The Famenin fall and other ordinary chondrites intermediate between H and L groups

1,2Hamed Pourkhorsandi,1Jérôme Gattacceca,1Pierre Rochette,3Thomas Smith,4Lydie Bonal,5Massimo D’Orazio,1Bertrand Devouard,1Corinne Sonzogni,2Vinciane Debaille
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13801]
1CNRS, IRD, INRAE, CEREGE, Aix-Marseille Univ, Aix-en-Provence, France
2Laboratoire G-Time, Université Libre de Bruxelles, CP 160/02, 50, Av. F.D. Roosevelt, Brussels, 1050 Belgium
3Institute of Geology and Geophysics, Chinese Academy of Sciences, 19 Beitucheng Western Road Chaoyang District, Box 9825, Beijing, 100029 China
4Institut de Planétologie et d’Astrophysique de Grenoble, Grenoble, France
5Dipartimento di Scienze della Terra, Università di Pisa, Pisa, Italy
Published by arrangement with John Wiley & Sons

The Famenin meteorite fell around 08:30 a.m. local time (GMT+4.5) on June 27, 2015 on the roof of a house in Famenin, a town in NW Iran. A single 640 g stone was recovered, shattered into several pieces upon impact. The shape of the impact hole and the relative position of the recovered meteorites indicate a N-NW fall direction. Famenin is an ordinary chondrite (OC) with well-preserved chondrules of various types, (Fe,Ni) metal, troilite, phosphate, and chromite. The organic matter systematics and the olivine and low-Ca compositional distributions (percent mean deviations 18% and 31%, respectively) indicate it is a type 3.4/3.8 chondrite. Considering the average chemical compositions of olivine (Fa17.5±4.7) and low-Ca pyroxene (Fs16.8±7.5), average Co content of the kamacite (5.6 mg g−1), and Cu/Ni and Ga/Ni ratios, Famenin should be classified as an H chondrite. However, saturation magnetization is 26.0 Am2 kg−1, indicating a bulk metal content similar to L chondrites. Similarly, the whole-rock Ni and Co contents (13073 and 540 µg g−1, respectively), and average chondrule diameter (550 µm) are closer to typical values for L chondrites than H chondrites. The (Fe,Ni) metal modal abundance (5 vol%), magnetic susceptibility, and possibly whole-rock oxygen isotopic composition indicate intermediate properties between H and L chondrites. Noble gas composition and cosmic-ray exposure ages of Famenin and El Médano 195 (another intermediate OC) shows their gas-rich character and an older ejection age from their parent body than those for the majority of H and L chondrites. Famenin, together with similar intermediate OCs, increases the diversity of this meteorite clan and suggests the existence of a separate OC group with a composition broadly intermediate between H and L groups for which a different designation (HL) is proposed. OCs likely originate from more than three parent bodies (H, L, and LL) as traditionally proposed.

Petrogenesis of Northwest Africa 8686: A ferroan olivine-phyric shergottite

1Robert W. Nicklas,1James M. D. Day,2Zoltan Vaci,3Arya Udry
Meteoritics & Planetary Science (in Press) Link to Article [https://doi.org/10.1111/maps.13805]
1Scripps Institution of Oceanography, University of California San Diego, La Jolla, California, 92093 USA
2Department of Earth and Planetary Science, Institute of Meteoritics, University of New Mexico, Albuquerque, New Mexico, 87131 USA
3Department of Geoscience, University of Nevada, Las Vegas, Las Vegas, Nevada, 89154 USA
Published by arrangement with John Wiley & Sons

Northwest Africa (NWA) 8686 is an olivine-phyric shergottite containing up to ~500 μm long olivine crystals in a fine-grained groundmass of augite, pigeonite, and maskelynite, with accessory merrillite, pyrrhotite, and oxides. Bulk rock and mineral major and trace element concentrations are reported for NWA 8686, along with bulk rock highly siderophile element (HSE: Os, Ir, Ru, Pt, Pd, Re) abundances and 187Re-187Os data. Based on its mineralogy, texture, and bulk rock rare earth element (REE) abundances, NWA 8686 is classified as an intermediate olivine-phyric shergottite. It is notable for having some of the most ferroan olivine macrocrysts (forsterite content = 51.5 ± 3.5) of any olivine-phyric shergottite. Olivine is absent from the NWA 8686 groundmass, which is unique for olivine-phyric shergottites, and the calculated groundmass composition is also not olivine normative. The bulk meteorite has a low Mg# of 59 yet has HSE in broadly chondritic proportions (~0.005 × CI chondrite). The bulk rock REE pattern for NWA 8686 shows depletions in both the light and heavy REE relative to the middle REE. Compiled olivine and bulk rock data for olivine-phyric shergottites indicate that olivine macrocrysts in almost all these meteorites are the result of entrainment of antecrysts or xenocrysts. The combination of low Mg# and chondritic HSE signatures in NWA 8686 means that it may have been formed either from the mixing between an evolved lava and early-formed HSE-rich phases such as Os-Ir alloys or by the melting of a low Mg# mantle source with chondritic HSE abundances. The elevated Gd/Yb ratio in both NWA 8686 and other intermediate olivine-phyric shergottites indicates that garnet was involved as either a residual or fractionating phase in their petrogenesis.

Smooth rims in Queen Alexandra Range (QUE) 99177: Fluid–chondrule interactions and clues on the geochemical conditions of the primordial fluid that altered CR carbonaceous chondrites

1Marina Martínez,1Adrian J.Brearley
Geochimica et Cosmochimica Acta (in Press) Link to Article [https://doi.org/10.1016/j.gca.2022.03.019]
1Department of Earth & Planetary Sciences, MSC03-2040, 1University of New Mexico, Albuquerque, NM 87131, USA
Copyright Elsevier

Queen Alexandra Range (QUE) 99177 is one of the least altered CR carbonaceous chondrite known, with mineralogical and isotopic characteristics that indicate a high level of pristinity. In this study, we have examined the so-called smooth rims that surround many type I chondrules in QUE 99177, using SEM, EPMA, and FIB-TEM techniques. We have characterized their constituent phases to unravel the precursor material(s) of smooth rims, assess their formation mechanisms, and constrain the conditions of the altering fluid. Smooth rims are the most common type of rims around type I chondrules and exclusively occur around chondrules with Silica-rich Igneous Rims (SIRs). Smooth rims consist of an Fe-rich, hydrous silicate material that is Si- and Fe-rich, with minor Mg, Al, Ca, and Mn, and gives low analytical totals measured by EPMA. TEM observations reveal that the Fe-rich silicate phase is an amorphous gel that contains unaltered crystalline phases and igneous glass. Crystalline phases consist of igneous, unaltered, zoned pyroxenes with compositions consistent with pyroxenes in SIRs, as well as albite and chromite. The amorphous gel preserves previous crystal outlines with morphologies consistent with silica (cristobalite) grains in SIRs and has a composition identical to pseudomorphic silica replacements in SIRs. Based on these observations, we conclude that smooth rims derive from low-temperature aqueous alteration of silica in SIRs by an Fe-rich fluid. We suggest that the Fe was derived by leaching of amorphous silicates in the matrix, which reacted rapidly with melted water ice, although alteration of Fe,Ni metal blebs in SIRs could potentially be an additional source of Fe. Silica underwent dissolution and replacement whereas feldspar and glass remained unaltered because (1) the fluid was slightly alkaline, (2) cristobalite has a reaction rate much higher than quartz and feldspar, and (3) the alteration was very limited and fast, indicating that it was due solely to melting of accreted water ice and there was no introduction of additional fluid from external sources.