Spectral reflectance properties of minerals exposed to martian surface conditions: Implications for spectroscopy-based mineral detection on Mars

1Nathalie Turenne,1Alexis Parkinson,1Daniel M.Applin,1Paul Mann,1Edward A.Cloutisa,2Stanley A.Mertzman
Planetary and Space Science (in Press) Link to Article [https://doi.org/10.1016/j.pss.2021.105377]
1Centre for Terrestrial and Planetary Exploration, University of Winnipeg, Winnipeg, Manitob, R3B 2E9, Canada
2Department of Earth and Environment, Franklin and Marshall College, P.O. Box 3003, Lancaster, PA, 17604, 3003, USA

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The evidence for unusually high hydrogen abundances in the central part of Valles Marineris on Mars

1I.Mitrofanov,1A.Malakhov,1M.Djachkova,1D.Golovin,1M.Litvak,1M.Mokrousov,1A.Sanin,2H.Svedhem,1L.Zelenyi
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2021.114805]
1Space Research Institute of the Russian Academy of Sciences, Profsoyuznaya str. 84/32, 117997 Moscow, Russia
2European Space Agency, ESTEC, Keplerlaan 1, 2201 AZ Noordwijk, Netherlands
Copyright Elsevier

Studies of hydrogen deposition in the shallow Martian subsurface have been conducted by two neutron and one gamma-ray detectors in the past and provided global hydrogen maps (Boynton et al., 2002; Feldman et al., 2002; Mitrofanov et al., 2002). It is known from these maps that hydrogen is most abundant in the polar permafrost areas compared to the equatorial band where frozen water is not stable on the surface. However, the spatial resolution of hundreds of kilometres typical for these maps does not allow for detection of local hydrogen-rich features that can be associated with geological structures. FREND neutron telescope (Mitrofanov et al., 2018) onboard ExoMars TGO (Vago et al., 2015) is capable of a much better spatial resolution for mapping neutron emission of Mars. In this Report we present the analysis of the most intriguing local area of highly suppressed neutron emission in the vicinity of the Martian equator, which coincides with Candor Chaos in the central area of Valles Marineris, thought to be promising for testing water ice (Gourronc et al., 2014). Provided such suppression would be interpreted as the evidence for very high content of hydrogen in the soil, the mean water equivalent hydrogen value in the local suppression area should be as large as 40.3 wt%. This finding is thought to be uncommon for equatorial regions, but is probably associated with particular geomorphological conditions inside Valles Marineris.

MAGMARS: a Melting Model for the Martian Mantle and FeO-rich Peridotite

1Max Collinet,1Ana-Catalina Plesa,2Timothy L. Grove,1Sabrina Schwinger,3,1Thomas Ruedas,1Doris Breuer
Journal of Geophysical Research (Planets) (In Press) Link to Article [https://doi.org/10.1029/2021JE006985]
1German Aerospace Center (DLR), Institute of Planetary Research, Rutherfordstraße 2, 12 489 Berlin Germany
2Massachusetts Institute of Technology, Department of Earth, Atmospheric and Planetary Sciences, 77 Massachusetts Avenue, MA, 02 139 USA
3Museum für Naturkunde Berlin, Impact and Meteorite Research, Invalidenstraße 43, 10 115 Berlin Germany
Published by arrangement with John Wiley & Sons

Martian basalts identified by rover in-situ analyses and the study of meteorites represent a direct link to the melting process in the planet’s interior and can be used to reconstruct the composition of the mantle and estimate its temperature. Experimentally calibrated numerical models are powerful tools to systematically search for the mantle compositions and melting conditions that can produce melts similar to primary basalts. However, currently available models are not suitable for modeling the melting of FeO-rich peridotites. In this study, we present experiments performed at 1.0 and 2.4–2.6 GPa on a primitive Martian mantle with various P2O5 contents. We use the new experiments together with a comprehensive database of previous melting experiments to calibrate a new model called MAGMARS. This model can reproduce the experimental melt compositions more accurately than Gibbs free energy minimization software (e.g. pMELTS) and can simulate near-fractional polybaric melting of various mantle sources. In addition, we provide an updated thermobarometer that can estimate the P–T melting conditions of primary melts and can be used as a prior step to constrain the input parameters of the MAGMARS melting model. We apply MAGMARS to estimate the source composition of the Adirondack-class basalts and find that melting a depleted mantle, at 2.3–1.7 GPa (Tp=1390±40°C) can best explain their bulk composition and K2O/Na2O ratio. MAGMARS represents a fast and accurate alternative to calculate the composition of the Martian primary melts and can be used as a stand-alone package or integrated with geodynamical models or other independent modeling software.

Machine Learning Mid-Infrared Spectral Models for Predicting Modal Mineralogy of CI/CM Chondritic Asteroids and Bennu

1L.B.Breitenfeld et al. (>10)
Journal of Geophysical research (Planets) (In Press) Link to Article [https://doi.org/10.1029/2021JE007035]
1Department of Geosciences, Stony Brook University, Stony Brook, NY, USA
Published by arrangement with John Wiley & Sons

Planetary surfaces can be complex mixtures of coarse and fine particles that exhibit linear and nonlinear mixing behaviors at mid-infrared (MIR) wavelengths. Machine learning multivariate analysis can estimate modal mineralogy of mixtures and is favorable because it does not assume linear mixing across wavelengths. We used partial least squares (PLS) and least absolute shrinkage and selection operator (lasso), two types of machine learning, to build MIR spectral models to determine the surface mineralogy of the asteroid (101955) Bennu using OSIRIS-REx Thermal Emission Spectrometer (OTES) data. We find that PLS models outperform lasso models. The cross-validated root-mean-square error of our final PLS models (consisting of 317 unique spectra of samples derived from 13 analog mineral samples and eight meteorites) range from ∼4–13 vol% depending on the mineral group. PLS predictions in vol% of Bennu’s average global composition are 78% phyllosilicate, 9% olivine, 11% carbonates, and 6% magnetite. Pyroxene is not predicted for the global average spectrum, though it has been detected in small amounts on Bennu. These mineral abundances confirm previous findings that the composition of Bennu is consistent with CI/CM chondrites with high degrees of aqueous alteration. The predicted mineralogy of two previously identified OTES spectral types vary minimally from the global average. In agreement with previous work, we interpret OTES spectral differences as primarily caused by relative abundances of fine particulates rather than major compositional variations.