¹C.M.Lisse et al. (>10)
The Astrophysical Journal 894, 116 Link to Article [DOI https://doi.org/10.3847/1538-4357/ab7b80]
¹ JHU-APL, 11100 Johns Hopkins Road, Laurel, MD 20723, USA; carey.lisse@jhuapl.edu, ron.vervack@jhuapl.edu

We report here time-domain infrared spectroscopy and optical photometry of the HD 145263 silica-rich circumstellar-disk system taken from 2003 through 2014. We find an F4V host star surrounded by a stable, massive 1022–1023 kg (MMoon to MMars) dust disk. No disk gas was detected, and the primary star was seen rotating with a rapid ~1.75 day period. After resolving a problem with previously reported observations, we find the silica, Mg-olivine, and Fe-pyroxene mineralogy of the dust disk to be stable throughout and very unusual compared to the ferromagnesian silicates typically found in primordial and debris disks. By comparison with mid-infrared spectral features of primitive solar system dust, we explore the possibility that HD 145263’s circumstellar dust mineralogy occurred with preferential destruction of Fe-bearing olivines, metal sulfides, and water ice in an initially comet-like mineral mix and their replacement by Fe-bearing pyroxenes, amorphous pyroxene, and silica. We reject models based on vaporizing optical stellar megaflares, aqueous alteration, or giant hypervelocity impacts as unable to produce the observed mineralogy. Scenarios involving unusually high Si abundances are at odds with the normal stellar absorption near-infrared feature strengths for Mg, Fe, and Si. Models involving intense space weathering of a thin surface patina via moderate (T < 1300 K) heating and energetic ion sputtering due to a stellar super-flare from the F4V primary are consistent with the observations. The space-weathered patina should be reddened, contain copious amounts of nanophase Fe, and should be transient on timescales of decades unless replenished.

¹Alexey Potapov,¹Cornelia Jäger,²Thomas Henning
The Astrophysical Journal 894, 110 Link to Article [DOI https://doi.org/10.3847/1538-4357/ab86b5]
¹Laboratory Astrophysics Group of the Max Planck Institute for Astronomy at the Friedrich Schiller University Jena, Institute of Solid State Physics, Helmholtzweg 3, D-07743 Jena, Germany; alexey.potapov@uni-jena.de
²Max Planck Institute for Astronomy, Königstuhl 17, D-69117 Heidelberg, Germany

The catalytic role of dust grain surfaces in the thermal reaction CO2 + 2NH3 → NH4+NH2COO− was recently demonstrated by our group. The rate coefficients for the reaction at 80 K on the surface of nanometer-sized carbon and silicate grains were measured to be up to three times higher compared to the reaction rate coefficients measured on KBr. In this study, the reaction was performed on carbon grains and on KBr in the extended temperature range of 50–80 K and with the addition of water ice. The reaction activation energy was found to be about three times lower on grains compared to the corresponding ice layer on KBr. Thus, the catalytic role of the dust grain surface in the studied reaction can be related to a reduction of the reaction barrier. Addition of water to NH3:CO2 ice on grains slowed the reaction down. At the H2O:CO2 ratio of 5:1, the reaction was not detected on the experimental timescale. This result calls into question the thermal formation of ammonium carbamate in dense molecular clouds and outer regions of protostellar and protoplanetary environments with dominating water ice mantle chemistry. However, it can still happen in inner regions of protostellar and protoplanetary environments in crystalline ices.

¹Florian Kirchschlager,¹M. J. Barlow,¹Franziska D. Schmidt
The Astrophysical Journal 893, 70 Link to Article [DOI https://doi.org/10.3847/1538-4357/ab7db8]
¹Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT, UK; f.kirchschlager@ucl.ac.uk

Core-collapse supernovae can condense large masses of dust post-explosion. However, sputtering and grain–grain collisions during the subsequent passage of the dust through the reverse shock can potentially destroy a significant fraction of the newly formed dust before it can reach the interstellar medium. Here we show that in oxygen-rich supernova remnants like Cassiopeia A, the penetration and trapping within silicate grains of the same impinging ions of oxygen, silicon, and magnesium that are responsible for grain surface sputtering can significantly reduce the net loss of grain material. We model conditions representative of dusty clumps (density contrast of χ = 100) passing through the reverse shock in the oxygen-rich Cassiopeia A remnant and find that, compared to cases where the effect is neglected as well as facilitating the formation of grains larger than those that had originally condensed, ion trapping increases the surviving masses of silicate dust by factors of up to two to four, depending on initial grain radii. For higher density contrasts (χ gsim 180), we find that the effect of gas accretion on the surface of dust grains surpasses ion trapping, and the survival rate increases to ~55% of the initial dust mass for χ = 256.