¹Sébastien Charnoz,²Paolo A.Sossi,³Yueh-Ning Lee,¹Julien Siebert,⁴Ryuki Hyodo,¹Laetitia Allibert,¹Francesco C.Pignatale,¹Maylis Landeau,⁵Apurva V.Oza,¹Frédéric Moynier
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2021.114451]
¹Université de Paris, Institut de Physique du Globe de Paris, CNRS, F-75005 Paris, France
²Institute of Geochemistry and Petrology, ETH Zürich, CH-8092 Zürich, Switzerland
³Department of Earth Sciences, National Taiwan Normal University, 88, Sec. 4, Ting-Chou Road, Taipei City 11677, Taiwan
⁴ISAS, JAXA, Sagamihara, Japan
⁵Physikalisches Institut, Universität Bern, Bern, Switzerland
Copyright Elsevier

Prevailing models for the formation of the Moon invoke a giant impact between a planetary embryo and the proto-Earth (Canup, 2004; Ćuk et al., 2016). Despite similarities in the isotopic and chemical abundances of refractory elements compared to Earth’s mantle, the Moon is depleted in volatiles (Wolf and Anders, 1980). Current models favour devolatilisation via incomplete condensation of the proto-Moon in an Earth-Moon debris-disk (Charnoz and Michaut, 2015; Canup et al., 2015; Lock et al., 2018). However the physics of this protolunar disk is poorly understood and thermal escape of gas is inhibited by the Earth’s strong gravitational field (Nakajima and Stevenson, 2014). Here we investigate a simple process, wherein the Earth’s tidal pull promotes intense hydrodynamic escape from the liquid surface of a molten proto-Moon assembling at 3–6 Earth radii. Such tidally-driven atmospheric escape persisting for less than 1 Kyr at temperatures ∼1600 − 1700 K reproduces the measured lunar depletion in K and Na, assuming the escape starts just above the liquid surface. These results are also in accord with timescales for the rapid solidification of a plagioclase lid at the surface of a lunar magma ocean (Elkins-Tanton et al., 2011). We find that hydrodynamic escape, both in an adiabatic or isothermal regime, with or without condensation, induces advective transport of gas away from the lunar surface, causing a decrease in the partial pressures of gas species (Ps) with respect to their equilibrium values (Psat). The observed enrichment in heavy stable isotopes of Zn and K (Paniello et al., 2012; Wang and Jacobsen, 2016) constrain Ps/Psat > 0.99, favouring a scenario in which volatile loss occurred at low hydrodynamic wind velocities (<1% of the sound velocity) and thus low temperatures. We conclude that tidally-driven atmospheric escape is an unavoidable consequence of the Moon’s assembly under the gravitational influence of the Earth, and provides new pathways toward understanding lunar formation.

¹Mathilde Faure et al. (>10)
Icarus (in Press) Link to Article [https://doi.org/10.1016/j.icarus.2021.114462]
¹Université Grenoble Alpes, CNRS, Institut de Planétologie et Astrophysique de Grenoble (IPAG), UMR 5274, Grenoble F-38041, France
Copyright Elsevier

We question here the radiolytic origin of (i) polyaromatic insoluble organic matter (IOM) recovered from primitive chondrites, and (ii) organics at the surface of reddish Trans-Neptunian Objects (TNOs), some minor planets and icy satellites. Organic synthesis by ion irradiation was investigated through experiments on a variety of targets: Polyethylene glycol 1450, lignin, cellulose and sucrose, exposed to low (C 40 keV and Ne 170 keV) and high energy (C 12 MeV, Ni 17 MeV, 78Kr 59 MeV) ions. These experiments show that all carbonaceous precursors evolve towards a sp2-rich amorphous carbon (a-C) above a critical nuclear dose of 10−7+10 eV.atom−1. A thorough review of the literature shows that this value applies for a large range of carbonaceous materials, including C-rich simple ices. Below this critical dose, irradiated targets are carbonized and transformed into cross-linked polymeric disordered solids, with abundant olefinic and acetylenic bonds, but devoid of aromatic or polyaromatic species. Ion irradiation of simple compounds, e.g. ices, is thereby not a viable process to synthesize IOM. However, in the case of aromatic-rich precursors, swift heavy ions irradiation leads to polyaromatic materials, by bridging existing aromatic or polyaromatic units. In the context of Early Solar System, i.e. Galactic Cosmic Rays (GCR) irradiation during 10–20 Myr, the formation of chondritic IOM from simple ices mixed with interstellar Polycyclic Aromatic Hydrocarbons (PAHs) appears as a plausible mechanism. This scenario, based on the recycling of existing carbonaceous interstellar grains under low-temperature conditions, would account for the heterogeneity of the D, 15N and 13C isotopic fractionations at the molecular scale, and the preservation of deuterium hot spots that are highly sensitive to high-temperature conditions (> 300 °C). At the surface of TNOs, sp2-rich amorphous carbons are formed by the implantation of GCRs and Solar wind ions. The electronic dose is also very high for an irradiation time of several Gyr (> 100 eV.atom−1), leading to the formation of reddish disordered solids, provided that the surface contains a minimum abundance of carbonaceous species. Finally, sp2-rich amorphous carbons produced in the laboratory (e.g. the ACAR compound from Zubko et al., 1996) are fair analogues of the darkening agent produced by radiolysis.