Coordinated chemical and microstructural analyses of presolar silicate grains from AGB/RGB stars and supernovae in the CO3.0 chondrite Dominion Range 08006

1Laura B. Seifert,1Pierre Haenecour,1,2Thomas J. Zega
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13811]
1Lunar and Planetary Laboratory, University of Arizona, 1629 E. University Blvd, Tucson, Arizona, 85721 USA
2Department of Materials Science and Engineering, University of Arizona, 1235 E. James E. Rogers Way, Tucson, Arizona, 85721 USA
Published ba arrangement with John Wiley & Sons

We report the structural and chemical analyses of six presolar silicate grains identified in situ in the CO3.0 carbonaceous chondrite Dominion Range (DOM) 08006. Two of the grains have O-isotopic compositions consistent with origins in the circumstellar envelopes of low-mass (<2M☉) asymptotic giant branch (AGB)/red giant branch (RGB) stars, although without Mg-isotopic data, origins in supernovae (SNe) cannot be ruled out. The other four grains have O-isotopic compositions consistent with origins in the ejecta of type-II SNe. Transmission electron microscopy analyses reveal that all grains are crystalline (single crystal or polycrystalline) and have varied compositions. The analyzed AGB/RGB grains include an Fe-rich crystalline olivine with an Fe-sulfide inclusion and a chemically zoned olivine grain that also contains an Fe-oxide rim. The grains derived from SNe include two polycrystalline assemblages with structures that overlap with both olivine and pyroxene, an assemblage composed of both a single crystal of forsterite and polycrystalline forsterite, and an orthopyroxene grain with an embedded Fe-sulfide crystal. The thermodynamic origins of both AGB/RGB and SN grains are also diverse. The structure and compositions of two grains are consistent with equilibrium thermodynamic predictions of condensation, whereas four are not, suggesting formation through nonequilibrium or multistep processes. Our observations of presolar silicate grains suggest that the circumstellar envelopes of AGB/RGB stars and the ejecta of SNe can produce grains with comparable structures and compositions.

Olivine aggregates reveal a complex collisional history of the main group pallasite parent body

1Nicolas P. Walte,2Gregor J. Golabek
Meteoritics & Planetary Science (in Press) Open Access Link to Article [https://doi.org/10.1111/maps.13810]
1Heinz Maier-Leibnitz Center for Neutron Science (MLZ), Technical University Munich, Garching, 85748 Germany
2Bayerisches Geoinstitut (BGI), University of Bayreuth, Bayreuth, 95447 Germany
Published by arrangement with John Wiley & Sons

Olivine aggregates, bodies found in pallasites that consist of olivines with coherent grain boundaries and minor amounts of Fe-Ni and troilite, likely represent well-preserved samples of different mantle regions of pallasite parent bodies (PPBs). We investigated olivine aggregates from the main group pallasites Fukang, Esquel, Imilac, and Seymchan and compare their textures with results from deformation experiments. Our measurements reveal an inverse relationship between the grain size of olivines and the primary metal fraction inside olivine aggregates, which is explained by simultaneous grain growth retarded by Zener pinning in different mantle regions. Textural evidence indicates that the mantle has remained at high temperatures before initial cooling occurred shortly after pallasite formation that was likely caused by an impact. Different degrees of annealing of the deformation textures suggest that the postcollisional cooling occurred in the order Seymchan, Imilac, Esquel, and Fukang. We interpret this observation with an increasing burial depth after the collision. We also demonstrate that the mantle has not been convecting before the impact despite being at high temperature. Using the minimum critical Rayleigh number, we estimate PPB radii assuming different core radii. Our results question the recent ferromagmatism hypothesis for pallasite formation and support a multistage formation process that includes one or several impacts.

Measuring the shock stage of Itokawa and asteroid regolith grains by electron backscattered diffraction, optical petrography, and synchrotron X-ray diffraction

1Michael Zolensky et al. (>10)
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13808]
1Astromaterials Research and Exploration Science, NASA Johnson Space Center, Houston, Texas, 77058 USA
Published by arrangement with John Wiley & Sons

Our goal was to devise a bridge between shock determinations of asteroid regolith grains by standard light optical petrography, synchrotron X-ray diffraction (SXRD), and electron backscattered diffraction (EBSD). We determined the optimal conditions under which to measure the shock stage of olivine crystals in astromaterial grains by EBSD. We applied this EBSD procedure to the shock stage determination of four regolith grains from asteroid Itokawa, returned to earth by the Hayabusa spacecraft. Interpretation of these data required a parallel examination of three ordinary chondrite standards that exhibited shock histories ranging from stage 2 to stage 4, using all three techniques. Standard light optical petrography indicated shock stage of S2/3 for the 24 Itokawa grains analyzed. SXRD results for seven Itokawa grains indicate a shock stage of S2. EBSD maps of four Itokawa grains indicate shock stage S3. Thus, the different techniques indicate slightly different shock stages, probably due to small sampling populations for EBSD and SXRD. We therefore recommend that significantly more than seven regolith grains should be separately analyzed by any shock determination technique, probably between 10 and 20. In any case, Itokawa regolith grains have been shocked to stage S2/3, or approximately 5–10 GPa. Finally, we investigated the crystallinity of one Itokawa olivine by SXRD, determining that the 5–10 GPa shock it had experienced did not appreciably alter the size of the unit cell, contrary to some previous suggestions.