Constraints on the emplacement of Martian nakhlite igneous rocks and their source volcano from advanced micro-petrofabric analysis

1S.Griffin et al. (>10)
Journal of Geophysical Research (Planets)(in Press) Open Access Link to Article [https://doi.org/10.1029/2021JE007080]
1School of Geographical and Earth Sciences, University of Glasgow, Glasgow, UK
Published by arrangement with John Wiley & Sons

The Martian nakhlite meteorites, which represent multiple events that belong to a single magma source region represent a key opportunity to study the evolution of Martian petrogenesis. Here 16 of the 26 identified nakhlite specimens are studied using coupled electron backscatter diffraction (EBSD) and emplacement end-member calculations. EBSD was used to determine shape preferred orientation (SPO) of contained augite (high Ca-clinopyroxene) phenocrysts by considering their crystallographic preferred orientation (CPO). Parameters derived from EBSD, and energy dispersive X-ray spectroscopy (EDS) data were used in basic emplacement models to assess their dominant mechanism against three end-member scenarios: thermal diffusion, crystal settling, and crystal convection. Results from CPO analyses indicate low intensity weak-moderate CPO. In all samples, a consistent foliation within the <001> axes of augite are observed typically coupled with a weaker lineation CPO in one of the other crystallographic axes. These CPO results agree best with crystal settling being the dominant emplacement mechanism for the nakhlites. Modelled crystal settling results identify two distinguishable groups outside of the model’s resolution indicating the presence of secondary emplacement mechanisms. Comparison of the two identified groups against petrofabric, geochemical, and age parameters indicate random variability between individual meteorites. Therefore, coupled petrofabric and emplacement modelling results identify an overarching characteristic of a dominant crystal settling emplacement mechanism for the nakhlite source volcano despite exhibiting random variation with each discharge through time.

Oxidized and reduced sulfur observed by the Sample Analysis at Mars (SAM) instrument suite on the Curiosity rover within the Glen Torridon region at Gale crater, Mars

1G.M.Wong et al. (>10)
Journal of Geophysical Research (Planets)(In Press) Open Access Link to Article [https://doi.org/10.1029/2021JE007084]
1Department of Geosciences, The Pennsylvania State University, University Park, PA, USA
Published by arrangement with John Wiley & Sons

The Mars Science Laboratory (MSL) Curiosity rover has been assessing the habitability and geologic history of Gale crater, Mars since landing in 2012. One of the primary objectives of the mission was to investigate a clay-bearing unit identified using orbital spectral data, designated the Glen Torridon (GT) region. This region was of particular interest because of its elevated abundance of clay minerals that may have preserved geochemical evidence of ancient habitable environments. The Curiosity rover explored the GT region for ∼750 sols and analyzed eight drilled samples with the Sample Analysis at Mars (SAM) instrument suite using evolved gas analysis-mass spectrometry. Evolved sulfur-bearing gases provided insight about the composition of sulfur-containing compounds in Martian samples. Evolved gases were analyzed by three methods to understand the oxidation state of sulfur in the samples: (1) SO2 evolution temperature, (2) quadratic discriminant analysis comparing SAM data to SAM-like laboratory investigations, and (3) sulfur isotope values from evolved 34SO2/32SO2. The results of these three methods were consistent with the majority of sulfur in the GT region being in an oxidized state, but two of the eight samples analyzed by SAM were consistent with the presence of small amounts of reduced sulfur. The oxidized and reduced sulfur could have a variety of sources and represents a nonequilibrium assemblage that could have supported putative ancient chemolithotrophic metabolisms.