Modeling the Dielectric Properties of Minerals from Crystals to Bulk Powders for Improved Interpretation of Asteroid Radar Observations

1,2D. C. Hickson,3A. L. Boivin,4C. A. Tsai,1M. G. Daly,3R. R. Ghent
Journal of Geophysical Research (Planets) (In Press) Link to Article [https://doi.org/10.1029/2019JE006141]
1Centre for Research in Earth and Space Science, York University, Toronto, ON, Canada
2Arecibo Observatory, University of Central Florida, PR, USA
3Solar System Exploration Group, Department of Earth Sciences, University of Toronto, Toronto, ON, Canada
4Department of Physics, University of Toronto, Toronto, ON, Canada
Published by arrangement with John Wiley & Sons

Planetary radar has provided a growing number of datasets on the inner planets and near‐Earth and main‐belt asteroid populations in the solar system. Physical interpretation of radar data for inference of surface properties requires constraints on the constitutive parameters of the material making up a given surface. In this study, the complex permittivity of seven minerals as a function of frequency and porosity is measured using the coaxial transmission line method to determine the mixing equation that best describes the relationship between the real part of the complex permittivity of single mineral crystals and granular mineral powders. We find the Looyenga‐Landau‐Lifshitz and Bruggeman Symmetric mixing equations to describe our experimental results with the highest accuracy. The variation in the real part of the permittivity of solid mineral crystals between different minerals is shown to depend on the grain density and the chemical composition of the minerals. These mixing relationships are incorporated into an asteroid radar model and used to calculate the porosity in the near‐surface of seven asteroids visited by robotic spacecraft using Earth‐based radar observations. The results of the asteroid radar model support the presence of significant porosity in the boulders on the surface of asteroid 101955 Bennu. This research highlights the ability of radar to measure the porosity on asteroid surfaces and provides theoretical and experimental justification for the inversion of permittivity to bulk density assumed by the asteroid radar model.

Constraints on the Mineralogy and Geochemistry of the Vera Rubin ridge, Gale crater, Mars, from Mars Science Laboratory Sample Analysis at Mars Evolved Gas Analyses

1Amy C. McAdam et al. (>10)
Journal of Geophysical Research (Planets) (In Press) Link to Article [https://doi.org/10.1029/2019JE006309]
1NASA Goddard Space Flight Center, Greenbelt, MD, USA
Published by arrangement with John Wiley & Sons

Vera Rubin ridge (VRR) is a topographic high within the layers of Mount Sharp, Gale crater, that exhibits a strong hematite spectral signature from orbit. The Mars Science Laboratory Curiosity rover carried out a comprehensive investigation to understand the depositional and diagenetic processes recorded in the rocks of VRR. Sample Analysis at Mars (SAM) evolved gas analyses (EGA) were performed on three samples from the ridge and one from directly beneath the ridge. SAM evolved H2O data suggested the presence of an Fe‐rich dioctahedral smectite, such as nontronite, in the sample from beneath the ridge. H2O data are also consistent with ferripyrophyllite in VRR samples. SAM SO2 data indicated that all samples contained Mg sulfates, and some Fe sulfate. Several volatile detections suggested trace reduced sulfur sources, such as Fe sulfides and/or S‐bearing organic compounds, in two samples while significant O2 and NO evolved from one sample indicated the presence of oxychlorine and nitrate/nitrite salts, respectively. The O2 evolution was the second highest to date and the first observed in ~1200 sols. HCl released from all samples likely resulted, in part, from trace chloride salts. All samples evolved CO2 and CO consistent with oxidized carbon compounds (e.g., oxalates), while some CO2 may result from carbonate. SAM‐derived constraints on the mineralogy and chemistry of VRR materials, in the context of additional mineralogy, geochemistry, and sedimentology information obtained by Curiosity , support a complex diagenetic history that involved fluids of a range of possible salinities, redox characteristics, pHs, and temperatures.