Casola
Earth and Planetary Science Letters 593, 117649 Link to Article [https://doi.org/10.1016/j.epsl.2022.117649]
1Université de Lorraine, CNRS, CRPG, UMR 7358, 15 rue Notre Dame des Pauvres, F-54501 Vandoeuvre-lès-Nancy, France
Copyright Elsevier

Barred olivine (BO) chondrules are small ferromagnesian silicate igneous droplets with unique dendritic textures that are considered to have formed in the early solar system during one or more brief high-temperature episodes, followed by rapid cooling in a gas. Rapid cooling rates of 100–7200 °C/h during chondrule formation have been proposed based on experiments attempting to reproduce BO crystal textures. However, the BO texture has never truly been reproduced under such rapid cooling conditions. Here, we experimentally show that true BO textures can be produced either after rapid cooling (>50 °C/h) following by reheating step or by cooling rates slower than 10 °C/h. Regardless of the thermal history considered, the chemical compositions of glass inclusions trapped within olivines of BO chondrules imply a final slow cooling rate one to two orders of magnitude below previous estimates. Such slow cooling rates are consistent with those estimated for plagioclase-bearing porphyritic chondrules and magmatic type-B Ca-Al-rich inclusions, suggesting that slow cooling rates are common to all similar chondritic objects.

Nova Colinas, Maranhão State: A newly confirmed, complex impact structure in Brazil

1Wolf Uwe Reimold et al. (>10)
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13833]
1Laboratory of Geochronology and Isotope Geochemistry, Instituto de Geociências, Universidade de Brasília, Brasília, DF, CEP70910-900 Brazil
Published by arrangement with John Wiley & Sons

The Nova Colinas structure is an approximately 7 km wide, nearly circular feature centered at 07°09′33″S/46°06′30″W in Nova Colinas municipality in southwestern Maranhão State, Brazil. The area has been investigated for 40 yr and it has been suggested repeatedly that the structure could be of impact origin—without proof having been furnished. Magnetic anomaly maps depict the structure clearly with a strong, positive magnetic anomaly over the apparent rim zone. The central area is characterized by significant positive K and Th radiometric anomalies. Fieldwork showed that the structure has annular features along the outside and some prominent, structurally dissected hills in the interior. Thirty-three arenite samples were collected for petrographic analysis, mostly from within the structure. Microdeformation, in the form of cataclasis; concussion fractures related to compaction, and presence of planar fractures, feather features, and planar deformation features in quartz are reported. Three samples with a multitude of quartz grains with these microdeformations were analyzed by universal stage to determine the crystallographic orientations of planar fractures and planar deformation features. The results provide robust evidence that these microdeformation features represent shock metamorphism, with low (approximately 5–10 GPa) to moderate (10–16 and 10–20 GPa) shock levels. Thus, the Nova Colinas structure is now confirmed as a bona fide meteorite impact structure. The structure is moderately eroded, as shown by the absence of stronger shock deformation. The still limited available structural geological field evidence, paired with remote sensing and geophysical data, indicates that the innermost part of the structure may have a sizable remnant of a central uplift. The Nova Colinas impact age is only poorly constrained from stratigraphic inference to an upper limit of about 200–250 Ma.